14243-64-2 | Chloro(triphenylphosphine)gold(i)

Packsize	Purity	Availability	Price	Discounted Price
100mg	98%	in stock	$20.00	$14.00
250mg	98%	in stock	$23.00	$16.00
1g	98%	in stock	$76.00	$53.00
2.5g	98%	in stock	$186.00	$130.00
5g	98%	in stock	$345.00	$241.00

Description

• Catalog Number: AI35055
• Chemical Name: Chloro(triphenylphosphine)gold(i)
• CAS Number: 14243-64-2
• Molecular Formula: C18H15AuClP
• Molecular Weight: 494.7050
• MDL Number: MFCD00009588
• SMILES: c1ccc(cc1)P(c1ccccc1)c1ccccc1.[Au]Cl

Computed Properties

• Complexity: 204
• Covalently-Bonded Unit Count: 2
• Heavy Atom Count: 21
• Rotatable Bond Count: 3

Upstream Synthesis Route

Chloro(triphenylphosphine)gold(I) is a highly versatile and valuable reagent in chemical synthesis. Its unique properties make it particularly useful in various organic transformations, enabling chemists to access a wide range of important chemical compounds.One of the key applications of Chloro(triphenylphosphine)gold(I) is in catalysis. It is commonly employed as a catalyst in a variety of reactions, such as carbon-carbon bond formations, oxidative additions, and cycloadditions. Its ability to activate unsaturated bonds and facilitate complex rearrangements makes it a powerful tool for streamlining synthetic pathways and achieving high yields of desired products.Furthermore, Chloro(triphenylphosphine)gold(I) plays a crucial role in promoting selective transformations. Its presence can lead to regioselective and stereoselective outcomes in reactions, allowing chemists to control the orientation of bond formations and obtain specific chiral products with high efficiency.Overall, Chloro(triphenylphosphine)gold(I) serves as a remarkable agent in chemical synthesis, offering chemists a reliable and effective way to access diverse chemical structures and accomplish complex synthetic challenges.

Literature

• Efficient synthesis of β-enaminones and β-enaminoesters catalyzed by gold (I)/silver (I) under solvent-free conditions.

  Molecules (Basel, Switzerland) 20120306

• Au(PPh(3))Cl-AgSbF(6)-catalyzed rearrangement of propargylic 1,3-dithianes: formation of 8-membered 1,3-bisthio-substituted cyclic allenes.

  Chemical communications (Cambridge, England) 20090514

• Synthesis, structure and cytotoxicity of triphenylphosphinegold(I) sulfanylpropenoates.

  Journal of inorganic biochemistry 20080201

• A powerful chiral counterion strategy for asymmetric transition metal catalysis.

  Science (New York, N.Y.) 20070727

• Sublethal concentrations of diverse gold compounds inhibit mammalian cytosolic thioredoxin reductase (TrxR1).

  Toxicology in vitro : an international journal published in association with BIBRA 20060901

• A mass spectrometric investigation of the binding of gold antiarthritic agents and the metabolite [Au(CN)2]- to human serum albumin.

  Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 20060701