60656-87-3 | Benzyloxyacetaldehyde

Packsize	Purity	Availability	Price	Discounted Price
1g	95%	in stock	$25.00	$18.00
5g	95%	in stock	$79.00	$55.00
10g	95%	in stock	$140.00	$98.00
25g	95%	in stock	$277.00	$194.00
100g	95%	in stock	$977.00	$684.00

Description

• Catalog Number: AB47494
• Chemical Name: Benzyloxyacetaldehyde
• CAS Number: 60656-87-3
• Molecular Formula: C9H10O2
• Molecular Weight: 150.1745
• MDL Number: MFCD00191779
• SMILES: O=CCOCc1ccccc1

Computed Properties

• Complexity: 106
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 11
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• XLogP3: 1.1

Literature

• Catalysis through temporary intramolecularity: mechanistic investigations on aldehyde-catalyzed Cope-type hydroamination lead to the discovery of a more efficient tethering catalyst.

  Journal of the American Chemical Society 20121010

• Generating a generation of proteasome inhibitors: from microbial fermentation to total synthesis of salinosporamide a (marizomib) and other salinosporamides.

  Marine drugs 20100101

• Synthetic studies on (-)-lemonomycin: an efficient asymmetric synthesis of lemonomycinone amide.

  The Journal of organic chemistry 20090306

• D-fructose-6-phosphate aldolase in organic synthesis: cascade chemical-enzymatic preparation of sugar-related polyhydroxylated compounds.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20090101

• Serine hydroxymethyl transferase from Streptococcus thermophilus and L-threonine aldolase from Escherichia coli as stereocomplementary biocatalysts for the synthesis of beta-hydroxy-alpha,omega-diamino acid derivatives.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

• Single diastereomers of polyhydroxylated 9-oxa-1-azabicyclo[4.2.1]nonanes from intramolecular 1,3-dipolar cycloaddition of omega-unsaturated nitrones.

  The Journal of organic chemistry 20061027

• Recombinant production of serine hydroxymethyl transferase from Streptococcus thermophilus and its preliminary evaluation as a biocatalyst.

  Applied microbiology and biotechnology 20050901

• (R)-Goniothalamin: total syntheses and cytotoxic activity against cancer cell lines.

  Bioorganic & medicinal chemistry 20050415

• Crystal structure of vinorine synthase, the first representative of the BAHD superfamily.

  The Journal of biological chemistry 20050408

• Aldol additions of dihydroxyacetone phosphate to N-Cbz-amino aldehydes catalyzed by L-fuculose-1-phosphate aldolase in emulsion systems: inversion of stereoselectivity as a function of the acceptor aldehyde.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20050218

• Chiral 2,6-bis(oxazolinyl)pyridine-rare earth metal complexes as catalysts for highly enantioselective 1,3-dipolar cycloaddition reactions of 2-benzopyrylium-4-olates.

  The Journal of organic chemistry 20050107

• An intramolecular 1,3-dipolar cycloaddition reaction towards the synthesis of chiral azetidine nucleoside analogues: the D-gluco case.

  Nucleosides, nucleotides & nucleic acids 20050101

• Stereo- and regioselectivity of Pd(0)/InI-mediated allylic additions to aldehydes and ketones. In situ generation of allylindium(III) intermediates from N-acylnitroso Diels-Alder cycloadducts and 1-amino-4-acetoxycyclopentenes.

  The Journal of organic chemistry 20030110

• Highly enantioselective 1,3-dipolar cycloaddition reactions of 2-benzopyrylium-4-olate catalyzed by chiral Lewis acids.

  Journal of the American Chemical Society 20021218