2071-20-7 | Bis(diphenylphosphino)methane

Packsize	Purity	Availability	Price	Discounted Price
10g	97%	in stock	$13.00	$9.00
25g	97%	in stock	$18.00	$12.00
100g	97%	in stock	$62.00	$43.00

Description

• Catalog Number: AB17548
• Chemical Name: Bis(diphenylphosphino)methane
• CAS Number: 2071-20-7
• Molecular Formula: C25H22P2
• Molecular Weight: 384.3897
• MDL Number: MFCD00003537
• SMILES: c1ccc(cc1)P(c1ccccc1)CP(c1ccccc1)c1ccccc1
• NSC Number: 147767

Computed Properties

• Complexity: 325
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 27
• Rotatable Bond Count: 6
• XLogP3: 6

Literature

• Bis[μ-bis-(diphenyl-phosphan-yl)methane-κ(2)P:P']bis-[(isoquinoline-κN)silver(I)] bis-(trifluoro-methane-sulfonate)-isoquinoline (1/1).

  Acta crystallographica. Section E, Structure reports online 20120801

• Bis[μ(2)-bis-(diphenyl-phosphan-yl)methane-κP:P']bis-(μ(4)-diphenyl-phosphinato-κO:O:O':O')bis-(μ(2)-trifluoro-acetato-κO:O')tetra-silver(I) acetonitrile disolvate.

  Acta crystallographica. Section E, Structure reports online 20111201

• [μ-Bis(diphenyl-phosphan-yl-κP)methane]-deca-carbonyl-tri-μ-hydrido-trirhenium(I)(3 Re-Re) dichloromethane solvate.

  Acta crystallographica. Section E, Structure reports online 20111201

• Synthesis and characterization of diiron dithiolate complexes containing a quinoxaline bridge.

  Dalton transactions (Cambridge, England : 2003) 20111107

• Synthesis, structure and photophysical properties of binuclear methylplatinum complexes containing cyclometalating 2-phenylpyridine or benzo{h}quinoline ligands: a comparison of intramolecular Pt-Pt and π-π interactions.

  Dalton transactions (Cambridge, England : 2003) 20110928

• A new cumulene diiron complex related to the active site of Fe-only hydrogenases and its phosphine substituted derivatives: synthesis, electrochemistry and structural characterization.

  Journal of inorganic biochemistry 20110901

• Bis[μ(2)-bis-(diphenyl-phosphan-yl)methane-κP:P']bis-(μ(4)-diphenyl-phosphinato-κO:O:O':O')bis-[μ(2)-trifluoro-methane-sulfonato-(0.546/0.454)]-κO:O';κO:O-tetra-silver(I) acetonitrile disolvate.

  Acta crystallographica. Section E, Structure reports online 20110801

• [μ(2)-Bis(diphenyl-phosphanyl)methane][μ(3)-bis-(diphenyl-phosphanyl)meth-yl]trichlorido-tetra-gold(I) tetra-hydro-furan disolvate.

  Acta crystallographica. Section E, Structure reports online 20110201

• [μ-Bis(diphenyl-phosphan-yl)methane-1:2κP:P']nona-carbonyl-1κC,2κC,3κC-[tris-(biphenyl-4-yl)arsane-3κAs]-triangulo-triruthenium(0).

  Acta crystallographica. Section E, Structure reports online 20110201

• Bis{[μ-bis-(diphenyl-phosphan-yl)methane-1:2κP:P']nona-carbonyl-1κC,2κC,3κC-[(4-methyl-sulfanylphen-yl)diphenyl-phosphane-3κP]-triangulo-triruthen-ium(0)} dichloro-methane monosolvate.

  Acta crystallographica. Section E, Structure reports online 20110201

• Computational insight into the Rh-mediated activation of white phosphorus.

  Inorganic chemistry 20110103

• A tetra-silver(I)ditungsten(VI) cluster with sulfide and bis-(diphenyl-phosphino)methane ligands.

  Acta crystallographica. Section E, Structure reports online 20101001

• catena-Poly[silver(I)-bis-[μ-bis-(diphenyl-phosphino)methane-κP:P']-μ-thio-cyanato-κS:S-silver(I)-μ-thio-cyanato-κS:N].

  Acta crystallographica. Section E, Structure reports online 20101001

• Associative and dissociative mechanisms in the formation of phthalazine bridged organodiplatinum(II) complexes.

  Inorganic chemistry 20100920

• An iridium-mediated C-H activation/CO2-carboxylation reaction of 1,1-bisdiphenylphosphinomethane.

  Dalton transactions (Cambridge, England : 2003) 20100907

• Bis([μ-bis-(diphenyl-phosphino)methane-1:2κP:P']nona-carbonyl-1κC,2κC,3κC-{tris-[4-(methyl-sulfan-yl)phen-yl]arsine-3κAs}-triangulo-triruthenium(0)) dichloro-methane monosolvate.

