6456-74-2 | tert-Butyl glycinate

Packsize	Purity	Availability	Price	Discounted Price
1g	97%	in stock	$8.00	$5.00
5g	97%	in stock	$18.00	$13.00
25g	97%	in stock	$42.00	$30.00
100g	97%	in stock	$106.00	$75.00
500g	97%	in stock	$449.00	$315.00

Description

• Catalog Number: AB50868
• Chemical Name: tert-Butyl glycinate
• CAS Number: 6456-74-2
• Molecular Formula: C6H13NO2
• Molecular Weight: 131.17292
• MDL Number: MFCD00038194
• SMILES: NCC(=O)OC(C)(C)C

Computed Properties

• Complexity: 104
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 9
• Hydrogen Bond Acceptor Count: 3
• Hydrogen Bond Donor Count: 1
• Rotatable Bond Count: 3
• XLogP3: 0.2

Literature

• A powerful synergistic effect for highly efficient diastereo- and enantioselective phase-transfer catalyzed conjugate additions.

  Chemical communications (Cambridge, England) 20110207

• Synthesis and structure-activity relationships of potent 1-(2-substituted-aminoacetyl)-4-fluoro-2-cyanopyrrolidine dipeptidyl peptidase IV inhibitors.

  Chemical & pharmaceutical bulletin 20080801

• alpha,alpha'-disubstituted amino acids with silylated side chains as lipophilic building blocks for the synthesis of peptaibol analogues.

  Chemistry & biodiversity 20080701

• Synthesis and ex vivo profiling of chemically modified cytomegalovirus CMVpp65 epitopes.

  Journal of peptide science : an official publication of the European Peptide Society 20080301

• Glycine- and sarcosine-based models of vanadate-dependent haloperoxidases in sulfoxygenation reactions.

  Inorganic chemistry 20070108

• Catalytic enantioselective synthesis of glutamic acid derivatives via tandem conjugate addition-elimination of activated allylic acetates under chiral PTC conditions.

  Journal of the American Chemical Society 20051005

• Cinchona alkaloid-based polymer-bound phase-transfer catalysts: efficient enantioselective alkylation of benzophenone imine of glycine esters.

  Molecular diversity 20050101

• A glycine-dependent riboswitch that uses cooperative binding to control gene expression.

  Science (New York, N.Y.) 20041008

• Chemo-enzymatic synthesis of N-arachidonoyl glycine.

  Biotechnology letters 20040801

• Acyclic stereoselective boron alkylation reactions for the asymmetric synthesis of beta-substituted alpha-amino acid derivatives.

  Journal of the American Chemical Society 20030305

• The enantioselective synthesis of alpha-amino acid derivatives via organoboranes.

  Journal of the American Chemical Society 20020814

• Chiral phosphine-free Pd-mediated asymmetric allylation of prochiral enolate with a chiral phase-transfer catalyst.

  Organic letters 20011018

• Enantioselective synthesis of (R)-3-(3,4-dihydroxyphenyl)alanine from tert-butyl glycinate.

  The Journal of organic chemistry 20010518