140681-55-6 | 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)

Packsize	Purity	Availability	Price	Discounted Price
250mg	98%	in stock	$6.00	$4.00
500mg	98%	in stock	$8.00	$5.00
1g	98%	in stock	$9.00	$6.00
5g	98%	in stock	$10.00	$7.00
25g	98%	in stock	$20.00	$14.00
100g	98%	in stock	$29.00	$20.00
250g	98%	in stock	$36.00	$25.00
500g	98%	in stock	$68.00	$47.00

Description

• Catalog Number: AA62878
• Chemical Name: 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)
• CAS Number: 140681-55-6
• Molecular Formula: C7H14B2ClF9N2
• Molecular Weight: 354.2601
• MDL Number: MFCD00142607
• SMILES: F[B+](F)(F)F.F[B+](F)(F)F.ClC[N+]12CC[N+](CC1)(CC2)F

Computed Properties

• Complexity: 168
• Covalently-Bonded Unit Count: 3
• Heavy Atom Count: 21
• Hydrogen Bond Acceptor Count: 11
• Rotatable Bond Count: 1

Literature

• Gold-catalyzed simultaneous formation of C-C, C═O, and C-F bonds in the presence of Selectfluor: a synthesis of fluoroindenes from allene esters.

  The Journal of organic chemistry 20120615

• Radiosynthesis and evaluation of [18F]Selectfluor bis(triflate).

  Angewandte Chemie (International ed. in English) 20100910

• Study on the selectivity in the electrophilic monofluorination of 2,3-allenoates with Selectfluor: an efficient synthesis of 4-fluoro-2(5H)-furanones and 3-fluoro-4-oxo-2(E)-alkenoates.

  Organic & biomolecular chemistry 20100107

• Transformations of organic molecules with F-TEDA-BF4 in ionic liquid media.

  Molecules (Basel, Switzerland) 20090706

• An efficient approach for monofluorination via highly regioselective fluorohydroxylation reaction of 3-aryl-1,2-allenes with Selectfluor.

  Organic letters 20080221

• Enantioselective alpha-fluorination of carbonyl compounds: organocatalysis or metal catalysis?

  Angewandte Chemie (International ed. in English) 20060116

• Quinine/selectfluor combination induced asymmetric semipinacol rearrangement of allylic alcohols: an effective and enantioselective approach to alpha-quaternary beta-fluoro aldehydes.

  Chemical communications (Cambridge, England) 20051128

• gem-Difluorination of 2,2-diaryl-1,3-dithiolanes by Selectfluor and pyridinium polyhydrogen fluoride.

  Chemical communications (Cambridge, England) 20050207

• Recent highlights in electrophilic fluorination with 1-chloromethyl-4-fluoro- 1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate).

  Accounts of chemical research 20040101

• The synthesis and characterization of BMS-204352 (MaxiPost) and related 3-fluorooxindoles as openers of maxi-K potassium channels.

  Bioorganic & medicinal chemistry letters 20020408

• Selectfluor F-TEDA-BF4 mediated and solvent directed iodination of aryl alkyl ketones using elemental iodine.

  Chemical communications (Cambridge, England) 20020307