188264-84-8 | (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(ii)

Packsize	Purity	Availability	Price	Discounted Price
250mg	99%	in stock	$6.00	$4.00
1g	99%	in stock	$7.00	$5.00
5g	99%	in stock	$15.00	$11.00
10g	99%	in stock	$24.00	$17.00

Description

• Catalog Number: AB14889
• Chemical Name: (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(ii)
• CAS Number: 188264-84-8
• Molecular Formula: C36H52CoN2O2
• Molecular Weight: 603.7435
• MDL Number: MFCD01631278
• SMILES: [O-]c1c(/C=N/[C@H]2CCCC[C@@H]2/N=C/c2cc(cc(c2[O-])C(C)(C)C)C(C)(C)C)cc(cc1C(C)(C)C)C(C)(C)C.[Co+2]

Computed Properties

• Complexity: 793
• Covalently-Bonded Unit Count: 2
• Defined Atom Stereocenter Count: 2
• Heavy Atom Count: 41
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 8

Upstream Synthesis Route

(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) is a versatile catalyst widely used in chemical synthesis. Its unique structure and properties make it highly effective in various organic transformations, particularly asymmetric catalysis.In chemical synthesis, this compound plays a crucial role as a catalyst in asymmetric reactions, where the control of stereochemistry is essential to obtain the desired chiral products. The chiral ligand in (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) provides a chiral environment around the cobalt center, allowing for selective activation of substrates and facilitating the formation of enantiomerically pure products.The catalytic activity of (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) has been demonstrated in a wide range of reactions, including asymmetric cyclopropanation, hydrogenation, alkynylation, and cycloaddition reactions. Its ability to control the stereochemistry of the products makes it a valuable tool for chemists working in the field of organic synthesis.Overall, (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) is a highly efficient catalyst that enables the synthesis of complex chiral molecules with high selectivity and yield. Its application in chemical synthesis has significantly contributed to the advancement of asymmetric catalysis and the development of new methodologies for the preparation of chiral compounds.