553-90-2 | Dimethyl oxalate

Packsize	Purity	Availability	Price	Discounted Price
5g	99%	in stock	$16.00	$11.00
25g	99%	in stock	$19.00	$13.00
100g	99%	in stock	$38.00	$26.00
500g	>99.0%(GC)	in stock	$70.00	$49.00

Description

• Catalog Number: AB45931
• Chemical Name: Dimethyl oxalate
• CAS Number: 553-90-2
• Molecular Formula: C4H6O4
• Molecular Weight: 118.0880
• MDL Number: MFCD09029577
• SMILES: COC(=O)C(=O)OC
• NSC Number: 9374

Computed Properties

• Complexity: 92.6
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 8
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 3
• XLogP3: -0.2

Literature

• Effect of feedstock solvent on the stability of Cu/SiO2 catalyst for vapor-phase hydrogenation of dimethyl oxalate to ethylene glycol.

  Chemical communications (Cambridge, England) 20120128

• Assimilable organic carbon (AOC) in soil water extracts using Vibrio harveyi BB721 and its implication for microbial biomass.

  PloS one 20120101

• Crystal packing and melting temperatures of small oxalate esters: the role of C-H···O hydrogen bonding.

  Acta crystallographica. Section B, Structural science 20111201

• Carbonylation of nitrobenzene in methanol with palladium bidentate phosphane complexes: an unexpectedly complex network of catalytic reactions, centred around a Pd-imido intermediate.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20111118

• Bis(N,N'-dimethyl-ethylenediammonium) tris-(oxalato-κO,O)cobaltate(II) dihydrate: an ion-pair complex.

  Acta crystallographica. Section E, Structure reports online 20110901

• N,N'-Dimethyl-ethylenediammonium dioxalatocuprate(II).

  Acta crystallographica. Section E, Structure reports online 20110801

• Design, synthesis, and structure-activity relationship exploration of 1-substituted 4-aroyl-3-hydroxy-5-phenyl-1H-pyrrol-2(5H)-one analogues as inhibitors of the annexin A2-S100A10 protein interaction.

  Journal of medicinal chemistry 20110414

• High activity and selectivity of Ag/SiO2 catalyst for hydrogenation of dimethyl oxalate.

  Chemical communications (Cambridge, England) 20100628

• The isolation of citric acid derivatives from Aspergillus niger.

  FEMS microbiology letters 20100501

• Catalytic properties of [Pd(COOMe)(n)X(2-n)(PPh(3))(2)] (n = 0, 1, 2; X = Cl, NO(2), ONO(2), OAc and OTs) in the oxidative carbonylation of MeOH.

  Inorganic chemistry 20100419

• Preparation of calcium oxalate by vesicle modification in the catanionic surfactant system CDS/TTABr/H2O.

  The journal of physical chemistry. B 20100218

• Novel C2-symmetric macrocycles bearing diamide-diester groups: synthesis and enantiomeric recognition for primary alkyl ammonium salts.

  The Journal of organic chemistry 20080404

• Metal-ligand-coordinated vesicles and vesicle-assisted preparation of calcium oxalate.

  The journal of physical chemistry. B 20080214

• Host-guest interaction in a thiourea-dimethyl oxalate (2/1) complex at 300 and 100 K.

  Acta crystallographica. Section C, Crystal structure communications 20060901

• A tripodal sulfur ligand for the selective ruthenium-catalysed hydrogenation of dimethyl oxalate.

  Chemical communications (Cambridge, England) 20060604

• Synthesis of nitrogen and sulfur macrocycles with cis exogenous oxygen and sulfur donor atoms.

  Organic & biomolecular chemistry 20051207

• Active control of methanol carbonylation selectivity over Au/carbon anode by electrochemical potential.

  The journal of physical chemistry. B 20050512

• Preparation of enantiopure biimidazoline ligands and their use in asymmetric catalysis.

  Organic & biomolecular chemistry 20040721

• Selectivity control of carbonylation of methanol to dimethyl oxalate and dimethyl carbonate over gold anode by electrochemical potential.

  Journal of the American Chemical Society 20040505

• Synthesis, structural evaluation, and estrogen receptor interaction of 2,3-diarylpiperazines.

  Journal of medicinal chemistry 20020523