159-66-0 | 9,9'-Spirobifluorene

Packsize	Purity	Availability	Price	Discounted Price
1g	97%	in stock	$16.00	$11.00
5g	97%	in stock	$20.00	$14.00
25g	97%	in stock	$86.00	$60.00
100g	97%	in stock	$249.00	$175.00
500g	97%	in stock	$1,022.00	$716.00

Description

• Catalog Number: AA81572
• Chemical Name: 9,9'-Spirobifluorene
• CAS Number: 159-66-0
• Molecular Formula: C25H16
• Molecular Weight: 316.39454000000006
• MDL Number: MFCD08704216
• SMILES: c1ccc2-c3c(C4(c2c1)c1ccccc1-c1c4cccc1)cccc3

Computed Properties

• Complexity: 413
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 25
• XLogP3: 6.4

Literature

• New dibenzofuran/spirobifluorene hybrids as thermally stable host materials for efficient phosphorescent organic light-emitting diodes with low efficiency roll-off.

  Physical chemistry chemical physics : PCCP 20121107

• Electroluminescence based on thermally activated delayed fluorescence generated by a spirobifluorene donor-acceptor structure.

  Chemical communications (Cambridge, England) 20121007

• Efficient greenish blue electrochemiluminescence from fluorene and spirobifluorene derivatives.

  Journal of the American Chemical Society 20120919

• Perylenetetracarboxylic diimide derivatives linked with spirobifluorene.

  Organic letters 20120615

• Spirobifluorene bridged Ir(III) and Os(II) polypyridyl arrays: synthesis, photophysical characterization, and energy transfer dynamics.

  Inorganic chemistry 20120305

• Electrochemistry and electrogenerated chemiluminescence of a spirobifluorene-based donor (triphenylamine)-acceptor (2,1,3-benzothiadiazole) molecule and its organic nanoparticles.

  Journal of the American Chemical Society 20110413

• Synthesis of a highly luminescent three-dimensional pyrene dye based on the spirobifluorene skeleton.

  Molecules (Basel, Switzerland) 20101028

• Micropore analysis of polymer networks by gas sorption and 129Xe NMR spectroscopy: toward a better understanding of intrinsic microporosity.

  Langmuir : the ACS journal of surfaces and colloids 20101005

• Exploring the effects of solvent polarity on the rate of Förster-type electronic energy transfer in a closely-spaced molecular dyad.

  Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology 20100730

• Nanostructured poly(benzimidazole): from mesoporous networks to nanofibers.

  ChemSusChem 20100222

• Morphological stable spirobifluorene/oxadiazole hybrids as bipolar host materials for efficient green and red electrophosphorescence.

  Chemistry, an Asian journal 20100201

• Amplified spontaneous emission properties of semiconducting organic materials.

  International journal of molecular sciences 20100101

• Theoretical study on photophysical properties of ambipolar spirobifluorene derivatives as efficient blue-light-emitting materials.

  The journal of physical chemistry. A 20090709

• 2,2',7,7'-Tetra-bromo-9,9'-spiro-bifluorene toluene hemisolvate.

  Acta crystallographica. Section E, Structure reports online 20090701

• The complex excited-state behavior of a polyspirobifluorene derivative: the role of spiroconjugation and mixed charge transfer character on excited-state stabilization and radiative lifetime.

  The journal of physical chemistry. B 20081225

• Synthesis and electrochemical properties of peripheral carbazole functional Ter(9,9-spirobifluorene)s.

  The Journal of organic chemistry 20080606

• Toward stable interfaces in conjugated polymers: microporous poly(p-phenylene) and poly(phenyleneethynylene) based on a spirobifluorene building block.

  Journal of the American Chemical Society 20080521

• Chiral diphosphine and monodentate phosphorus ligands on a spiro scaffold for transition-metal-catalyzed asymmetric reactions.

  Accounts of chemical research 20080501

• Electrogenerated chemiluminescence of a spirobifluorene-linked bisanthracene: a possible simultaneous, two-electron transfer.

  Journal of the American Chemical Society 20080416

• Electrochemistry and electrogenerated chemiluminescence of 3,6-di(spirobifluorene)-N-phenylcarbazole.

  Journal of the American Chemical Society 20080116

• Dispirofluorene-indenofluorene derivatives as new building blocks for blue organic electroluminescent devices and electroactive polymers.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20070101

• Dispirofluorene-indenofluorene (DSFIF): synthesis, electrochemical, and optical properties of a promising new family of luminescent materials.

  Organic letters 20060119

• Deformation of a 'rigid' molecule in self-assembled nanostructures.

  The journal of physical chemistry. B 20051222

• Electrode surface modification by a spirobifluorene derivative. An XPS and electrochemical investigation.

  The journal of physical chemistry. B 20051006

• Improved synthesis of 2,2'-dibromo-9,9'-spirobifluorene and its 2,2'-bisdonor-7,7'-bisacceptor-substituted fluorescent derivatives.

  Organic letters 20050818

• Efficient upconversion fluorescence in a blue-emitting spirobifluorene-anthracene copolymer doped with low concentrations of Pt(II)octaethylporphyrin.

  The Journal of chemical physics 20050815

• Tailoring the mobility of a 3D molecule adsorbed on a metal surface.

  The journal of physical chemistry. B 20050804

• A new polymorph and two inclusion compounds of 9,9'-spirobifluorene.

  Acta crystallographica. Section C, Crystal structure communications 20050501

• Highly rigid diphosphane ligands with a large dihedral angle based on a chiral spirobifluorene backbone.

  Angewandte Chemie (International ed. in English) 20050204

• pi-Conjugated twin molecules based on truxene: synthesis and optical properties.

  Organic letters 20041223

• Molecular tectonics. Porous hydrogen-bonded networks built from derivatives of 9,9'-spirobifluorene.

  The Journal of organic chemistry 20040319

• Regioregular head-to-tail oligothiophene-functionalized 9,9'-spirobifluorene derivatives. 2. NMR characterization, thermal behaviors, and electrochemical properties.

  The Journal of organic chemistry 20021115

• Head-to-tail regioregular oligothiophene-functionalized 9,9'-spirobifluorene derivatives. 1. Synthesis.

  The Journal of organic chemistry 20020712