17261-28-8 | 2-(Diphenylphosphino)benzoic acid

Packsize	Purity	Availability	Price	Discounted Price
1g	98%	in stock	$5.00	$4.00
5g	98%	in stock	$6.00	$5.00
10g	98%	in stock	$8.00	$6.00
25g	98%	in stock	$17.00	$12.00
100g	98%	in stock	$58.00	$41.00
500g	98%	in stock	$289.00	$203.00

Description

• Catalog Number: AB50120
• Chemical Name: 2-(Diphenylphosphino)benzoic acid
• CAS Number: 17261-28-8
• Molecular Formula: C19H15O2P
• Molecular Weight: 306.295
• MDL Number: MFCD00674024
• SMILES: OC(=O)c1ccccc1P(c1ccccc1)c1ccccc1

Computed Properties

• Complexity: 340
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 22
• Hydrogen Bond Acceptor Count: 2
• Hydrogen Bond Donor Count: 1
• Rotatable Bond Count: 4
• XLogP3: 4.1

Literature

• Stereoselective synthesis of trisubstituted olefins by a directed allylic substitution strategy.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20111010

• Stereoselective and diversity-oriented synthesis of trisubstituted allylic alcohols and amines.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20111010

• Ruthenium-catalysed linear-selective allylic alkylation of allyl acetates.

  Chemical communications (Cambridge, England) 20070121

• Electronic differentiation competes with transition state sensitivity in palladium-catalyzed allylic substitutions.

  Beilstein journal of organic chemistry 20070101

• Predicting the stereochemistry of diphenylphosphino benzoic acid (DPPBA)-based palladium-catalyzed asymmetric allylic alkylation reactions: a working model.

  Accounts of chemical research 20061001

• Hybridization dependent cleavage of internally modified disulfide-peptide nucleic acids.

  Bioorganic & medicinal chemistry letters 20050201

• Synthesis, characterization and antioxidant activity of new copper(I) complexes of scorpionate and water soluble phosphane ligands.

  Dalton transactions (Cambridge, England : 2003) 20040907

• Heterodimerization of olefins. 1. Hydrovinylation reactions of olefins that are amenable to asymmetric catalysis.

  The Journal of organic chemistry 20031031

• Dynamic kinetic asymmetric cycloadditions of isocyanates to vinylaziridines.

  Journal of the American Chemical Society 20031001

• New diphosphine ligands containing ethyleneglycol and amino alcohol spacers for the rhodium-catalyzed carbonylation of methanol.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20020802

• Geminal dicarboxylates as carbonyl surrogates for asymmetric synthesis. Part I. Asymmetric addition of malonate nucleophiles.

  Journal of the American Chemical Society 20010425