333-27-7 | Methyl trifluoromethanesulfonate

Packsize	Purity	Availability	Price	Discounted Price
1g	98%	in stock	$6.00	$4.00
5g	98%	in stock	$15.00	$10.00
10g	97%	in stock	$24.00	$17.00
25g	98%	in stock	$40.00	$28.00
500g	98%	in stock	$636.00	$445.00

Description

• Catalog Number: AB46581
• Chemical Name: Methyl trifluoromethanesulfonate
• CAS Number: 333-27-7
• Molecular Formula: C2H3F3O3S
• Molecular Weight: 164.1036
• MDL Number: MFCD00000409
• SMILES: COS(=O)(=O)C(F)(F)F
• NSC Number: 270679

Computed Properties

• Complexity: 172
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 9
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 1
• XLogP3: 0.9

Literature

• Noncovalent interactions in peri-substituted chalconium acenaphthene and naphthalene salts: a combined experimental, crystallographic, computational, and solid-state NMR study.

  Inorganic chemistry 20121015

• 9-(3-Fluoro-phen-oxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate monohydrate.

  Acta crystallographica. Section E, Structure reports online 20120301

• Reactivity of divalent germanium alkoxide complexes is in sharp contrast to the heavier tin and lead analogues.

  Inorganic chemistry 20120206

• Dissociative electron attachment to triflates.

  The Journal of chemical physics 20111207

• 9-(2,5-Dimethyl-phen-oxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.

  Acta crystallographica. Section E, Structure reports online 20111201

• Fully automated and reproducible radiosynthesis of high specific activity [¹¹C]raclopride and [¹¹C]Pittsburgh compound-B using the combination of two commercial synthesizers.

  Nuclear medicine communications 20111101

• (Isopropyl-amino)(meth-yl)diphenyl-phospho-nium iodide.

  Acta crystallographica. Section E, Structure reports online 20110701

• Activation of carbon dioxide by divalent tin alkoxides complexes.

  Inorganic chemistry 20110307

• 1,2-diphosphaacenaphthene 1,2-dications: synthetic, stereochemical and computational study of the stabilising role of naphthalene-1,8-diyl backbone.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20110225

• Lithium salts of [1,12-dialkyl-CB11Me10]- anions.

  Inorganic chemistry 20101115

• 9-(4-Fluoro-phen-oxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.

  Acta crystallographica. Section E, Structure reports online 20101101

• 9-(4-Chloro-phen-oxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.

  Acta crystallographica. Section E, Structure reports online 20101101

• 10-Methyl-9-[2-(propan-2-yl)phenoxy-carbonyl]-acridinium trifluoro-methane-sulfonate.

  Acta crystallographica. Section E, Structure reports online 20101101

• 9-Phenyl-10H-acridinium trifluoro-methane-sulfonate.

  Acta crystallographica. Section E, Structure reports online 20101101

• 9-(2,6-Dimethyl-phen-oxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.

  Acta crystallographica. Section E, Structure reports online 20101101

• Room temperature palladium-catalyzed cross coupling of aryltrimethylammonium triflates with aryl Grignard reagents.

  Organic letters 20101001

• Synthesis, structure, and reactivity of a stabilized phosphiranylium salt.

  Angewandte Chemie (International ed. in English) 20100726

• Identification and evaluation of [11C]GSK931145 as a novel ligand for imaging the type 1 glycine transporter with positron emission tomography.

  Synapse (New York, N.Y.) 20100701

• 9-Benzyl-10-methyl-acridinium trifluoro-methane-sulfonate.

  Acta crystallographica. Section E, Structure reports online 20100701

• Effects of frozen conditions on stereoselectivity and velocity of O-glycosylation reactions.

  Bioorganic & medicinal chemistry 20100601

• 9-(4-Methyl-phenoxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.

  Acta crystallographica. Section E, Structure reports online 20100601

• 9-(4-Bromo-phenoxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.

  Acta crystallographica. Section E, Structure reports online 20100601

• Microstructured poly(2-oxazoline) bottle-brush brushes on nanocrystalline diamond.

  Physical chemistry chemical physics : PCCP 20100507

• First principles insight into the alpha-glucan structures of starch: their synthesis, conformation, and hydration.

  Chemical reviews 20100414

• [Three cases of occupational methyl trifluoromethanesulfonate poisoning].

  Zhonghua lao dong wei sheng zhi ye bing za zhi = Zhonghua laodong weisheng zhiyebing zazhi = Chinese journal of industrial hygiene and occupational diseases 20100401

• 9-(2-Ethyl-phenoxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.

  Acta crystallographica. Section E, Structure reports online 20100401

• 10-Methyl-9-phenoxy-carbonyl-acridinium trifluoro-methane-sulfonate monohydrate.

  Acta crystallographica. Section E, Structure reports online 20100401

• Catalytic (asymmetric) methylene transfer to aldehydes.

