7440-16-6 | Rhodium

Packsize	Purity	Availability	Price	Discounted Price
250mg		in stock	$43.00	$30.00
1g		in stock	$86.00	$60.00
5g		in stock	$400.00	$280.00

Description

• Catalog Number: AB46983
• Chemical Name: Rhodium
• CAS Number: 7440-16-6
• Molecular Formula: Rh
• Molecular Weight: 102.9055
• MDL Number: MFCD00011201
• SMILES: [Rh]

Computed Properties

• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 1

Literature

• Transition metal-α-amino acid complexes with antibiotic activity against Mycobacterium spp.

  Antimicrobial agents and chemotherapy 20130701

• Synthesis and antiplasmodial evaluation of novel (4-aminobutyloxy)quinolines.

  Bioorganic & medicinal chemistry letters 20130101

• Aqueous-phase hydroformylation of 1-octene using hydrophilic sulfonate salicylaldimine dendrimers.

  Dalton transactions (Cambridge, England : 2003) 20121207

• Efficient synthesis of oxazoles by dirhodium(II)-catalyzed reactions of styryl diazoacetate with oximes.

  Chemical communications (Cambridge, England) 20121207

• Rhodium(II) catalyzed diastereoselective reactions of diazoacetamides with isatins: an efficient approach to 3-hydroxy-3,3'-bioxindoles.

  Organic & biomolecular chemistry 20121128

• Pyridine synthesis by reactions of allyl amines and alkynes proceeding through a Cu(OAc)2 oxidation and Rh(III)-catalyzed N-annulation sequence.

  Chemical communications (Cambridge, England) 20121128

• A chelating tetrapeptide rhodium complex comprised of a histidylidene residue: biochemical tailoring of an NHC-Rh hydrosilylation catalyst.

  Chemical communications (Cambridge, England) 20121118

• Novel C,N-chelate rhodium(III) and iridium(III) antitumor complexes incorporating a lipophilic steroidal conjugate and their interaction with DNA.

  Dalton transactions (Cambridge, England : 2003) 20121107

• Dirhodium carboxylates catalyzed enantioselective coupling reactions of α-diazophosphonates, anilines, and electron-deficient aldehydes.

  Angewandte Chemie (International ed. in English) 20121105

• Enantioselective synthesis of β-aryloxycarboxylic esters via asymmetric hydrogenation of β-aryloxy-α,β-unsaturated esters.

  Organic letters 20121102

• Rh(I)-catalyzed Pauson-Khand-type cycloaddition reaction of ene-vinylidenecyclopropanes with carbon monoxide (CO).

  Organic letters 20121102

• Chemistry. Lending handedness to the cyclopentadienyl ligand.

  Science (New York, N.Y.) 20121026

• Biotinylated Rh(III) complexes in engineered streptavidin for accelerated asymmetric C-H activation.

  Science (New York, N.Y.) 20121026

• Synthesis of enaminones by rhodium-catalyzed denitrogenative rearrangement of 1-(N-sulfonyl-1,2,3-triazol-4-yl)alkanols.

  Journal of the American Chemical Society 20121024

• Rhodium-catalyzed ring opening of benzocyclobutenols with site-selectivity complementary to thermal ring opening.

  Journal of the American Chemical Society 20121024

• Modular construction of a porous organometallic network based on rhodium olefin complexation.

  Journal of the American Chemical Society 20121024

• Synthesis of phenol derivatives from cyclohex-2-enones bearing an alkyne through Lewis acid-catalyzed enolization and intramolecular Alder-Rickert reaction.

  The Journal of organic chemistry 20121019

• Rhodium-catalyzed synthesis of diaryl sulfides using aryl fluorides and sulfur/organopolysulfides.

  Organic letters 20121019

• Chemo- and enantioselective Rh-catalysed hydrogenation of 3-methylene-1,2-diazetidines: application to vicinal diamine synthesis.

  Chemical communications (Cambridge, England) 20121011

• A rhodium complex-linked β-barrel protein as a hybrid biocatalyst for phenylacetylene polymerization.

  Chemical communications (Cambridge, England) 20121009

• Rhodium-catalyzed cross-aldol reaction: in situ aldehyde-enolate formation from allyloxyboranes and primary allylic alcohols.

