4358-87-6 | Methyl 2-hydroxy-2-phenylacetate

Packsize	Purity	Availability	Price	Discounted Price
1g	97%	in stock	$16.00	$11.00
5g	97%	in stock	$16.00	$12.00
10g	97%	in stock	$19.00	$13.00
25g	97%	in stock	$26.00	$18.00
100g	97%	in stock	$73.00	$51.00
500g	97%	in stock	$312.00	$218.00

Description

• Catalog Number: AG24250
• Chemical Name: Methyl 2-hydroxy-2-phenylacetate
• CAS Number: 4358-87-6
• Molecular Formula: C9H10O3
• Molecular Weight: 166.1739
• MDL Number: MFCD00004493
• SMILES: COC(=O)C(c1ccccc1)O
• NSC Number: 6539

Computed Properties

• Complexity: 150
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 12
• Hydrogen Bond Acceptor Count: 3
• Hydrogen Bond Donor Count: 1
• Rotatable Bond Count: 3
• Undefined Atom Stereocenter Count: 1
• XLogP3: 1.2

Literature

• Theoretical study on chiral recognition mechanism of methyl mandelate enantiomers on permethylated β-cyclodextrin.

  Journal of molecular modeling 20120201

• Characterization of an unusual adsorption behavior of racemic methyl-mandelate on a tris-(3,5-dimethylphenyl) carbamoyl cellulose chiral stationary phase.

  Journal of chromatography. A 20110923

• Hydrolysis of triacetin catalyzed by immobilized lipases: effect of the immobilization protocol and experimental conditions on diacetin yield.

  Enzyme and microbial technology 20110506

• A novel halophilic lipase, LipBL, showing high efficiency in the production of eicosapentaenoic acid (EPA).

  PloS one 20110101

• Ionophore-based potentiometric sensors for the flow-injection determination of promethazine hydrochloride in pharmaceutical formulations and human urine.

  Sensors (Basel, Switzerland) 20110101

• Integration of newly isolated biocatalyst and resin-based in situ product removal technique for the asymmetric synthesis of (R)-methyl mandelate.

  Bioprocess and biosystems engineering 20100901

• Biochemical characterization of a recombinant short-chain NAD(H)-dependent dehydrogenase/reductase from Sulfolobus acidocaldarius.

  Extremophiles : life under extreme conditions 20100301

• Gas phase elimination kinetics of methyl mandelate: experimental and DFT studies.

  The journal of physical chemistry. A 20091105

• Chiral recognition between alpha-hydroxylesters: a double-resonance IR/UV study of the complexes of methyl mandelate with methyl glycolate and methyl lactate.

  The journal of physical chemistry. A 20081009

• Calculations of the energy distribution from perturbation peak data--a new tool for characterization of chromatographic phases.

  Journal of chromatography. A 20080905

• Exploiting nanospace for asymmetric catalysis: confinement of immobilized, single-site chiral catalysts enhances enantioselectivity.

  Accounts of chemical research 20080601

• Screening and immobilization Burkholderia sp. GXU56 lipase for enantioselective resolution of (R,S)-methyl mandelate.

  Applied biochemistry and biotechnology 20080401

• N-methyl-(R)-3-(tert-butyl)-sulfinyl-1,4-dihydropyridine: a novel NADH model compound.

  Molecules (Basel, Switzerland) 20070312

• Purification of different lipases from Aspergillus niger by using a highly selective adsorption on hydrophobic supports.

  Biotechnology and bioengineering 20051220

• Reactivity of methyl mandelate-Ti(IV)-enediolate: oxidative homocoupling versus aldol and direct Mannich-type syn-diastereoselective condensation.

  The Journal of organic chemistry 20050513

• Enantioselective synthesis of primary 1-(aryl)alkylamines by nucleophilic 1,2-addition of organolithium reagents to hydroxyoxime ethers and application to asymmetric synthesis of G-protein-coupled receptor ligands.

  The Journal of organic chemistry 20040820

• Validation of the accuracy of the perturbation peak method for determination of single and binary adsorption isotherm parameters in LC.

  Analytical chemistry 20040815

• [Enantiomeric separation of mandelic acid and its analogues by high performance liquid chromatography with 2,6-di-O-pentyl-beta-cyclodextrin coated symmetry C8 column].

  Se pu = Chinese journal of chromatography 20040701

• Esters of mandelic acid as substrates for (S)-mandelate dehydrogenase from Pseudomonas putida: implications for the reaction mechanism.

  Biochemistry 20040224

• Micromide and guamamide: cytotoxic alkaloids from a species of the marine cyanobacterium Symploca.

  Journal of natural products 20040101

• Constraining asymmetric organometallic catalysts within mesoporous supports boosts their enantioselectivity.

  Journal of the American Chemical Society 20031210

• The mandelamide keto-enol system in aqueous solution. Generation of the enol by hydration of phenylcarbamoylcarbene.

  Journal of the American Chemical Society 20030108

• Atropoisomeric quinolinium salt promoting the access to both enantiomeric forms of methyl mandelate: a versatile NADH mimic.

  Chemical communications (Cambridge, England) 20021007

• Asymmetric autocatalysis and its application to chiral discrimination.

  Chirality 20020701

• Enantiomer separation of mandelates and their analogs on cyclodextrin derivative chiral stationary phases by capillary GC.

  Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 20011001