1129-30-2 | 2,6-Diacetylpyridine

Packsize	Purity	Availability	Price	Discounted Price
250mg	98%	in stock	$8.00	$5.00
1g	98%	in stock	$9.00	$6.00
5g	98%	in stock	$12.00	$9.00
10g	98%	in stock	$15.00	$11.00
25g	98%	in stock	$18.00	$13.00
100g	98%	in stock	$60.00	$42.00
500g	98%	in stock	$293.00	$206.00

Description

• Catalog Number: AB60571
• Chemical Name: 2,6-Diacetylpyridine
• CAS Number: 1129-30-2
• Molecular Formula: C9H9NO2
• Molecular Weight: 163.1733
• MDL Number: MFCD00006304
• SMILES: CC(=O)c1cccc(n1)C(=O)C
• NSC Number: 63355

Computed Properties

• Complexity: 181
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 12
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• XLogP3: 0.9

Upstream Synthesis Route

2,6-Diacetylpyridine is a versatile compound that finds wide applications in chemical synthesis. One of the key uses of this compound is as a building block in the preparation of various organic molecules. Its unique structure containing two acetyl functional groups attached to a pyridine ring allows for diverse chemical transformations, making it a valuable reagent in organic synthesis.In organic chemistry, 2,6-diacetylpyridine can be utilized as a starting material for the synthesis of complex molecules such as pharmaceuticals, agrochemicals, and specialty chemicals. Its acetyl groups can undergo reactions like nucleophilic substitution, acylation, and condensation, enabling the formation of new carbon-carbon and carbon-heteroatom bonds.Additionally, 2,6-diacetylpyridine can serve as a ligand in coordination chemistry, forming complexes with various metal ions. These complexes often display unique properties and reactivity, making them useful in catalysis and material science. The presence of the pyridine ring offers coordination sites for metal ions, leading to the formation of stable complexes with tailored properties for specific applications.Overall, 2,6-diacetylpyridine plays a crucial role in chemical synthesis by serving as a versatile building block and a ligand in the development of novel molecules and materials. Its diverse reactivity and structural features make it a valuable tool for organic and coordination chemists seeking to create and explore new compounds for various purposes.

Literature

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  Acta crystallographica. Section E, Structure reports online 20120201

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  Acta crystallographica. Section E, Structure reports online 20111201

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  Inorganic chemistry 20110620

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  Analytica chimica acta 20110318

• Complexation of nitrogen and sulphur donor Schiff's base ligand to Cr(III) and Ni(II) metal ions: synthesis, spectroscopic and antipathogenic studies.

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  Chemical communications (Cambridge, England) 20101014

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  Dalton transactions (Cambridge, England : 2003) 20100728

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  Acta crystallographica. Section E, Structure reports online 20100301

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• Applications of several spectral techniques to characterize coordination compounds derived from 2,6-diacetylpyridine derivative.

  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20090915

• Redox, thermodynamic and spectroscopic of some transition metal complexes containing heterocyclic Schiff base ligands.

  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20090915

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  Acta crystallographica. Section E, Structure reports online 20090701

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  Acta crystallographica. Section E, Structure reports online 20090501

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  Acta crystallographica. Section E, Structure reports online 20081201

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  Acta crystallographica. Section E, Structure reports online 20080601

• Bis(pyridinium) trans-tetrachlorido-dioxidouranate(VI) dioxane solvate.

  Acta crystallographica. Section E, Structure reports online 20080101

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  Acta crystallographica. Section E, Structure reports online 20080101

• Tricopper(II) complexes of unsymmetrical macrocycles incorporating phenol and pyridine moieties: the development of two stepwise routes.

  Dalton transactions (Cambridge, England : 2003) 20070928

• Versatility of 2,6-diacetylpyridine (dap) hydrazones in generating varied molecular architectures: synthesis and structural characterization of a binuclear double helical Zn(II) complex and a Mn(II) coordination polymer.

  Dalton transactions (Cambridge, England : 2003) 20070321

• Preconcentration and determination of trace elements with 2,6-diacetylpyridine functionalized Amberlite XAD-4 by flow injection and atomic spectroscopy.

  The Analyst 20051101

• Controlled ligand deprotonation in lanthanide chelates with asymmetric semicarbazone/benzoylhydrazone or semicarbazone/thiosemicarbazone coordination spheres.

  Inorganic chemistry 20050808

• Versatility of 2,6-diacetylpyridine (dap) hydrazones in stabilizing uncommon coordination geometries of Mn(II): synthesis, spectroscopic, magnetic and structural characterization.

  Dalton transactions (Cambridge, England : 2003) 20050721

• Pentacoordinated Cu(II)/Zn(II) complexes bearing macrocyclic skeleton: synthesis, spectroscopic and molecular structure optimization studies.

  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20050301

• Autocatalytic asymmetric reduction of 2,6-diacetylpyridine.

  Organic letters 20031016

• Nickel(II) 2,6-diacetylpyridine bis(isonicotinoylhydrazonate) and bis(benzoylhydrazonate) complexes: structure and antimycobacterial evaluation. Part XI.

  Bioorganic & medicinal chemistry 20010801