484-11-7 | 2,9-dimethyl-1,10-phenanthroline

Packsize	Purity	Availability	Price	Discounted Price
1g	98%	in stock	$10.00	$7.00
5g	98%	in stock	$20.00	$14.00
10g	98%	in stock	$25.00	$17.00
25g	98%	in stock	$58.00	$40.00
100g	98%	in stock	$228.00	$159.00

Description

• Catalog Number: AI50990
• Chemical Name: 2,9-dimethyl-1,10-phenanthroline
• CAS Number: 484-11-7
• Molecular Formula: C14H12N2
• Molecular Weight: 208.2585
• MDL Number: MFCD00004973
• SMILES: Cc1ccc2c(n1)c1nc(C)ccc1cc2
• NSC Number: 4280

Computed Properties

• Complexity: 227
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 16
• Hydrogen Bond Acceptor Count: 2
• XLogP3: 3.3

Literature

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• A spectroscopic and computational study on the effects of methyl and phenyl substituted phenanthroline ligands on the electronic structure of Re(I) tricarbonyl complexes containing 2,6-dimethylphenylisocyanide.

  Dalton transactions (Cambridge, England : 2003) 20050321

• Syntheses, structural analyses and redox kinetics of four-coordinate [CuL2]2+ and five-coordinate [CuL2(solvent)]2+ complexes (L = 6,6'-dimethyl-2,2'-bipyridine or 2,9-dimethyl-1,10-phenanthroline): completely gated reduction reaction of [Cu(dmp)2]2+ in nitromethane.

  Dalton transactions (Cambridge, England : 2003) 20050321

• Structural properties and dissociative fluxional motion of 2,9-dimethyl-1,10-phenanthroline in platinum(II) complexes.

  Inorganic chemistry 20050307

• Effect of neocuproine, a copper(i) chelator, on rat bladder function.

  The Journal of pharmacology and experimental therapeutics 20050301

• Studies in oligonucleotide-based artificial nuclease systems. intramolecular copper (II) complex formation in an oligonucleotide bis-phenanthroline conjugate.

  Nucleosides, nucleotides & nucleic acids 20050101

• Novel total antioxidant capacity index for dietary polyphenols and vitamins C and E, using their cupric ion reducing capability in the presence of neocuproine: CUPRAC method.

  Journal of agricultural and food chemistry 20041229

• Cu(I)(2,9-bis(trifluoromethyl)-1,10-phenanthroline)2+ complexes: correlation between solid-state structure and photoluminescent properties.

  Inorganic chemistry 20041227

• Photochemical expulsion of the neutral monodentate ligand L in Ru(terpy*)(diimine)(L)2+: a dramatic effect of the steric properties of the spectator diimine ligand.

  Inorganic chemistry 20041227

• Synthesis, crystal structures, and anti-convulsant activities of ternary [Zn(II)(3,5-diisopropylsalicylate)(2)], [Zn(II)(salicylate)(2)] and [Zn(II)(aspirinate)(2)] complexes.

  Journal of inorganic biochemistry 20041101

• Zn2+-catalyzed methanolysis of phosphate triesters: a process for catalytic degradation of the organophosphorus pesticides paraoxon and fenitrothion.

  Inorganic chemistry 20041018

• Aldehydic DNA lesions in calf thymus DNA and HeLa S3 cells produced by bacterial quinone metabolites of fluoranthene and pyrene.

  Carcinogenesis 20040901

• Role of OGG1 and NTG2 in the repair of oxidative DNA damage and mutagenesis induced by hydrogen peroxide in Saccharomyces cerevisiae: relationships with transition metals iron and copper.

  Yeast (Chichester, England) 20040901

• Nitric oxide and BCNU chemoresistance in C6 glioma cells: role of S-nitrosoglutathione.

  Free radical biology & medicine 20040515

• General method for the synthesis of 8-arylsulfanyl adenine derivatives.

  The Journal of organic chemistry 20040430

• Evidence that NiNi acetyl-CoA synthase is active and that the CuNi enzyme is not.

  Biochemistry 20040406

• Sensitive indirect spectrophotometric determination of isoniazid.

  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20040301

• Neocuproine inhibits the decomposition of endogenous S-nitrosothiol by ultraviolet irradiation in the mouse gastric fundus.

  European journal of pharmacology 20040206

• Metal-assisted light-induced DNA cleavage activity of 2-(methylthio)phenylsalicylaldimine Schiff base copper(II) complexes having planar heterocyclic bases.

  Journal of inorganic biochemistry 20040201

• Speciation of ternary cobalt(II) phenanthroline-silica surface complexes as a function of pH and ligand steric bulk.

  Inorganic chemistry 20031117

• Ternary copper complexes for photocleavage of DNA by red light: direct evidence for sulfur-to-copper charge transfer and d-d band involvement.

  Journal of the American Chemical Society 20031008

• Structure-dependent photophysical properties of singlet and triplet metal-to-ligand charge transfer states in copper(I) bis(diimine) compounds.

  Inorganic chemistry 20031006

• Modulation of mitochondrial membrane potential and reactive oxygen species production by copper in astrocytes.

