13991-08-7 | 1,2-Bis(diphenylphosphino)benzene

Packsize	Purity	Availability	Price	Discounted Price
250mg	97%	in stock	$11.00	$8.00
1g	≥95%	in stock	$15.00	$10.00
5g	97%	in stock	$29.00	$20.00
10g	95%	in stock	$31.00	$22.00
15g	95%	in stock	$46.00	$32.00
25g	95%	in stock	$75.00	$53.00
50g	95%	in stock	$149.00	$105.00
100g	95%	in stock	$281.00	$197.00

Description

• Catalog Number: AA61755
• Chemical Name: 1,2-Bis(diphenylphosphino)benzene
• CAS Number: 13991-08-7
• Molecular Formula: C30H24P2
• Molecular Weight: 446.4591
• MDL Number: MFCD00014081
• SMILES: c1ccc(c(c1)P(c1ccccc1)c1ccccc1)P(c1ccccc1)c1ccccc1

Computed Properties

• Complexity: 439
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 32
• Rotatable Bond Count: 6
• XLogP3: 7.3

Literature

• Rhodium-catalyzed synthesis of diaryl sulfides using aryl fluorides and sulfur/organopolysulfides.

  Organic letters 20121019

• Photoluminescence properties, molecular structures, and theoretical study of heteroleptic silver(I) complexes containing diphosphine ligands.

  Inorganic chemistry 20120521

• Dual luminescent tetranuclear organogold(I) macrocycles of 5,5'-diethynyl-2,2'-bipyridine and their efficient sensitization of Yb(III) luminescence.

  Inorganic chemistry 20120102

• Bis(imidate)palladium(II) complexes with labile ligands. Mimics of classical precursors?

  Dalton transactions (Cambridge, England : 2003) 20111221

• Conjugate reduction and reductive aldol cyclization of α,β-unsaturated thioesters catalyzed by (BDP)CuH.

  Organic & biomolecular chemistry 20110907

• Vapochromic and mechanochromic tetrahedral gold(I) complexes based on the 1,2-bis(diphenylphosphino)benzene ligand.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20101025

• Brilliant reversible luminescent mechanochromism of silver(I) complexes containing o-bis(diphenylphosphino)benzene and phosphinesulfide.

  Chemical communications (Cambridge, England) 20100321

• Luminescent mononuclear Ag(I)-bis(diphosphine) complexes: correlation between the photophysics and the structures of mononuclear Ag(I)-bis(diphosphine) complexes.

  Inorganic chemistry 20100201

• Vicinal diphosphoniums: electrostatic repulsion under covalent constraint.

  Dalton transactions (Cambridge, England : 2003) 20091028

• Iron-catalysed fluoroaromatic coupling reactions under catalytic modulation with 1,2-bis(diphenylphosphino)benzene.

  Chemical communications (Cambridge, England) 20090314

• Iron-catalysed Negishi coupling of benzyl halides and phosphates.

  Chemical communications (Cambridge, England) 20090207

• Photochemistry and photophysics of the tetrahedral silver(I) complex with diphosphine ligands: [Ag(dppb)2]PF6 (dppb = 1, 2-bis[diphenylphosphino]benzene).

  Chemical communications (Cambridge, England) 20081221

• Rhodium-catalyzed substitution reaction of aryl fluorides with disulfides: p-orientation in the polyarylthiolation of polyfluorobenzenes.

  Journal of the American Chemical Society 20080917

• Kinetic and high-pressure mechanistic investigation of the aqua substitution in the trans-aquaoxotetracyano complexes of re(v) and tc(v): some implications for nuclear medicine.

  Metal-based drugs 20080101

• Alkyl carbon-nitrogen reductive elimination from platinum(IV)-sulfonamide complexes.

  Journal of the American Chemical Society 20070829

• Photophysical properties of highly luminescent copper(I) halide complexes chelated with 1,2-bis(diphenylphosphino)benzene.

  Inorganic chemistry 20070319

• 1,2-Bis(diphenylphosphino)benzene and two related mono-methiodides, [o-C(6)H(4)(PR(2))(PR(2)Me)]I (R = Ph or Me).

  Acta crystallographica. Section C, Crystal structure communications 20060701

• Mechanistic information on the reductive elimination from cationic trimethylplatinum(IV) complexes to form carbon-carbon bonds.

  Inorganic chemistry 20051031

• Phosphine coordination complexes of the diphenylphosphenium cation: a versatile synthetic methodology for P-P bond formation.

  Journal of the American Chemical Society 20031126

• Synthesis, characterization, and reactivity of arylpalladium cyanoalkyl complexes: selection of catalysts for the alpha-arylation of nitriles.

  Journal of the American Chemical Society 20020814

• Studies of reductive elimination reactions to form carbon-oxygen bonds from Pt(IV) complexes.

  Journal of the American Chemical Society 20010321