6163-58-2 | Tri-o-tolylphosphine

Packsize	Purity	Availability	Price	Discounted Price
10g	98%	in stock	$8.00	$5.00
25g	98%	in stock	$15.00	$10.00
100g	98%	in stock	$28.00	$19.00
500g	98%	in stock	$135.00	$94.00

Description

• Catalog Number: AB47241
• Chemical Name: Tri-o-tolylphosphine
• CAS Number: 6163-58-2
• Molecular Formula: C21H21P
• Molecular Weight: 304.3652
• MDL Number: MFCD00008514
• SMILES: Cc1ccccc1P(c1ccccc1C)c1ccccc1C
• NSC Number: 116667

Computed Properties

• Complexity: 287
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 22
• Rotatable Bond Count: 3
• XLogP3: 5.7

Literature

• Effects of phosphorus substituents on reactions of α-alkoxyphosphonium salts with nucleophiles.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20120903

• Mechanochemical and solution synthesis, X-ray structure and IR and 31P solid state NMR spectroscopic studies of copper(I) thiocyanate adducts with bulky monodentate tertiary phosphine ligands.

  Dalton transactions (Cambridge, England : 2003) 20120707

• Palladium-catalyzed cross-coupling of sterically demanding boronic acids with α-bromocarbonyl compounds.

  The Journal of organic chemistry 20111007

• Synthesis and antibacterial activity of 2, 3-dehydro-3-O-(3-aryl-E-prop-2-enyl)-10, 11-anhydroclarithromycin derivatives.

  The Journal of antibiotics 20110401

• Imaging of I2-imidazoline receptors by small-animal PET using 2-(3-fluoro-[4-11C]tolyl)-4,5-dihydro-1H-imidazole ([11C]FTIMD).

  Nuclear medicine and biology 20100701

• Remarkable effect of phosphine on the reactivity of O,P-acetal--efficient substitution reaction of O,P-acetal.

  Chemical communications (Cambridge, England) 20100614

• Synthesis of InP nanofibers from tri(m-tolyl)phosphine: an alternative route to metal phosphide nanostructures.

  Dalton transactions (Cambridge, England : 2003) 20100107

• Palladium-catalyzed intramolecular C(sp(3))--H functionalization: catalyst development and synthetic applications.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20070101

• Bulky triarylarsines are effective ligands for palladium catalysed Heck olefination.

  Dalton transactions (Cambridge, England : 2003) 20050421

• Palladium-catalyzed intramolecular coupling between aryl iodides and allyl moieties via thermal and microwave-assisted conditions.

  Journal of the American Chemical Society 20050112

• Unexpected hydrodeiodo Sonogashira-Heck-Casser coupling reaction of 2,2'-diiodobiphenyls with acetylenes.

  The Journal of organic chemistry 20020308