  Organic letters 20100205

• H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.

  Accounts of chemical research 20100119

• Bis(4'-dibutylaminostyryl)benzene: spectroscopic behavior upon protonation or methylation.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20091207

• Carbonyl-chlorido(1-methyl-sulfanylpenta-1,3-dien-1-yl-5-yl-idene)bis-(triphenyl-phosphane)osmium(II).

  Acta crystallographica. Section E, Structure reports online 20091101

• Addition of methyl triflate to a hafnocene dinitrogen complex: stepwise n(2) methylation and conversion to a hafnocene hydrazonato compound.

  Journal of the American Chemical Society 20091021

• Synthesis and reactivity of a Ru(I) dimer devoid of pi-acid ligands.

  Dalton transactions (Cambridge, England : 2003) 20090814

• Cationic heterocycles as ligands: synthesis and reactivity with anionic nucleophiles of cationic triruthenium clusters containing C-metalated N-methylquinoxalinium or N-methylpyrazinium ligands.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20090727

• 9-Chloro-2,4-dimethoxy-acridinium trifluoro-methane-sulfonate.

  Acta crystallographica. Section E, Structure reports online 20090401

• 9-(Methyl-sulfan-yl)acridinium trifluoro-methane-sulfonate.

  Acta crystallographica. Section E, Structure reports online 20090301

• Synthesis and reactivity of metal carbene complexes with heterobiaryl spacer substituents.

  Dalton transactions (Cambridge, England : 2003) 20090128

• Synthesis of phenol and quinone metabolites of benzo[a]pyrene, a carcinogenic component of tobacco smoke implicated in lung cancer.

  The Journal of organic chemistry 20090116

• 9-Ethyl-10-methyl-acridinium trifluoro-methane-sulfonate.

  Acta crystallographica. Section E, Structure reports online 20090101

• Lewis-acid-assisted methyl exchange reactions in silylated aminodichloroarsanes.

  Inorganic chemistry 20081215

• The preparation of stable aziridinium ions and their ring-openings.

  Chemical communications (Cambridge, England) 20080928

• Divergent and regioselective synthesis of 1,2,4- and 1,2,5-trisubstituted imidazoles.

  The Journal of organic chemistry 20080905

• C-H activation on a diphosphine and hydrido-bridged diiridium complex: generation and detection of an active IrII-IrII species [(Cp*Ir)2(micro-dmpm)(micro-H)]+.

  Dalton transactions (Cambridge, England : 2003) 20080721

• (Carbonyl-1κC)bis-[2,3(η)-cyclo-penta-dien-yl][μ(3)-(S-methyl trithio-carbonato)methylidyne-1:2:3κC,S'':C:C](triphenyl-phosphine-1κP)(μ(3)-sulfido-1:2:3κS)dicobalt(II)iron(II) trifluoro-methane-sulfonate.

  Acta crystallographica. Section E, Structure reports online 20080501

• Pyridine ring opening at room temperature at a rhenium tricarbonyl bipyridine complex.

  Journal of the American Chemical Society 20080430

• Carboxylation of an ansa-zirconocene dinitrogen complex: regiospecific hydrazine synthesis from N2 and CO2.

  Journal of the American Chemical Society 20080402

• 10-Methyl-9-(2-nitro-phenoxy-carbon-yl)acridinium trifluoro-methane-sulfonate.

  Acta crystallographica. Section E, Structure reports online 20080201

• Reactivity and stability of platinum(II) formyl complexes based on PCP-type ligands. The significance of sterics.

  Dalton transactions (Cambridge, England : 2003) 20071228

• Synthesis and properties of 1-methylthiopropargylammonium salts and their use as key precursors to sulfur-containing enediynes.

  Organic letters 20071206

• Phase-transfer-catalyzed asymmetric acylimidazole alkylation.

  Organic letters 20071108

• Alkylation and acylation of cyclotriphosphazenes.

  Inorganic chemistry 20070820

• Bifunctional building blocks for glyco-architectures by TiCl4 -promoted ring opening of cyclodextrin derivatives.

  Biomacromolecules 20070701

• Cyclotetraphosphinophosphonium ions: synthesis, structures, and pseudorotation.

  Journal of the American Chemical Society 20070613

• Monocyclic di- and triphosphinophosphonium cations: new foundational frameworks for catena-phosphorus chemistry.

  Inorganic chemistry 20070514

• Synthesis of para-methoxybenzyl (PMB) ethers under neutral conditions.

  Chemical communications (Cambridge, England) 20070414

• Carbon-11 labeling chemistry based upon [11C]methyl iodide.

  Ernst Schering Research Foundation workshop 20070101

• Diphosphiranium (P2C) or diphosphetanium (P2C2) cyclic cations: different fates for the electrophile-initiated cyclodimerization of a phosphaalkene.

  Journal of the American Chemical Society 20061220

• Synthesis of extended polyphosphacumulenes.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20061115

• Boryllithium: isolation, characterization, and reactivity as a boryl anion.