  Angewandte Chemie (International ed. in English) 20121008

• Abnormal oxazol-4-ylidene and thiazol-4-ylidene rhodium complexes: synthesis, structure, and properties.

  Chemical communications (Cambridge, England) 20121007

• Development and testing of a compact basis set for use in effective core potential calculations on rhodium complexes.

  Journal of computational chemistry 20121005

• Determination of orientational isomerism in rhodium(II) metallopeptides by pyrene fluorescence.

  Organic & biomolecular chemistry 20121003

• Synthesis and resolution of the biaryl-like diphosphine (S)-Me2-CATPHOS, preparation of a derived rhodium precatalyst and applications in asymmetric hydrogenation.

  Nature protocols 20121001

• Mechanistic study of a one-step catalytic conversion of fructose to 2,5-dimethyltetrahydrofuran.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20120924

• Rhodium-catalyzed direct C-H amination of benzamides with aryl azides: a synthetic route to diarylamines.

  Angewandte Chemie (International ed. in English) 20120924

• Reductive cleavage of the Csp2-Csp3 bond of secondary benzyl alcohols: rhodium catalysis directed by N-containing groups.

  Angewandte Chemie (International ed. in English) 20120924

• Rhodium-catalyzed [2 + 2] cycloaddition of ynamides with nitroalkenes.

  Organic letters 20120921

• Scope and mechanistic analysis of the enantioselective synthesis of allenes by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and propargylic alcohols.

  Journal of the American Chemical Society 20120919

• Catalytic mechanism in artificial metalloenzyme: QM/MM study of phenylacetylene polymerization by rhodium complex encapsulated in apo-Ferritin.

  Journal of the American Chemical Society 20120919

• Hydrodefluorination and hydrogenation of fluorobenzene under mild aqueous conditions.

  Environmental science & technology 20120918

• Investigations into the formation and stability of cationic rhodium diphosphane η6-arene complexes.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20120917

• Rhodium-phosphoramidite catalyzed alkene hydroacylation: mechanism and octaketide natural product synthesis.

  Journal of the American Chemical Society 20120912

• Organic carbonates as stabilizing solvents for transition-metal nanoparticles.

  Dalton transactions (Cambridge, England : 2003) 20120828

• Screening rhodium metallopeptide libraries 'on bead': asymmetric cyclopropanation and a solution to the enantiomer problem.

  Angewandte Chemie (International ed. in English) 20120820

• Stereoselective intermolecular C-H amination reactions.

  Chemical communications (Cambridge, England) 20120814

• Selective rhodium(III)-catalyzed cross-dehydrogenative coupling of furan and thiophene derivatives.

  Angewandte Chemie (International ed. in English) 20120813

• Enantioselective rhodium-catalyzed nucleophilic allylation of cyclic imines with allylboron reagents.

  Angewandte Chemie (International ed. in English) 20120813

• Stereospecific synthesis and catalytic activity of L-histidylidene metal complexes.

  Dalton transactions (Cambridge, England : 2003) 20120807

• New tetraphosphorus ligands for highly linear selective hydroformylation of allyl and vinyl derivatives.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20120806

• Sequence-specific inhibition of a designed metallopeptide catalyst.

  Chemical communications (Cambridge, England) 20120804

• Rhodium-catalyzed carbonylation of cyclopropyl substituted propargyl esters: a tandem 1,3-acyloxy migration [5 + 1] cycloaddition.

  The Journal of organic chemistry 20120803

• Regioselective Rh(I)-catalyzed sequential hydrosilylation toward the assembly of silicon-based peptidomimetic analogues.

  The Journal of organic chemistry 20120720

• Diastereoselective [4 + 1] cycloaddition of alkenyl propargyl acetates with CO catalyzed by [RhCl(CO)2]2.

  The Journal of organic chemistry 20120720

• Synthesis of aza-fused polycyclic quinolines via double C-H bond activation.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20120716

• C sp 3-H bond activation triggered by formation of metallacycles: rhodium(I)-catalyzed cyclopropanation/cyclization of allenynes.

  Angewandte Chemie (International ed. in English) 20120716

• Rhodium-catalyzed intramolecular formation of N-sulfamoyl 2,3-aziridino-γ-lactones and their use for the enantiospecific synthesis of α,β-diamino acid derivatives.

  The Journal of organic chemistry 20120706

• Rh-catalyzed intermolecular reactions of cyclic α-diazocarbonyl compounds with selectivity over tertiary C-H bond migration.