  Journal of neurochemistry 20031001

• Utilization of activating and masking effects by ligands for highly selective catalytic spectrophotometric determination of copper and iron in natural waters.

  Talanta 20030829

• 'Chiral-at-Metal' octahedral ruthenium(II) complexes with achiral ligands: a new type of enantioselective catalyst.

  Inorganic chemistry 20030811

• MLCT state structure and dynamics of a copper(I) diimine complex characterized by pump-probe X-ray and laser spectroscopies and DFT calculations.

  Journal of the American Chemical Society 20030611

• Intracellular metal ion chelators inhibit TNFalpha-induced SP-1 activation and adhesion molecule expression in human aortic endothelial cells.

  Free radical biology & medicine 20030315

• Heterobimetallic oxalato-bridged M(II)Re(IV) complexes (M = Mn, Fe, Co, Ni): synthesis, crystal structure, and magnetic properties.

  Inorganic chemistry 20030224

• Inner-sphere complexation of cobalt(II) 2,9-dimethyl-1,10-phenanthroline ([Co(neo)]2+) with commercial and sol-gel derived silica gel surfaces.

  Inorganic chemistry 20030127

• Excited state molecular structure determination in disordered media using laser pump/X-ray probe time-domain X-ray absorption spectroscopy.

  Faraday discussions 20030101

• Anti- and pro-oxidant effects of urate in copper-induced low-density lipoprotein oxidation.

  European journal of biochemistry 20021101

• Rapid excited-state structural reorganization captured by pulsed X-rays.

  Journal of the American Chemical Society 20020911

• The oxidative effect of bacterial lipopolysaccharide on native and cross-linked human hemoglobin as a function of the structure of the lipopolysaccharide.

  European journal of biochemistry 20020901

• Bis(1,10-phenanthroline)(thiosulfato)manganese(II) methanol solvate and catena-poly[[diaqua(2,9-dimethyl-1,10-phenanthroline)manganese(II)]-mu-thiosulfato].

  Acta crystallographica. Section C, Crystal structure communications 20020801

• Heme nitrosylation of deoxyhemoglobin by s-nitrosoglutathione requires copper.

  The Journal of biological chemistry 20020705

• Investigation of the reaction of copper(I) with 2,9-dimethyl-1,10-phenanthroline at trace level by thermal lensing.

  Talanta 20020703

• Synthesis and structural characterization of Cu(I) and Ni(II) complexes that contain the bis[2-(diphenylphosphino)phenyl]ether ligand. Novel emission properties for the Cu(I) species.

  Inorganic chemistry 20020617

• Catalytic effect of sulfoxides on the fluxional motion of 2,9-dimethyl-1,10-phenanthroline in a platinum(II) complex: evaluation of steric and electronic contributions.

  Inorganic chemistry 20020603

• Pairing of propellers: dimerization of octahedral ruthenium(II) and osmium(II) complexes of eilatin via pi-pi stacking featuring heterochiral recognition.

  Journal of the American Chemical Society 20020515

• Synergic extraction of lanthanoids by mixtures of LIX 54 (high molecular weight beta-diketone) and bidentate neutral amines.

  Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 20020301

• Redox induced reversible structural transformations of dimeric and polymeric phenanthroline-based copper chelates.

  Inorganic chemistry 20020225

• Synthesis, characterization, photophysical properties, and biological labeling studies of a series of luminescent rhenium(I) polypyridine maleimide complexes.

  Inorganic chemistry 20020114

• Simple Cu(I) complexes with unprecedented excited-state lifetimes.

  Journal of the American Chemical Society 20020109

• A approximately 35 kDa polypeptide from insect cells binds to yeast ACS like elements in the presence of ATP.

  BMC biochemistry 20020101

• Low-density lipoprotein modification by normal, myeloperoxidase-deficient and NADPH oxidase-deficient granulocytes and the impact of redox active transition metal ions.

  Redox report : communications in free radical research 20020101

• Chloro(2,9-dimethyl-1,10-phenanthroline-N,N')(isoquinoline-1-carboxylato-O,N)copper(II).

  Acta crystallographica. Section C, Crystal structure communications 20011101

• Electrochemiluminescence of copper(I) bis(2,9-dimethyl-1,10- phenanthroline).

  Analytical chemistry 20011001

• Oxidative DNA damage by capsaicin and dihydrocapsaicin in the presence of Cu(II).

  Cancer letters 20010828

• Fluxional behavior of the dinitrogen ligand 2,9-dimethyl-1,10-phenanthroline in cationic methyl platinum(II) complexes.

  Inorganic chemistry 20010702

• Nitric oxide initiates iron binding to neocuproine.

  Nitric oxide : biology and chemistry 20010401

• Role of copper ions and cytochrome P450 in the vasodilator actions of the nitroxyl anion generator, Angeli's salt, on rat aorta.

  European journal of pharmacology 20010202

• Evaluation of antioxidant activity of epigallocatechin gallate in biphasic model systems in vitro.

  Molecular and cellular biochemistry 20010201

• Pre- and postjunctional protective effect of neocuproine on the nitrergic neurotransmitter in the mouse gastric fundus.

  British journal of pharmacology 20010101