  Science (New York, N.Y.) 20061006

• Synthesis and characterization of osmium(II) trispyrazolylborate complexes.

  Inorganic chemistry 20060626

• Improved synthesis of the peripheral benzodiazepine receptor ligand [11C]DPA-713 using [11C]methyl triflate.

  Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine 20060501

• Method for the determination of inorganic polysulfide distribution in aquatic systems.

  Analytical chemistry 20060415

• Changes in coordination of sterically demanding hybrid imidazolylphosphine ligands on Pd(0) and Pd(II).

  Journal of the American Chemical Society 20060118

• Study of thioglycosylation in ionic liquids.

  Beilstein journal of organic chemistry 20060101

• Synthesis and properties of Ph2S(=N-(Ph2)S[triple bond]N)2.

  Inorganic chemistry 20051128

• The amide group in N-acetylglucosamine glycosyl acceptors affects glycosylation outcome.

  The Journal of organic chemistry 20050805

• Synthesis of cimiracemate B, a phenylpropanoid found in Cimicifuga racemosa.

  Natural product research 20050401

• Spectroscopic studies on the cation-anion, cation-solvent and anion-solvent interactions in the LiCF3SO3/acetamide complex system.

  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20050114

• Ring expansion-annulation strategy for the synthesis of substituted azulenes and oligoazulenes. 2. Synthesis of azulenyl halides, sulfonates, and azulenylmetal compounds and their application in transition-metal-mediated coupling reactions.

  The Journal of organic chemistry 20041210

• Synthesis of tertiary propargylamines by sequential reactions of in situ generated thioiminium salts with organolithium and -magnesium reagents.

  Journal of the American Chemical Society 20040519

• Improved synthesis of [11C]SA4503, [11C]MPDX and [11C]TMSX by use of [11C]methyl triflate.

  Annals of nuclear medicine 20040401

• A formal total synthesis of (+/-)-halichlorine and (+/-)-pinnaic acid.

  Organic letters 20040318

• Asymmetric dearomatization of the furan ring promoted by conjugate organolithium addition to (menthyloxy)(3-furyl)carbene complexes of chromium.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20031205

• Substitution pattern of 3-deoxy-D-manno-oct-2-ulosonic acid in bacterial lipopolysaccharides investigated by methylation analysis of whole LPS.

  Carbohydrate research 20031114

• Synthesis of fluorescence-labelled disaccharide substrates of glucosidase II.

  Carbohydrate research 20030910

• Protonation reactions of dinuclear pyrazolato iridium(I) complexes.

  Inorganic chemistry 20030728

• Acyclic selenoiminium salts: isolation, first structural characterization, and reactions.

  Organic letters 20030417

• Preparation of unsymmetrical sulfonylureas from N,N'-sulfuryldiimidazoles.

  The Journal of organic chemistry 20030110

• [Synthesis of aminoethyl glycosides of the carbohydrate chains of glycolipids Gb3, Gb4 i Gb5].

  Bioorganicheskaia khimiia 20030101

• Steric and electronic effects on the reactivity of rh and ir complexes containing P-S, P-P, and P-O ligands. Implications for the effects of chelate ligands in catalysis.

  Journal of the American Chemical Society 20021113

• An improved method for the preparation of [11C]verapamil.

  Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine 20021001

• Reversible intramolecular hydride transfer between tantalum and an aromatic ring: an eta(5)-cyclohexadienyl complex as a masked hydride.

  Journal of the American Chemical Society 20020724

• Optimizing the least nucleophilic anion. A new, strong methyl(+) reagent.

  Journal of the American Chemical Society 20020220

• Synthesis, structure, and reactivity of closo-2,3,4,5,6,7,8,9,10,11-decahydroxy-1,12-bis(sulfonic acid)-1,12-dicarbadodecaborane(12).

  Journal of the American Chemical Society 20011226

• A simple loop method for the automated preparation of (11C)raclopride from (11C)methyl triflate.

  Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine 20010701

• MeOTf-mediated alkynylation of selenoamides leading to beta-methylselenenyl alpha,beta-unsaturated ketones and their characterization.

  Organic letters 20010628

• Synthesis of propyl and 2-aminoethyl glycosides of alpha-D-galactosyl-(1-->3')-beta-lactoside.

  Carbohydrate research 20010615

• Protonation and deprotonation of TpOs(NHPh)Cl(2): an unusually inert amido ligand.

  Inorganic chemistry 20010409

• Stereoselective synthesis of 2-S-phenyl-2-deoxy-beta-glycosides using phenyl 2,3-O-thionocarbonyl-1-thioglycoside donors via 1,2-Migration and concurrent glycosidation.

  Organic letters 20010208

• Stereospecific reduction of phosphine oxides to phosphines by the use of a methylation reagent and lithium aluminum hydride.

  Organic letters 20010111