  Journal of the American Chemical Society 20120704

• Highly stereoselective C-C bond formation by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and chiral allylic alcohols.

  Journal of the American Chemical Society 20120704

• Modular functionalization of allenes to aminated stereotriads.

  Journal of the American Chemical Society 20120704

• Oxygen reduction reactions of monometallic rhodium hydride complexes.

  Inorganic chemistry 20120702

• Interaction between water-soluble rhodium complex RhCl(CO)(TPPTS)₂ and surfactants probed by spectroscopic methods.

  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20120701

• The chemoselective reactions of tyrosine-containing G-protein-coupled receptor peptides with [Cp*Rh(H2O)3](OTf)2, including 2D NMR structures and the biological consequences.

  Journal of the American Chemical Society 20120627

• Conformational, steric and electronic effects on the site- and chemoselectivity of the metal-catalyzed reaction of N-bis(trimethylsilyl)methyl, N-(2-indolyl)methyl α-diazoamides.

  Organic & biomolecular chemistry 20120621

• Catalytic protein modification with dirhodium metallopeptides: specificity in designed and natural systems.

  Journal of the American Chemical Society 20120620

• The combined C-H functionalization/Cope rearrangement: discovery and applications in organic synthesis.

  Accounts of chemical research 20120619

• Stereoselective synthesis of norephedrine and norpseudoephedrine by using asymmetric transfer hydrogenation accompanied by dynamic kinetic resolution.

  The Journal of organic chemistry 20120615

• Convenient method for the functionalization of the 4- and 6-positions of the androgen skeleton.

  Chemical communications (Cambridge, England) 20120614

• Highly regio- and stereoselective dirhodium vinylcarbene induced nitrone cycloaddition with subsequent cascade carbenoid aromatic cycloaddition/N-O cleavage and rearrangement.

  Angewandte Chemie (International ed. in English) 20120611

• Rh(II)2-catalyzed synthesis of α-, β-, or δ-carbolines from aryl azides.

  Angewandte Chemie (International ed. in English) 20120611

• Kinetic and geometric isotope effects originating from different adsorption potential energy surfaces: cyclohexane on Rh(111).

  The Journal of chemical physics 20120607

• Self-assembled hexanuclear organometallic cages: synthesis, characterization, and host-guest properties.

  Chemistry, an Asian journal 20120601

• Kinetics of the oxidation of lactose by copper(II) complexed with bipyridyl in alkaline medium using chloro-complex of rhodium(III) in its nano-concentration range as homogeneous catalyst: a spectrophotometric study.

  Carbohydrate research 20120601

• Preparation of chiral 3-arylpyrrolidines via the enantioselective 1,4-addition of arylboronic acids to fumaric esters catalyzed by Rh(I)/chiral diene complexes.

  Organic letters 20120601

• Ligand-controlled regioselectivity in the hydrothiolation of alkynes by rhodium N-heterocyclic carbene catalysts.

  Journal of the American Chemical Society 20120516

• Halogen oxidation and halogen photoelimination chemistry of a platinum-rhodium heterobimetallic core.

  Inorganic chemistry 20120507

• Rhodium-catalyzed synthesis of branched amines by direct addition of benzamides to imines.

  Organic letters 20120504

• Rh2(II)-catalyzed intramolecular aliphatic C-H bond amination reactions using aryl azides as the N-atom source.

  Journal of the American Chemical Society 20120502

• Formal synthesis of (-)-englerin A and cytotoxicity studies of truncated englerins.

  Chemistry, an Asian journal 20120501

• In-vitro assessment of oxidative stress generated by orthodontic archwires.

  American journal of orthodontics and dentofacial orthopedics : official publication of the American Association of Orthodontists, its constituent societies, and the American Board of Orthodontics 20120501

• Computational study of the adsorption and dissociation of phenol on Pt and Rh surfaces.

  Physical chemistry chemical physics : PCCP 20120428

• Rhodium/copper-catalyzed annulation of benzimides with internal alkynes: indenone synthesis through sequential C-H and C-N cleavage.

  Angewandte Chemie (International ed. in English) 20120416

• Total syntheses of the elusive welwitindolinones with bicyclo[4.3.1] cores.

