128-69-8 | 3,4,9,10-Perylenetetracarboxylic dianhydride

Packsize	Purity	Availability	Price	Discounted Price
10g	98%	in stock	$12.00	$8.00
25g	98%	in stock	$18.00	$12.00
100g	98%	in stock	$42.00	$29.00

Description

• Catalog Number: AB44309
• Chemical Name: 3,4,9,10-Perylenetetracarboxylic dianhydride
• CAS Number: 128-69-8
• Molecular Formula: C24H8O6
• Molecular Weight: 392.3167
• MDL Number: MFCD00006916
• SMILES: O=C1OC(=O)c2c3c1ccc1c3c(cc2)c2c3c1ccc1c3c(cc2)C(=O)OC1=O
• NSC Number: 79895

Computed Properties

• Complexity: 730
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 30
• Hydrogen Bond Acceptor Count: 6
• XLogP3: 4.5

Upstream Synthesis Route

Perylene-3,4,9,10-tetracarboxylic dianhydride, commonly known as PTCDA, is a versatile compound widely used in chemical synthesis. This molecule plays a crucial role as an intermediate in the synthesis of various organic materials and polymers. Particularly in the field of organic electronics, PTCDA is utilized as a building block for organic semiconductors due to its unique properties.In chemical synthesis, PTCDA is often employed as a precursor for the production of functional organic materials such as conducting polymers, photovoltaic devices, and light-emitting diodes. Its rigid polycyclic structure and electron-accepting nature make it a valuable component for constructing conjugated systems with enhanced electronic properties.Moreover, PTCDA is known for its ability to form ordered molecular assemblies, making it an essential tool for creating thin films and nanostructures with tailored optoelectronic properties. By controlling the deposition techniques and conditions, researchers can harness the self-assembly behavior of PTCDA to fabricate thin films with specific morphologies and functionalities.Overall, the application of Perylene-3,4,9,10-tetracarboxylic dianhydride in chemical synthesis offers a pathway to design and develop novel organic materials with applications in electronics, photonics, and material science. Its versatility and compatibility with various synthetic strategies make it a valuable ingredient in the toolbox of organic chemists and materials scientists seeking to explore the frontiers of molecular design and functional material development.

Literature

• Supramolecular ordering of PTCDA molecules: the key role of dispersion forces in an unusual transition from physisorbed into chemisorbed state.

  ACS nano 20121023

• Improved efficiency of organic/inorganic hybrid near-infrared light upconverter by device optimization.

  ACS applied materials & interfaces 20120926

• Comparison of the electronic structure of different perylene-based dye-aggregates.

  Journal of computational chemistry 20120705

• 3,4,9,10-Perylenetetracarboxylic dianhydride functionalized graphene sheet as labels for ultrasensitive electrochemiluminescent detection of thrombin.

  Analytica chimica acta 20120513

• Two-photon fluorescence microscopy imaging of cellular oxidative stress using profluorescent nitroxides.

  Journal of the American Chemical Society 20120314

• Commensurate registry and chemisorption at a hetero-organic interface.

  Physical review letters 20120309

• Understanding dissipative tip-molecule interactions with submolecular resolution on an organic adsorbate.

  Small (Weinheim an der Bergstrasse, Germany) 20120220

• Transient grating studies of femtosecond processes in ultra-thin layers of PTCDA.

  Chemphyschem : a European journal of chemical physics and physical chemistry 20120201

• Different interface orientations of pentacene and PTCDA induce different degrees of disorder.

  Nanoscale research letters 20120101

• Modeling intermolecular interactions of physisorbed organic molecules using pair potential calculations.

  The Journal of chemical physics 20111221

• Charge transfer dynamics of 3,4,9,10-perylene-tetracarboxylic-dianhydride molecules on Au(111) probed by resonant photoemission spectroscopy.

  The Journal of chemical physics 20111107

• Chemical reaction mediated self-assembly of PTCDA into nanofibers.

  Nanoscale 20110901

• PTCDA on Cu(111) partially covered with NaCl.

  Nanotechnology 20110722

• Seeding atomic layer deposition of high-k dielectrics on epitaxial graphene with organic self-assembled monolayers.

