15956-28-2 | Rhodium(ii) acetate dimer

Packsize	Purity	Availability	Price	Discounted Price
50mg	98%	in stock	$29.00	$20.00
100mg	98%	in stock	$49.00	$34.00
250mg	>98%	in stock	$86.00	$60.00
1g	98%	in stock	$251.00	$176.00
5g	98%	in stock	$1,099.00	$769.00
10g	98%	in stock	$1,951.00	$1,366.00

Description

• Catalog Number: AA81667
• Chemical Name: Rhodium(ii) acetate dimer
• CAS Number: 15956-28-2
• Molecular Formula: C10H12O8Rh2
• Molecular Weight: 466.0085
• MDL Number: MFCD00149212
• SMILES: CC1=[O][Rh]234C5(O1)[Rh]14(C3(OC(=[O]1)C)[O]=C(O2)C)OC(=[O]5)C

Computed Properties

• Complexity: 25.5
• Covalently-Bonded Unit Count: 6
• Heavy Atom Count: 18
• Hydrogen Bond Acceptor Count: 8

Literature

• Rhodium acetate/base-catalyzed N-silylation of indole derivatives with hydrosilanes.

  Chemical communications (Cambridge, England) 20120925

• Vinyl diazophosphonates as precursors to quaternary substituted indolines and cyclopentenes.

  Organic letters 20110218

• A strategy to synthesize taxol side chain and (-)-epi cytoxazone via chiral Brønsted acid-Rh(2)(OAc)(4) co-catalyzed enantioselective three-component reactions.

  The Journal of organic chemistry 20101105

• Tetra-mu-acetato-bis{[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]rhodium(II)}(Rh-Rh) tetrahydrofuran tetrasolvate.

  Acta crystallographica. Section C, Crystal structure communications 20081001

• 2D NMR study of the DNA duplex d(CTCTC*A*ACTTCC).d(GGAAGTTGAGAG) cross-linked by the antitumor-active dirhodium(II,II) unit at the cytosine-adenine step.

  Biochemistry 20080226

• Mechanism and control of rare tautomer trapping at a metal-metal bond: adenine binding to dirhodium antitumor agents.

  Journal of the American Chemical Society 20080116

• A computational study on DNA bases interactions with dinuclear tetraacetato-diaqua-dirhodium(II,II) complex.

  Journal of inorganic biochemistry 20080101

• Distal renal tubular acidosis associated with anion exchanger 1 mutations in children in Thailand.

  American journal of kidney diseases : the official journal of the National Kidney Foundation 20070601

• Unprecedented head-to-head conformers of d(GpG) bound to the antitumor active compound tetrakis (mu-carboxylato)dirhodium(II,II).

  Journal of the American Chemical Society 20030903

• Novel binding interactions of the DNA fragment d(pGpG) cross-linked by the antitumor active compound tetrakis(mu-carboxylato)dirhodium(II,II).

  Journal of the American Chemical Society 20030903

• DNA cleavage by photogenerated Rh(2)(O(2)CCH(3))(4)(H(2)O)(2)(+).

  Inorganic chemistry 20010521

• An approach toward isoindolobenzazepines using the ammonium ylide/Stevens.

  The Journal of organic chemistry 20010406