15206-55-0 | Methyl benzoylformate

Packsize	Purity	Availability	Price	Discounted Price
10g	97%	in stock	$6.00	$4.00
25g	97%	in stock	$12.00	$8.00
100g	97%	in stock	$38.00	$26.00
500g	97%	in stock	$108.00	$75.00

Description

• Catalog Number: AB76036
• Chemical Name: Methyl benzoylformate
• CAS Number: 15206-55-0
• Molecular Formula: C9H8O3
• Molecular Weight: 164.158
• MDL Number: MFCD00008443
• SMILES: COC(=O)C(=O)c1ccccc1

Computed Properties

• Complexity: 180
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 12
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• XLogP3: 1.7

Literature

• The first case of competitive heterogeneously catalyzed enantioselective hydrogenation of ketones.

  Chemical communications (Cambridge, England) 20110207

• Integration of newly isolated biocatalyst and resin-based in situ product removal technique for the asymmetric synthesis of (R)-methyl mandelate.

  Bioprocess and biosystems engineering 20100901

• Mechanistic insights on the magnesium(II) ion-activated reduction of methyl benzoylformate with chelated NADH peptide beta-lactam models.

  The Journal of organic chemistry 20090904

• [Overview of 40 years' chemical study].

  Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan 20090101

• Exploiting nanospace for asymmetric catalysis: confinement of immobilized, single-site chiral catalysts enhances enantioselectivity.

  Accounts of chemical research 20080601

• N-methyl-(R)-3-(tert-butyl)-sulfinyl-1,4-dihydropyridine: a novel NADH model compound.

  Molecules (Basel, Switzerland) 20070312

• Unusual temperature dependence of enantioselectivity in asymmetric reductions by chiral NADH models.

  Organic letters 20060511

• Amine degradation by 4,5-epoxy-2-decenal in model systems.

  Journal of agricultural and food chemistry 20060322

• Synthesis, properties, and oxidizing ability of areno-annulated 1,3-dimethyl-10-phenylcyclohepta[4,5]pyrrolo[2,3-d]pyrimidine- 2,4(1,3H)-dionylium ions.

  The Journal of organic chemistry 20060106

• Ru-Catalyzed asymmetric hydrogenation of alpha-ketoesters with CeCl3.7H2O as additive.

  Organic letters 20051124

• Stereoselective generation of vicinal stereogenic quaternary centers by photocycloaddition of 5-methoxy oxazoles to alpha-keto esters: synthesis of erythro beta-hydroxy dimethyl aspartates.

  Organic & biomolecular chemistry 20040421

• Constraining asymmetric organometallic catalysts within mesoporous supports boosts their enantioselectivity.

  Journal of the American Chemical Society 20031210

• Atropoisomeric quinolinium salt promoting the access to both enantiomeric forms of methyl mandelate: a versatile NADH mimic.

  Chemical communications (Cambridge, England) 20021007

• The [2+2]-photocycloaddition of aromatic aldehydes and ketones to 3,4-dihydro-2-pyridones: regioselectivity, diastereoselectivity, and reductive ring opening of the product oxetanes.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20011015