  Acta crystallographica. Section E, Structure reports online 20100901

• Nucleophilic aromatic addition reactions of the metallabenzenes and metallapyridinium: attacking aromatic metallacycles with bis(diphenylphosphino)methane to form metallacyclohexadienes and cyclic eta(2)-allene-coordinated complexes.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20100618

• Cytotoxicity of half sandwich ruthenium(II) complexes with strong hydrogen bond acceptor ligands and their mechanism of action.

  Journal of inorganic biochemistry 20100201

• Bis{[μ-bis-(diphenyl-phosphino)methane-1:2κP:P']nona-carbonyl-1κC,2κC,3κC-[tris-(4-methoxy-phen-yl)arsine-3κAs]-triangulo-triruthenium(0)} dichloro-methane solvate.

  Acta crystallographica. Section E, Structure reports online 20100101

• catena-Poly[[(6,7,9,10,17,18,20,21-octa-hydro-5,8,11,16,19,22-hexa-oxadibenzo[a,j]cyclo-octa-decene)barium]-di-μ-thio-cyanato-[thio-cyanato-diaurate(I)(Au-Au)]-μ-thio-cyanato].

  Acta crystallographica. Section E, Structure reports online 20091201

• Bis[μ(2)-bis-(diphenyl-phosphino)methane]bis-(μ(2)-ethane-1,2-dithiol-ato)-μ(4)-sulfido-μ(2)-sulfido-disulfidodimolybdenum(V)disilver(I) dimethyl-formamide tris-olvate.

  Acta crystallographica. Section E, Structure reports online 20091201

• [μ-Bis-(diphenyl-phosphino)methane-1:2κP:P']nonacarbonyl-1κC,2κC,3κC-[tris-(4-methyl-phen-yl)arsine-3κAs]-triangulo-triruthenium(0).

  Acta crystallographica. Section E, Structure reports online 20091201

• catena-Poly[[[acetonitrile-copper(I)]-bis-[μ-bis-(diphenyl-phosphino)methane-κP:P']-copper(I)-μ-1,2-di-4-pyridy-l-ethene] bis-(tetra-fluoridoborate)].

  Acta crystallographica. Section E, Structure reports online 20091101

• Bis[μ-bis-(diphenyl-phosphino)methane-κP:P']bis-[(2,2'-bipyridine-κN,N')copper(I)] bis-(tetra-fluoro-borate).

  Acta crystallographica. Section E, Structure reports online 20091001

• Synthesis and structure of an 'iron-doped' copper selenide cluster molecule: [Cu30Fe2Se6(SePh)24(dppm)4].

  Inorganic chemistry 20090921

• Heteroleptic arene ruthenium complexes based on meso-substituted dipyrrins: synthesis, structure, reactivity, and electrochemical studies.

  Inorganic chemistry 20090817

• The controlled formation and cleavage of an intramolecular d8-d8 Pt-Pt interaction in a dinuclear cycloplatinated molecular 'pivot-hinge'.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20090803

• Gold complexes with the selenolate ligand [2-(Me2NCH2)C6H4Se]-.

  Inorganic chemistry 20090504

• Synthesis and crystal structures of bis(diphenylphosphanyl)methanides of lithium and calcium as well as of their borane adducts.

  Dalton transactions (Cambridge, England : 2003) 20090428

• Laser spectroscopy for atmospheric and environmental sensing.

  Sensors (Basel, Switzerland) 20090101

• Formation of [PtPd(2)(mu(3)-X)(2)(P-P)(dppmX)(2)](2+) (X = S, Se; P-P = dppe, 2 x PPh(3)) aggregates through activation of the chalcogen-rich [PtX(4)] ring by a Pd(I)-Pd(I) bond.

  Dalton transactions (Cambridge, England : 2003) 20081114

• A C-H activation-CO(2)-carboxylation reaction sequence mediated by an 'Iridium(dppm)' species. Formation of the anionic ligand (Ph(2)P)(2)C-COOH.

  Chemical communications (Cambridge, England) 20081021

• Synthesis and photophysical studies of calix[4]arene-based binuclear platinum(II) complexes: probing metal-metal and ligand-ligand interactions.

  Inorganic chemistry 20080616

• Bis[μ-bis-(diphenyl-phosphino)methane-κP:P']bis-[(chloro-difluoro-acetato-κO)silver(I)](Ag-Ag).

  Acta crystallographica. Section E, Structure reports online 20080501

• Reactivity of a heterocyclic As-Se compound with metal salts: syntheses and structures of the first copper complexes and of new alkali metal salts containing As-Se anions.

