105-58-8 | Diethyl carbonate

Packsize	Purity	Availability	Price	Discounted Price
5g	98%	in stock	$9.00	$6.00
25g	98%	in stock	$15.00	$10.00
100g	98%	in stock	$20.00	$14.00
250g	98%	in stock	$30.00	$21.00
500g	98%	in stock	$44.00	$31.00

Description

• Catalog Number: AB45894
• Chemical Name: Diethyl carbonate
• CAS Number: 105-58-8
• Molecular Formula: C5H10O3
• Molecular Weight: 118.1311
• MDL Number: MFCD00009107
• SMILES: CCOC(=O)OCC
• NSC Number: 8849

Computed Properties

• Complexity: 62.1
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 8
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• XLogP3: 1.2

Upstream Synthesis Route

Diethyl carbonate serves as a versatile chemical reagent in various synthetic processes due to its unique properties. In chemical synthesis, it commonly acts as a solvent and a reactant. As a solvent, diethyl carbonate is utilized in reactions such as esterifications, transesterifications, and carbonylation reactions. Its high boiling point and low toxicity make it a favorable choice for these applications. Additionally, diethyl carbonate can also serve as a reactant in the synthesis of various organic compounds, including pharmaceutical intermediates, plasticizers, and specialty chemicals. Its ability to undergo reactions such as transesterification, condensation, and carbonylation makes it an essential component in the production of a wide range of chemical products. With its versatile nature and reactivity, diethyl carbonate plays a crucial role in advancing synthetic chemistry processes.

Literature

• Carbonate, acetate and phenolate phosphonium salts as catalysts in transesterification reactions for the synthesis of non-symmetric dialkyl carbonates.

  Organic & biomolecular chemistry 20120828

• Iridium-catalyzed oxidant-free dehydrogenative C-H bond functionalization: selective preparation of N-arylpiperidines through tandem hydrogen transfers.

  Angewandte Chemie (International ed. in English) 20120827

• Synthesis, characterization, and use of Nb(V)/Ce(IV)-mixed oxides in the direct carboxylation of ethanol by using pervaporation membranes for water removal.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20120813

• A convenient synthesis of triflate anion ionic liquids and their properties.

  Molecules (Basel, Switzerland) 20120507

• Identification of aroma-active compounds in Jiashi muskmelon juice by GC-O-MS and OAV calculation.

  Journal of agricultural and food chemistry 20120502

• Physical and electrochemical properties of synthesized carbon nanotubes [CNTs] on a metal substrate by thermal chemical vapor deposition.

  Nanoscale research letters 20120101

• Integrative and intermediate self-assembly of multi-walled hybrid nanotubes for catanionic biomimetics.

  Chemical communications (Cambridge, England) 20111214

• Thermal properties of ionic systems near the liquid-liquid critical point.

  The Journal of chemical physics 20111207

• Structure-activity relationship for the first-in-class clinical steroid sulfatase inhibitor Irosustat (STX64, BN83495).

  ChemMedChem 20111104

• Enzymatic synthesis of fatty acid ethyl esters by utilizing camellia oil soapstocks and diethyl carbonate.

  Bioresource technology 20111101

• A solid lithium electrolyte via addition of lithium isopropoxide to a metal-organic framework with open metal sites.

  Journal of the American Chemical Society 20110921

• Lipase-catalyzed copolymerization of dialkyl carbonate with 1,4-butanediol and ω-pentadecalactone: synthesis of poly(ω-pentadecalactone-co-butylene-co-carbonate).

  Biomacromolecules 20110509

• Desymmetrization of (R,R)-hexa-1,5-diene-3,4-diol via monofunctionalization and rhodium-catalyzed allylic substitution.

  The Journal of organic chemistry 20110401

• Copper nanofiber-networked cobalt oxide composites for high performance Li-ion batteries.

  Nanoscale research letters 20110101

• Flowerlike vanadium sesquioxide: solvothermal preparation and electrochemical properties.

  Chemphyschem : a European journal of chemical physics and physical chemistry 20101025

• Theoretical investigations on oxidative stability of solvents and oxidative decomposition mechanism of ethylene carbonate for lithium ion battery use.

  The journal of physical chemistry. B 20091231

• Diethyl 2,6-dimethyl-pyridine-3,5-dicarboxyl-ate at 100 K.

  Acta crystallographica. Section E, Structure reports online 20091001

• Effects of solvents and salt on the thermal stability of lithiated graphite used in lithium ion battery.

  Journal of hazardous materials 20090815

• Effects of dimethyl or diethyl carbonate as an additive on volatility and flash point of an aviation fuel.

  Journal of hazardous materials 20090130

• Synthesis, structure, electrochemistry, and cytotoxic properties of ferrocenyl ester derivatives.

  Metal-based drugs 20090101

• Organic carbonates as alternative solvents for palladium-catalyzed substitution reactions.

  ChemSusChem 20080101

• Diethyl 2-tert-butyl-6,9-dibromo-4,11-dioxo-5,10-dihydro-cis-1H,3H,4H,11H-2-azo-3a,4a,10a,11a-tetra-aza-benz[f]indeno[2,1,7-ija]azulene-11b,11c-dicarboxyl-ate.

  Acta crystallographica. Section E, Structure reports online 20080101

• Synthesis of a new scaffold: the 7H,8H-pyrimido[1,6-b]pyridazin-6,8-dione nucleus.

  Molecules (Basel, Switzerland) 20071230

• Preferential intramolecular ring closure of aminoalcohols with diethyl carbonate to oxazolidinones.

  Chemical & pharmaceutical bulletin 20070501

• Direct Yellow and Methylene Blue liquid-liquid extraction with alkylene carbonates.

  Chemosphere 20050801

• Solvent decompositions and physical properties of decomposition compounds in Li-ion battery electrolytes studied by DFT calculations and molecular dynamics simulations.

  The journal of physical chemistry. B 20050224

• Enzymatic synthesis and chemical recycling of poly(carbonate-urethane).

  Macromolecular bioscience 20040809

• Nucleophilic substitution reactions of aryl N-phenyl thiocarbamates with benzylamines in acetonitrile.

  The Journal of organic chemistry 20040430

• An efficient synthesis of organic carbonates: atom economic protocol with a new catalytic system.

  Chemical communications (Cambridge, England) 20040321

• [Product analysis of oxo synthesis of diethyl carbonate by GC/MS].

  Se pu = Chinese journal of chromatography 20040301

• Ion-molecule interactions in solutions of lithium perchlorate in propylene carbonate + diethyl carbonate mixtures: an IR and molecular orbital study.

  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20020801

• Steryl and stanyl esters of fatty acids by solvent-free esterification and transesterification in vacuo using lipases from Rhizomucor miehei, Candida antarctica, and Carica papaya.

  Journal of agricultural and food chemistry 20011101

• [An IR study of ion solvation and association of lithium perchlorate in some organic solvents].

  Guang pu xue yu guang pu fen xi = Guang pu 20010801

• Comparison of pharmacophore cinnoline and quinoline systems on the basis of computer calculation and pharmacological screening of their condensed systems.

  Die Pharmazie 20010601