144026-79-9 | Scandium(iii) trifluoromethanesulfonate

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Description

• Catalog Number: AA70864
• Chemical Name: Scandium(iii) trifluoromethanesulfonate
• CAS Number: 144026-79-9
• Molecular Formula: C3F9O9S3Sc
• Molecular Weight: 492.1632
• MDL Number: MFCD00798539
• SMILES: FC(S(=O)(=O)[O-])(F)F.FC(S(=O)(=O)[O-])(F)F.FC(S(=O)(=O)[O-])(F)F.[Sc+3]

Computed Properties

• Complexity: 145
• Covalently-Bonded Unit Count: 4
• Heavy Atom Count: 25
• Hydrogen Bond Acceptor Count: 18

Literature

• Lewis acid trapping of an elusive copper-tosylnitrene intermediate using scandium triflate.

  Journal of the American Chemical Society 20120912

• Catalytic asymmetric sulfenylation of unprotected 3-substituted oxindoles.

  Organic letters 20120601

• Sc(OTf)3-catalyzed synthesis of indoles and SnCl4-mediated regioselective hydrochlorination of 5-(arylamino)pent-3-yn-2-ones.

  The Journal of organic chemistry 20111021

• Chiral Sc-catalyzed asymmetric Michael reactions of thiols with enones in water.

  Organic & biomolecular chemistry 20110521

• Efficient conversion of triacylglycerols and fatty acids to biodiesel in a microwave reactor using metal triflate catalysts.

  Organic & biomolecular chemistry 20101021

• Highly enantioselective synthesis of alpha-stereogenic esters through catalytic asymmetric michael addition of 4-oxo-4-arylbutenoates.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20100903

• Scandium triflate-catalyzed one-pot domino approach towards general and efficient syntheses of unsymmetrical 9-substituted xanthene derivatives.

  Organic & biomolecular chemistry 20100307

• Selective heteronuclear Hartmann-Hahn: a multiple-pulse sequence for selective magnetization transfer in the structural elucidation of 'isotagged' oligosaccharides.

  Journal of magnetic resonance (San Diego, Calif. : 1997) 20100301

• Biomimetic synthesis of a new class of bacterial signaling molecules.

  Organic letters 20090716

• Sc(OTf)(3)-catalyzed condensation of 2-alkyl-N-tosylaziridine with aldehydes or ketones: an efficient synthesis of 5-alkyl-1,3-oxazolidines.

  Chemical communications (Cambridge, England) 20090714

• Alpha-sulfanyl and alpha-selanyl propadienyl cations: regioselective generations and cycloadditions with thioamides and selemides controlled by MeNO2-H2O system.

  Organic letters 20090702

• Sc(OTf)3-catalyzed or t-BuOK promoted tandem reaction of 2-(2-(alkynyl)benzylidene)malonate with indole.

  Organic letters 20080605

• Sc(OTf)3-mediated silylation of hydroxy functional groups on a solid surface: a catalytic grafting method operating at room temperature.

  Angewandte Chemie (International ed. in English) 20080101

• Asymmetric Friedel-Crafts alkylation of indoles with methyl (E)-2-oxo-4-aryl-3-butenoates catalyzed by Sc(OTf)3/pybox.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

• Enantioselective Friedel-Crafts alkylations catalyzed by bis(oxazolinyl)pyridine-scandium(III) triflate complexes.

  Journal of the American Chemical Society 20070815

• Highly diastereoselective synthesis of beta-carboxy-gamma-lactams and their ethyl esters via Sc(OTf)(3)-catalyzed imino Mukaiyama-aldol type reaction of 2,5-bis(trimethylsilyloxy)furan with imines.

  The Journal of organic chemistry 20070622

• First catalytic and green synthesis of aryl-(Z)-vinyl chlorides and its plausible addition-elimination mechanism.

  Organic letters 20070315

• Mild reductive opening of aryl pyranosides promoted by scandium(III) triflate.

  Journal of the American Chemical Society 20070110

• Direct C-glycosylation of indole with unprotected mono-, di-, and trisaccharides: a one-pot synthesis of 1-deoxy-1,1-bis(3-indolyl)alditols.

  Carbohydrate research 20061127

• Catalytic enantioselective and diastereoselective addition of aldehyde-derived enecarbamates to alpha-oxo aldehydes.

  Angewandte Chemie (International ed. in English) 20060602

• Scandium triflate catalyzed cycloaddition of imines with 1,1-cyclopropanediesters: efficient and diastereoselective synthesis of multi-substituted pyrrolidines.

  Organic & biomolecular chemistry 20060121

• Catalytic asymmetric ring opening of meso-epoxides with aromatic amines in water.

  Organic letters 20051013

• Enantioselective indole Friedel--Crafts alkylations catalyzed by bis(oxazolinyl)pyridine-scandium(III) triflate complexes.

  Journal of the American Chemical Society 20030910

• Highly enantioselective 1,3-dipolar cycloaddition reactions of 2-benzopyrylium-4-olate catalyzed by chiral Lewis acids.

  Journal of the American Chemical Society 20021218

• Scandium(III) trifluoromethanesulfonate catalyzed aromatic nitration with inorganic nitrates and acetic anhydride.

  Chemical & pharmaceutical bulletin 20020801

• Direct formation of N-acylated amino acid derivatives via nucleophilic addition to N-acylimino esters using a polymer-supported amine and scandium triflate.

  Journal of combinatorial chemistry 20010101