  Dalton transactions (Cambridge, England : 2003) 20080221

• Strong intra- and intermolecular aurophilic interactions in a new series of brilliantly luminescent dinuclear cationic and neutral au(I) benzimidazolethiolate complexes.

  Inorganic chemistry 20080204

• Bis[μ-methyl-enebis(diphenyl-phosphine)]bis-[(5-nitro-1,10-phenanthroline)silver(I)] bis-(hexa-fluoridoanti-monate).

  Acta crystallographica. Section E, Structure reports online 20080101

• The nature of the chemical bond in linear three-body systems: from i3- to mixed chalcogen/halogen and trichalcogen moieties.

  Bioinorganic chemistry and applications 20070101

• Rhodium dimers with 2,2-dimethyl-1,3-diisocyano and bis(diphenylphosphino)methane bridging ligands.

  Inorganic chemistry 20061030

• Syntheses, structures, and nonlinear optical properties of heteroselenometallic W-Se-Ag cluster compounds containing phosphine ligands.

  Inorganic chemistry 20061016

• Structures, photoluminescence, and reversible vapoluminescence properties of neutral platinum(II) complexes containing extended pi-conjugated cyclometalated ligands.

  Journal of the American Chemical Society 20060628

• Solution and solid-state properties of luminescent M-M bond-containing coordination/organometallic polymers using the RNC-M2(dppm)2-CNR building blocks (M = Pd, Pt; R = Aryl, Alkyl).

  Inorganic chemistry 20060403

• Pyridine-2-thionate as a versatile ligand in Pd(II) and Pt(II) chemistry: the presence of three different co-ordination modes in [Pd2(micro2-S,N-C5H4SN)(micro2-kappa2S-C5H4SN)(micro2-dppm)(S-C5H4SN)2].

  Dalton transactions (Cambridge, England : 2003) 20060128

• Synthesis of heterobimetallic Ru-Mn complexes and the coupling reactions of epoxides with carbon dioxide catalyzed by these complexes.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20060123

• Versatility of dithiophosphates in the syntheses of copper(I) complexes with bis(diphenylphosphino)alkanes: abstraction of chloride from dichloromethane.

  Inorganic chemistry 20051226

• Arsinophosphonium cations from arsenium-phosphine and -bisphosphine coordination chemistry.

  Inorganic chemistry 20051212

• Oxidative addition of methyl iodide to a new type of binuclear platinum(II) complex: a kinetic study.

  Inorganic chemistry 20051114

• The synthesis, structural, and spectroscopic characterization of uranium(IV) perrhenate complexes.

  Inorganic chemistry 20051017

• Transformation of mu4-phosphinidenes at an Ru5 center: isolation and structural characterization of hydroxyphosphinidene cluster acids, fluorophosphinidenes, and a novel mu5-phosphide.

  Inorganic chemistry 20050418

• Novel metallamacrocyclic gold(I) thiolate cluster complex: structure and luminescence of [Au9(mu-dppm)4(mu-p-tc)6](PF6)3.

  Chemical communications (Cambridge, England) 20050328

• Diphosphine-phosphenium coordination complexes representing monocations with pendant donors and ligand tethered dications.

  Journal of the American Chemical Society 20041229

• Molecular design of luminescence ion probes for various cations based on weak gold(I)...gold(I) interactions in dinuclear gold(I) complexes.

  Inorganic chemistry 20041115

• Spectroscopic evidence for the direct coordination of the pertechnetate anion to the uranyl cation in [UO2(TcO4)(DPPMO2)2]+.

  Inorganic chemistry 20040906

• Molecular QCA cells. 1. Structure and functionalization of an unsymmetrical dinuclear mixed-valence complex for surface binding.

  Inorganic chemistry 20030908

• Molecular QCA cells. 2. Characterization of an unsymmetrical dinuclear mixed-valence complex bound to a Au surface by an organic linker.

  Inorganic chemistry 20030908

• Complexes of lanthanide nitrates with bis(diphenylphosphino)methane dioxide.

  Inorganic chemistry 20030728

• Luminescence tribochromism and bright emission in gold(I) thiouracilate complexes.

  Journal of the American Chemical Society 20030702

• Reduction of the pertechnetate anion with bidentate phosphine ligands.

  Inorganic chemistry 20021104

• Novel intramolecular C-H bond activation in an iridium dppm complex.

  Inorganic chemistry 20020923

• Palladium(II) and platinum(II) analogues of luminescent diimine Triangulo complexes supported by triply bridging sulfide ligands: structural and spectroscopic comparisons.

  Inorganic chemistry 20011217

• [Bis(diphenylphosphino)methane][1,3-bis(diphenylphosphino)propane]platinum(II) dibromide.

  Acta crystallographica. Section C, Crystal structure communications 20011101