26782-71-8 | D-tert-Leucine

Packsize	Purity	Availability	Price	Discounted Price
250mg	97%	in stock	$6.00	$4.00
1g	97%	in stock	$7.00	$5.00
5g	98%	in stock	$15.00	$10.00
10g	97%	in stock	$29.00	$20.00
25g	97%	in stock	$68.00	$48.00
100g	97%	in stock	$250.00	$175.00
500g	97%	in stock	$1,246.00	$872.00

Description

• Catalog Number: AB73330
• Chemical Name: D-tert-Leucine
• CAS Number: 26782-71-8
• Molecular Formula: C6H13NO2
• Molecular Weight: 131.1729
• MDL Number: MFCD00004265
• SMILES: N[C@H](C(C)(C)C)C(=O)O

Computed Properties

• Complexity: 115
• Covalently-Bonded Unit Count: 1
• Defined Atom Stereocenter Count: 1
• Heavy Atom Count: 9
• Hydrogen Bond Acceptor Count: 3
• Hydrogen Bond Donor Count: 2
• Rotatable Bond Count: 2
• XLogP3: -1.8

Literature

• Asymmetric construction of spirocyclohexanonerhodanines catalyzed by simple diamine derived from chiral tert-leucine.

  Chemical communications (Cambridge, England) 20120921

• Chiral recognition of α-amino acids by an optically active (2S,5S,8S,11S)-2,5,8,11-tetraethyl cyclen cobalt(III) complex.

  Inorganic chemistry 20110103

• Total synthesis of the large non-ribosomal peptide polytheonamide B.

  Nature chemistry 20100401

• Scaleable catalytic asymmetric Strecker syntheses of unnatural alpha-amino acids.

  Nature 20091015

• The tert-butyl group in chemistry and biology.

  Organic & biomolecular chemistry 20080807

• Effect of organic cosolvent on kinetic resolution of tert-leucine by penicillin G acylase from Kluyvera citrophila.

  Bioprocess and biosystems engineering 20060401

• Preparation of optically pure tert-leucine by penicillin G acylase-catalyzed resolution.

  Preparative biochemistry & biotechnology 20060101

• Preferred conformations of peptides containing tert-leucine, a sterically demanding, lipophilic alpha-amino acid with a quaternary side-chain Cbeta atom.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20050408

• Highly selective asymmetric acetate aldol reactions of an N-acetyl thiazolidinethione reagent.

  Organic letters 20040108

• An efficient and selective enzymatic oxidation system for the synthesis of enantiomerically pure D-tert-leucine.

  Organic letters 20031002

• Enzyme-assisted preparation of D-tert.-leucine.

  Bioscience, biotechnology, and biochemistry 20010901