1633-22-3 | [2.2]Paracyclophane

Packsize	Purity	Availability	Price	Discounted Price
5g	98%	in stock	$10.00	$7.00
10g	98%	in stock	$12.00	$8.00
25g	98%	in stock	$13.00	$9.00
100g	98%	in stock	$42.00	$29.00
250g	98%	in stock	$102.00	$71.00
500g	98%	in stock	$155.00	$108.00

Description

• Catalog Number: AA85354
• Chemical Name: [2.2]Paracyclophane
• CAS Number: 1633-22-3
• Molecular Formula: C16H16
• Molecular Weight: 208.2982
• MDL Number: MFCD00003707
• SMILES: C1Cc2ccc(cc2)CCc2ccc1cc2
• NSC Number: 91575

Computed Properties

• Complexity: 156
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 16
• XLogP3: 3.7

Literature

• A pass too far: dissociation of internal energy selected paracyclophane cations, theory and experiment.

  Physical chemistry chemical physics : PCCP 20120914

• Spectroelectrochemistry of a photochromic [2.2]paracyclophane-bridged imidazole dimer: clarification of the electrochemical behavior of HABI.

  The journal of physical chemistry. A 20120628

• Photochromic properties of [2.2]paracyclophane-bridged imidazole dimer with increased photosensitivity by introducing pyrenyl moiety.

  The journal of physical chemistry. A 20111124

• Comprehensive understanding of structure- photosensitivity relationships of photochromic [2.2]paracyclophane-bridged imidazole dimers.

  The journal of physical chemistry. A 20110512

• 12,12'-[2,2'-Oxybis(ethane-2,1-di-yl)bis-(-oxy)]bis-[(R(p))-4-bromo-[2.2]paracyclo-phane].

  Acta crystallographica. Section E, Structure reports online 20110401

• Single-molecule conductance through multiple π-π-stacked benzene rings determined with direct electrode-to-benzene ring connections.

  Journal of the American Chemical Society 20110223

• Facile synthesis of planar chiral N-oxides and their use in Lewis base catalysis.

  Chemical communications (Cambridge, England) 20110107

• Synthesis, structure, and electronic and photophysical properties of two- and three-layered [3.3]paracyclophane-based donor-acceptor systems.

  The Journal of organic chemistry 20100917

• Multitiered 2D pi-stacked conjugated polymers based on pseudo-geminal disubstituted [2.2]paracyclophane.

  Journal of the American Chemical Society 20100908

• 5,8-Dibromo-14,15,17,18-tetra-methyl-2,11-dithia-[3.3]paracyclo-phane.

  Acta crystallographica. Section E, Structure reports online 20100801

• EPR and ENDOR studies of dimeric paracyclophane radical cations and dications containing tri- and pentamethylene-bridged p-phenylene diamine units.

  The journal of physical chemistry. A 20100617

• A fast photochromic molecule that colors only under UV light.

  Journal of the American Chemical Society 20090401

• 4-Amino-13-(1-naphth-yl)-[2,2]paracyclo-phane.

  Acta crystallographica. Section E, Structure reports online 20080401

• Symmetrically tetrasubstituted [2.2]paracyclophanes: their systematization and regioselective synthesis of several types of bis-bifunctional derivatives by double electrophilic substitution.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

• The 'cyclophene' [2.2.2](1,2,4)cyclophan-9-ene.

  Acta crystallographica. Section C, Crystal structure communications 20071201

• Designing cyclophane-based molecular wire sensors.

  The journal of physical chemistry. B 20061130

• Fancy bioisosteres: novel paracyclophane derivatives as super-affinity dopamine D3 receptor antagonists.

  Journal of medicinal chemistry 20060615

• Role of electron density and magnetic couplings on the nucleus-independent chemical shift (NICS) profiles of [2.2]paracyclophane and related species.

  The Journal of organic chemistry 20060217

• Design and construction of a 2D metal organic framework with multiple cavities: a nonregular net with a paracyclophane that codes for multiply fused nodes.

  Journal of the American Chemical Society 20051019

• Theoretical study of the effects of solvent environment on photophysical properties and electronic structure of paracyclophane chromophores.

  The Journal of chemical physics 20050608

• Synthesis of macrocycles via cobalt-mediated [2 + 2 + 2] cycloadditions.

  Journal of the American Chemical Society 20050316

• Atropisomeric (R,R)-2,2'-Bi([2]paracyclo[2](5,8)quinolinophane) and (R,R)-1,1'-Bi([2]paracyclo[2](5,8)isoquinolinophane): synthesis, structural analysis, and chiroptical properties.

  The Journal of organic chemistry 20050204

• Two-photon absorption in three-dimensional chromophores based on [2.2]-paracyclophane.

  Journal of the American Chemical Society 20040922

• Electrophilic substitution of dibromoparacyclophane: a route to novel paracyclophane phosphine ligands.

  Organic letters 20040610

• Binuclear rhenium(I) complexes with bridging [2.2]paracyclophane-diimine ligands: probing electronic coupling through pi-pi interactions.

  Inorganic chemistry 20040126

• Through-space delocalized water-soluble paracyclophane bichromophores: new fluorescent optical reporters.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20030721

• Three-dimensional nonlinear optical chromophores based on through-space delocalization.

  Journal of the American Chemical Society 20021113

• Water-soluble oligomer dimers based on paracyclophane: a new optical platform for fluorescent sensor applications.

  Journal of the American Chemical Society 20021009

• Phosphonites based on the paracyclophane backbone: new ligands for highly selective rhodium-catalyzed asymmetric hydrogenation.

  Organic letters 20011115

• Anti-inflammatory planar chiral [2.2]paracyclophaneacetic acid enantiomers.

  Inflammation research : official journal of the European Histamine Research Society ... [et al.] 20010701