50777-76-9 | 2-(Diphenylphosphino)benzaldehyde

Packsize	Purity	Availability	Price	Discounted Price
5g	97%	in stock	$9.00	$7.00
10g	97%	in stock	$17.00	$12.00

Description

• Catalog Number: AI51412
• Chemical Name: 2-(Diphenylphosphino)benzaldehyde
• CAS Number: 50777-76-9
• Molecular Formula: C19H15OP
• Molecular Weight: 290.2955610000001
• MDL Number: MFCD00013367
• SMILES: O=Cc1ccccc1P(c1ccccc1)c1ccccc1

Computed Properties

• Complexity: 300
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 21
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• XLogP3: 4.1

Literature

• Synthesis of the phosphino-fullerene PPh2(o-C6H4)(CH2NMeCH)C60 and its function as an η1-P or η3-P,C2 ligand.

  Dalton transactions (Cambridge, England : 2003) 20120314

• Intermolecular hydroacylation: high activity rhodium catalysts containing small-bite-angle diphosphine ligands.

  Journal of the American Chemical Society 20120314

• Aldimines generated from aza-Wittig reaction between bis(iminophosphoranes) derived from 1,1'-diazidoferrocene and aromatic or heteroaromatic aldehydes: electrochemical and optical behaviour towards metal cations.

  Dalton transactions (Cambridge, England : 2003) 20111214

• Chlorido{N-[2-(diphenyl-phosphan-yl)benz-yl]-1-(pyridin-2-yl)methanamine-κP}gold(I).

  Acta crystallographica. Section E, Structure reports online 20111101

• Stereoselective synthesis of trisubstituted olefins by a directed allylic substitution strategy.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20111010

• Stereoselective and diversity-oriented synthesis of trisubstituted allylic alcohols and amines.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20111010

• Chlorido{N-[2-(diphenylphosphanyl)benz-ylidene]-2-(2-thienyl)ethanamine-κN,P}methylpalladium(II) dichloromethane hemisolvate.

  Acta crystallographica. Section E, Structure reports online 20100601

• Diphen-yl[2-(2-pyridylamino-meth-yl)phen-yl]phosphine oxide.

  Acta crystallographica. Section E, Structure reports online 20100501

• Total synthesis of (+)-bourgeanic acid utilizing o-DPPB-directed allylic substitution.

  Organic letters 20090806

• New hydridoirida-beta-diketones derived from 8-quinoline-carbaldehyde and o-(diphenylphosphino)benzaldehyde.

  Dalton transactions (Cambridge, England : 2003) 20090607

• Synthesis and characterization of iron(II) complexes with tetradentate diiminodiphosphine or diaminodiphosphine ligands as precatalysts for the hydrogenation of acetophenone.

  Inorganic chemistry 20090119

• Synthesis and characterization of a novel Pd(II) complex with the condensation product of 2-(diphenylphosphino)benzaldehyde and ethyl hydrazinoacetate. Cytotoxic activity of the synthesized complex and related Pd(II) and Pt(II) complexes.

  Journal of inorganic biochemistry 20061101

• o-DPPB-directed copper-mediated and -catalyzed allylic substitution with Grignard reagents.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20060825

• Palladium-catalyzed allylic alkylation using chiral hydrazones as ligands.

  The Journal of organic chemistry 20010309