1121-66-0 | Cyclohept-2-en-1-one

Packsize	Purity	Availability	Price	Discounted Price
1g	90%	in stock	$25.00	$17.00
5g	90%	in stock	$30.00	$21.00
10g	90%	in stock	$55.00	$39.00
25g	90%	in stock	$126.00	$89.00
100g	90%	in stock	$503.00	$353.00

Description

• Catalog Number: AE08428
• Chemical Name: Cyclohept-2-en-1-one
• CAS Number: 1121-66-0
• Molecular Formula: C7H10O
• Molecular Weight: 110.1537
• MDL Number: MFCD00004157
• SMILES: C1CCC(=O)C=CC1
• NSC Number: 155333

Computed Properties

• Complexity: 114
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 8
• Hydrogen Bond Acceptor Count: 1
• XLogP3: 1.4

Literature

• Hydroxy-amide functionalized azolium salts for Cu-catalyzed asymmetric conjugate addition: stereocontrol based on ligand structure and copper precatalyst.

  The Journal of organic chemistry 20120420

• Hyperaromatic stabilization of arenium ions: cyclohexa- and cycloheptadienyl cations-experimental and calculated stabilities and ring currents.

  Journal of the American Chemical Society 20111214

• Reversal of stereoselectivity in the Cu-catalyzed conjugate addition reaction of dialkylzinc to cyclic enone in the presence of a chiral azolium compound.

  The Journal of organic chemistry 20100820

• [Development of new synthetic reactions featuring tandem carbon-carbon bond formation].

  Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan 20070901

• Analysis of a cycloheptenone derivative: an experimental and theoretical approach.

  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20060301

• Diastereoselective synthesis of five- and seven-membered rings by [2+2+1], [3+2], [3+2+2], and [4+3] carbocyclization reactions of beta-substituted (alkenyl)(methoxy)carbene complexes with methyl ketone lithium enolates.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20050819

• Diastereoselective synthesis of cycloheptadienol derivatives by a formal [5+2] carbocyclization reaction of alpha,beta,gamma,delta-diunsaturated (methoxy)carbene complexes with methyl ketone lithium enolates.

  Angewandte Chemie (International ed. in English) 20041018

• Urease inhibitory activity of simple alpha,beta-unsaturated ketones.

  Life sciences 20031024

• Mild, fast, and stereoselective epoxide opening by ketone enolate anions. Application to synthesis of the norlignan curculigine.

  The Journal of organic chemistry 20030418

• Highly enantioselective 1,4-addition of diorganozinc reagents to cyclic enones using chiral diphosphite ligands derived from H8-binaphthol.

  Organic letters 20021031

• Discovery of a new efficient chiral ligand for copper-catalyzed enantioselective Michael additions by high-throughput screening of a parallel library.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20010618