  ACS nano 20110628

• High dispersion of platinum-ruthenium nanoparticles on the 3,4,9,10-perylene tetracarboxylic acid-functionalized carbon nanotubes for methanol electro-oxidation.

  Chemical communications (Cambridge, England) 20110514

• A novel solid-state electrochemiluminescence detector for capillary electrophoresis based on tris(2,2'-bipyridyl)ruthenium(II) immobilized in Nafion/PTC-NH2 composite film.

  Talanta 20110415

• Recent advances in submolecular resolution with scanning probe microscopy.

  Nature chemistry 20110401

• Nanofabrication of heteromolecular organic nanostructures on epitaxial graphene via room temperature feedback-controlled lithography.

  Nano letters 20110209

• Vibronic line shapes of PTCDA oligomers in helium nanodroplets.

  The Journal of chemical physics 20110207

• Formation of organic crystalline nanopillar arrays and their application to organic photovoltaic cells.

  ACS applied materials & interfaces 20110101

• STM-induced light emission from thin films of perylene derivatives on the HOPG and Au substrates.

  Nanoscale research letters 20110101

• Analytical model for the photocurrent-voltage characteristics of bilayer MEH-PPV/TiO2 photovoltaic devices.

  Nanoscale research letters 20110101

• Intermolecular vs molecule-substrate interactions: A combined STM and theoretical study of supramolecular phases on graphene/Ru(0001).

  Beilstein journal of nanotechnology 20110101

• Reversible bond formation in a gold-atom-organic-molecule complex as a molecular switch.

  Physical review letters 20101231

• Delocalized π state between molecules through a surface confined pseudodihydrogen bond.

  Physical review letters 20101126

• Alkali metal doped organic molecules on insulators: charge impact on the optical properties.

  Advanced materials (Deerfield Beach, Fla.) 20100922

• Structural templating of multiple polycrystalline layers in organic photovoltaic cells.

  Optics express 20100913

• Direct imaging of intermolecular bonds in scanning tunneling microscopy.

  Journal of the American Chemical Society 20100901

• Metal-organic extended 2D structures: Fe-PTCDA on Au(111).

  Nanotechnology 20100730

• Tailoring two-dimensional PTCDA-melamine self-assembled architectures at room temperature by tuning molecular ratio.

  Nanotechnology 20100423

• Relationship between crystalline order and exciton diffusion length in molecular organic semiconductors.

  Advanced materials (Deerfield Beach, Fla.) 20100319

• Solubilized derivatives of perylenetetracarboxylic dianhydride (PTCDA) adsorbed on highly oriented pyrolytic graphite.

  Langmuir : the ACS journal of surfaces and colloids 20100316

• The role of van der Waals interactions in surface-supported supramolecular networks.

  Physical chemistry chemical physics : PCCP 20100128

• Structural and electronic properties of PTCDA thin films on epitaxial graphene.

  ACS nano 20091124

• Ultra-sensitive fluorescence spectroscopy of isolated surface-adsorbed molecules using an optical nanofiber.

  Optics express 20091123

• Magneto-optical Kerr effect spectroscopy--a sensitive tool for investigating the molecular orientation in organic semiconductor films.

  The journal of physical chemistry. B 20091112

• Line-on-line organic-organic heteroepitaxy of quaterrylene on hexa-peri-hexabenzocoronene on Au(111).

  Langmuir : the ACS journal of surfaces and colloids 20091103

• Electronic structure at the perylene-tetracarboxylic acid dianhydride/Ag(111) interface studied with two-photon photoelectron spectroscopy.

  The Journal of chemical physics 20091014

• Gas phase and bulk ultraviolet photoemission spectroscopy of 3,4,9,10-perylene-tetracarboxylic dianhydride, 1,4,5,8-naphthalene-tetracarboxylic dianhydride, and 1,8-naphthalene-dicarboxylic anhydride.

  The Journal of chemical physics 20090721

• Submolecular features of epitaxially grown PTCDA on Cu(111) analyzed by force field spectroscopy.

  Nanotechnology 20090701

• Determination of the local contact potential difference of PTCDA on NaCl: a comparison of techniques.

  Nanotechnology 20090701

• Surface assembly: Graphene goes undercover.

