2170-06-1 | 1-Phenyl-2-(trimethylsilyl)acetylene

Packsize	Purity	Availability	Price	Discounted Price
1g	95%	in stock	$18.00	$12.00
5g	95%	in stock	$23.00	$17.00
10g	95%	in stock	$45.00	$32.00
25g	95%	in stock	$59.00	$42.00
500g	95%	in stock	$1,131.00	$792.00

Description

• Catalog Number: AB58701
• Chemical Name: 1-Phenyl-2-(trimethylsilyl)acetylene
• CAS Number: 2170-06-1
• Molecular Formula: C11H14Si
• Molecular Weight: 174.31436
• MDL Number: MFCD00054860
• SMILES: C[Si](C#Cc1ccccc1)(C)C

Computed Properties

• Complexity: 192
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 12
• Rotatable Bond Count: 2

Literature

• Facile coupling of propargylic, allylic and benzylic alcohols with allylsilane and alkynylsilane, and their deoxygenation with Et3SiH, catalyzed by Bi(OTf)3 in [BMIM][BF4] ionic liquid (IL), with recycling and reuse of the IL.

  Organic & biomolecular chemistry 20120928

• Fluorinated alcohols as promoters for the metal-free direct substitution reaction of allylic alcohols with nitrogenated, silylated, and carbon nucleophiles.

  The Journal of organic chemistry 20120907

• Diethyl 4,5-diphenyl-3,6-bis-(trimethyl-sil-yl)benzene-1,2-dicarboxyl-ate.

  Acta crystallographica. Section E, Structure reports online 20110701

• Tetrabutylammonium fluoride (TBAF)-catalyzed addition of substituted trialkylsilylalkynes to aldehydes, ketones, and trifluoromethyl ketones.

  The Journal of organic chemistry 20110603

• The influence of halogen substituents on the course of hydrogallation and hydroalumination reactions.

  Dalton transactions (Cambridge, England : 2003) 20091221

• 3,4-Diphenyl-2,5-bis-(trimethyl-silyl)cyclo-penta-dienone.

  Acta crystallographica. Section E, Structure reports online 20081101

• cis/trans Isomerism of hydroalumination and hydrogallation products-reflections on stability and rearrangement mechanism.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

• Rhenium- and gold-catalyzed coupling of aromatic aldehydes with trimethyl(phenylethynyl)silane: synthesis of diethynylmethanes.

  Angewandte Chemie (International ed. in English) 20070101

• Electrical characterization of metal-molecule-silicon junctions.

  Annals of the New York Academy of Sciences 20031201