546-68-9 | Titanium(IV) isopropoxide

Packsize	Purity	Availability	Price	Discounted Price
5g	97%	in stock	$25.00	$17.00
25g	97%	in stock	$41.00	$29.00
100g	97%	in stock	$89.00	$62.00
500g	97%	in stock	$297.00	$208.00

Description

• Catalog Number: AB47423
• Chemical Name: Titanium(IV) isopropoxide
• CAS Number: 546-68-9
• Molecular Formula: C12H28O4Ti
• Molecular Weight: 284.2153
• MDL Number: MFCD00008871
• SMILES: [O-]C(C)C.[O-]C(C)C.[O-]C(C)C.[O-]C(C)C.[Ti+4]

Computed Properties

• Complexity: 10.8
• Covalently-Bonded Unit Count: 5
• Heavy Atom Count: 17
• Hydrogen Bond Acceptor Count: 4

Literature

• Development and application of a new solid-phase microextraction fiber by sol-gel technology on titanium wire.

  Analytica chimica acta 20120912

• One-pot deposition of palladium on hybrid TiO2 nanoparticles and catalytic applications in hydrogenation.

  Journal of colloid and interface science 20120301

• Assessment of by-products of chlorination and photoelectrocatalytic chlorination of an azo dye.

  Journal of hazardous materials 20120227

• Enhanced visible light photocatalytic disinfection of gram negative, pathogenic Escherichia coli bacteria with Ag/TiV oxide nanoparticles.

  Colloids and surfaces. B, Biointerfaces 20110801

• Cyclopropylamines from N,N-dialkylcarboxamides and Grignard reagents in the presence of titanium tetraisopropoxide or methyltitanium triisopropoxide.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20101210

• Catalytic reactions of titanium alkoxides with Grignard reagents and imines: a mechanistic study.

  Chemistry, an Asian journal 20100802

• Concerning the potential reversibility of carbometalation in alkoxide-directed Ti(Oi-Pr)4-mediated reductive cross-coupling of homoallylic alcohols with aromatic imines.

  Chemical communications (Cambridge, England) 20100521

• Titanium(IV) isopropoxide mediated synthesis of pyrimidin-4-ones.

  Organic letters 20100521

• Effects of bias voltage on diamond like carbon coatings deposited using titanium isopropoxide (TIPOT) and acetylene/argon mixtures onto various substrate materials.

  Journal of nanoscience and nanotechnology 20100401

• Controlled oxidation of organic sulfides to sulfoxides under ambient conditions by a series of titanium isopropoxide complexes using environmentally benign H2O2 as an oxidant.

  Dalton transactions (Cambridge, England : 2003) 20100307

• Highly enantioselective addition of terminal alkynes to aldehydes catalyzed by a new chiral beta-sulfonamide alcohol/Ti(OiPr)4/Et2Zn/R3N catalyst system.

  Chirality 20090201

• Fabrication of platy apatite nanocrystals loaded with TiO2 nanoparticles by two-step emulsion method and their photocatalytic activity.

  Journal of colloid and interface science 20081015

• A theoretical analysis of the Ti(IV)-catalyzed glycoaminocyanation reaction.

  Carbohydrate research 20080721

• Catalytic asymmetric aryl transfer reactions to aldehydes with Grignard reagents as the aryl source.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

• Active cytotoxic reagents based on non-metallocene non-diketonato well-defined C2-symmetrical titanium complexes of tetradentate bis(phenolato) ligands.

  Journal of the American Chemical Society 20071010

• Highly enantioselective alkynylation of aldehydes using a new BINOL/Ti(OiPr)4/chiral sulfonamide catalyst system.

  Chirality 20070801

• Highly concentrated catalytic asymmetric allylation of ketones.

  Organic letters 20070201

• Transformation of D-(-)-ribose into a natural product-like scaffold via a Lewis acid catalyzed intramolecular hetero-Diels-Alder reaction.

  Nucleosides, nucleotides & nucleic acids 20070101

• Titanium, zinc and alkaline-earth metal complexes supported by bulky O,N,N,O-multidentate ligands: syntheses, characterisation and activity in cyclic ester polymerisation.

  Dalton transactions (Cambridge, England : 2003) 20060114

• Synthesis of TiO2 photocatalysts in supercritical CO2 via a non-hydrolytic route.

  The journal of physical chemistry. B 20051013

• Palladium-catalyzed allylation of acidic and less nucleophilic anilines using allylic alcohols directly.

  Chemical & pharmaceutical bulletin 20051001

• The rhodium catalyzed three-component reaction of diazoacetates, titanium(IV) alkoxides and aldehydes.

  Chemical communications (Cambridge, England) 20050528

• Readily available sulfamide-amine alcohols for enantioselective phenylacetylene addition to aldehydes in the absence of Ti(O(i)Pr)4.

  Chirality 20050515

• Controlled delivery of paclitaxel from stent coatings using poly(hydroxystyrene-b-isobutylene-b-hydroxystyrene) and its acetylated derivative.

  Biomacromolecules 20050101

• Photodegradation of surfactants on the nanosized TiO2 prepared by hydrolysis of the alkoxide titanium.

  Chemosphere 20040101

• Reagentless amperometric immunosensors based on direct electrochemistry of horseradish peroxidase for determination of carcinoma antigen-125.

  Analytical chemistry 20031015

• Highly enantioselective reductive amination of simple aryl ketones catalyzed by Ir-f-Binaphane in the presence of titanium(IV) isopropoxide and iodine.

  The Journal of organic chemistry 20030516

• A convenient synthesis of 1,1-disubstituted 1,2,3,4-tetrahydroisoquinolines via Pictet-Spengler reaction using titanium(IV) isopropoxide and acetic-formic anhydride.

  Chemical & pharmaceutical bulletin 20020201