  Nature chemistry 20090601

• Room-temperature molecular-resolution characterization of self-assembled organic monolayers on epitaxial graphene.

  Nature chemistry 20090601

• Molecular imaging of polyimide formation.

  Physical chemistry chemical physics : PCCP 20090227

• Enhanced photoelectrochemical detection of bioaffinity reactions by vertically oriented au nanobranches complexed with a biotinylated polythiophene derivative.

  Sensors (Basel, Switzerland) 20090101

• Nanofabrication of PTCDA molecular chains on rutile TiO(2)(011)-(2 × 1) surfaces.

  Nanotechnology 20081210

• PTCDA molecules on a KBr/InSb system: a low temperature STM study.

  Nanotechnology 20081126

• Self-assembled monolayers of a bis(pyrazol-1-yl)pyridine-substituted thiol on Au(111).

  Langmuir : the ACS journal of surfaces and colloids 20081118

• Fabrication of surface-supported low-dimensional polyimide networks.

  Journal of the American Chemical Society 20081029

• Electron lifetime in a Shockley-type metal-organic interface state.

  Physical review letters 20081003

• Two-dimensional pentacene:3,4,9,10-perylenetetracarboxylic dianhydride supramolecular chiral networks on Ag(111).

  Journal of the American Chemical Society 20080917

• Luminescence from 3,4,9,10-perylenetetracarboxylic dianhydride on Ag(111) surface excited by tunneling electrons in scanning tunneling microscopy.

  The Journal of chemical physics 20080707

• Strain induced dewetting of a molecular system: bimodal growth of PTCDA on NaCl.

  Physical review letters 20080509

• High resolution LT-STM imaging of PTCDA molecules assembled on an InSb(001) c(8 × 2) surface.

  Nanotechnology 20080507

• Role of intermolecular interactions on the electronic and geometric structure of a large pi-conjugated molecule adsorbed on a metal surface.

  Physical review letters 20080404

• Nanostructured conductive material containing ferrocenyl for reagentless amperometric immunosensors.

  Biomaterials 20080401

• Temperature dependence of the energy dissipation in dynamic force microscopy.

  Nanotechnology 20080130

• Ultra-sensitive surface absorption spectroscopy using sub-wavelength diameter optical fibers.

  Optics express 20070917

• Interaction of alkali metals with perylene-3,4,9,10-tetracarboxylic-dianhydride thin films studied by IR spectroscopy.

  The Journal of chemical physics 20070428

• PTCDA molecules on an InSb(001) surface studied with atomic force microscopy.

  Nanotechnology 20070404

• Ballistic electron microscopy of individual molecules.

  Science (New York, N.Y.) 20070330

• Selective nontemplated adsorption of organic molecules on nanofacets and the role of bonding patterns.

  Physical review letters 20061013

• Photophysics of PTCDA and Me-PTCDI thin films: effects of growth temperature.

  The journal of physical chemistry. B 20060406

• Two-dimensional simulations of CuPc-PCTDA solar cells: the importance of mobility and molecular pi stacking.

  The journal of physical chemistry. B 20060216

• Fabrication of fluorescent nanotubes based on layer-by-layer assembly via covalent bond.

  Langmuir : the ACS journal of surfaces and colloids 20060103

• A comparison of fine structures in high-resolution x-ray-absorption spectra of various condensed organic molecules.

  The Journal of chemical physics 20050722

• Charge recombination in CuPc/PTCDA thin films.

  The journal of physical chemistry. B 20050616

• Laser-induced fluorescence spectroscopy of N,N'-dimethyl 3,4,9,10-perylene tetracarboxylic diimide monomers and oligomers attached to helium nanodroplets.

  Physical chemistry chemical physics : PCCP 20050321

• Molecular distortions and chemical bonding of a large pi-conjugated molecule on a metal surface.

  Physical review letters 20050128

• Line shapes and satellites in high-resolution x-ray photoelectron spectra of large pi-conjugated organic molecules.

  The Journal of chemical physics 20041122

• Laser-induced fluorescence spectroscopy of 3,4,9,10-perylenetetracarboxylic-dianhydrid in helium nanodroplets.

  The Journal of chemical physics 20040115