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Home  > Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)

AA14984

116128-29-1 | Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)

Packsize Purity Availability Price Discounted Price    Quantity
200mg 97% in stock $57.00 $40.00 -   +

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Description
Catalog Number: AA14984
Chemical Name: Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)
CAS Number: 116128-29-1
Molecular Formula: C52H46O4P2Ru
Molecular Weight: 897.9368
MDL Number: MFCD09753021
SMILES: Cc1ccc(cc1)P(c1ccc2c(c1c1c(ccc3c1cccc3)P(c1ccc(cc1)C)c1ccc(cc1)C)cccc2)c1ccc(cc1)C.[O-]C(=O)C.[O-]C(=O)C.[Ru+2]

 

Upstream Synthesis Route
  • The Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) complex is a versatile catalyst commonly employed in chemical synthesis. With its unique structure and properties, this catalyst plays a crucial role in facilitating various organic transformations.One prominent application of this ruthenium complex is in asymmetric hydrogenation reactions. Asymmetric hydrogenation is a key process in organic chemistry for the selective reduction of unsaturated compounds such as ketones, imines, and enamides. The Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) catalyst, with its chiral ligands, enables the synthesis of enantiomerically pure compounds, making it valuable in the production of pharmaceuticals, agrochemicals, and fine chemicals.Additionally, this ruthenium catalyst is utilized in carbon-carbon bond formation reactions, including asymmetric allylic substitutions and allylic alkylation. These transformations are vital in the construction of complex molecular structures with high stereocontrol, making the Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) catalyst a preferred choice for synthetic chemists aiming to access chiral compounds efficiently and selectively.
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