  Angewandte Chemie (International ed. in English) 20120416

• Reduction of nitrous acid with a macrocyclic rhodium complex that acts as a functional model of nitrite reductase.

  Inorganic chemistry 20120416

• Competitive [2,3]- and [1,2]-oxonium ylide rearrangements. Concerted or stepwise?

  Organic letters 20120406

• Cellular impact and selectivity of half-sandwich organorhodium(III) anticancer complexes and their organoiridium(III) and trichloridorhodium(III) counterparts.

  Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 20120401

• Rh-catalyzed intramolecular sp2 C-H bond difluoromethylenation.

  Chemical communications (Cambridge, England) 20120325

• Rh(I)-catalyzed asymmetric synthesis of 3-substituted isoindolinones through CO gas-free aminocarbonylation.

  The Journal of organic chemistry 20120316

• Total synthesis of (-)-anisatin.

  Organic letters 20120316

• Rhodium-catalyzed carbonylation of 3-acyloxy-1,4-enynes for the synthesis of cyclopentenones.

  Organic letters 20120316

• Total synthesis of (-)-kaitocephalin based on a Rh-catalyzed C-H amination.

  Organic letters 20120316

• Extrusion of CO from aryl ketones: rhodium(I)-catalyzed C-C bond cleavage directed by a pyridine group.

  Angewandte Chemie (International ed. in English) 20120312

• Total synthesis of (+)-asteriscanolide: further exploration of the rhodium(I)-catalyzed [(5+2)+1] reaction of ene-vinylcyclopropanes and CO.

  Chemistry, an Asian journal 20120305

• Synthesis of pyridines from ketoximes and terminal alkynes via C-H bond functionalization.

  The Journal of organic chemistry 20120302

• Mechanism of intermolecular hydroacylation of vinylsilanes catalyzed by a rhodium(I) olefin complex: a DFT study.

  Journal of molecular modeling 20120301

• In vitro oxidative stress induced by conventional and self-ligating brackets.

  The Angle orthodontist 20120301

• Theoretical investigations on electronic spectra and the redox-switchable second-order nonlinear optical responses of rhodium(I)-9,10-phenanthrenediimine complexes.

  Journal of molecular graphics & modelling 20120301

• [RhIIICp*]-catalyzed dehydrogenative aryl-aryl bond formation.

  Angewandte Chemie (International ed. in English) 20120227

• Regioselective synthesis of 1,2-dihydropyridines by rhodium-catalyzed hydroboration of pyridines.

  Journal of the American Chemical Society 20120227

• Diastereoselective rhodium-catalyzed ene-cycloisomerization reactions of alkenylidenecyclopropanes: total synthesis of (-)-α-kainic acid.

  Journal of the American Chemical Society 20120227

• Chemoenzymatic synthesis of a mixed phosphine-phosphine oxide catalyst and its application to asymmetric allylation of aldehydes and hydrogenation of alkenes.

  Organic & biomolecular chemistry 20120221

• Rhodium-catalyzed 1,3-acyloxy migration and subsequent intramolecular [4+2] cycloaddition of vinylallene and unactivated alkyne.

  Chemical communications (Cambridge, England) 20120221

• Rhodium-catalyzed and zinc(II)-triflate-promoted asymmetric hydrogenation of tetrasubstituted α,β-unsaturated ketones.

  Organic letters 20120217

• Reaction pathways of Rh+ (3F and 1D) with CH3OCH3 in the gas phase.

  Rapid communications in mass spectrometry : RCM 20120215

• Aryl methyl sulfides as substrates for rhodium-catalyzed alkyne carbothiolation: arene functionalization with activating group recycling.

  Journal of the American Chemical Society 20120215

• Cooperative ligand effects in phase-switching homogeneous catalysts.

  Angewandte Chemie (International ed. in English) 20120213

• Tandem Rh(III)-catalyzed oxidative acylation of secondary benzamides with aldehydes and intramolecular cyclization: the direct synthesis of 3-hydroxyisoindolin-1-ones.

  Organic letters 20120203

• Rhodium-catalyzed xanthone formation from 2-aryloxybenzaldehydes via cross-dehydrogenative coupling (CDC).

  Organic letters 20120203

• Rhodium-catalyzed cleavage reaction of aryl methyl ethers with thioesters.

  Organic letters 20120203

• Rhodium-catalyzed redox allylation reactions of ketones.

  Chemical communications (Cambridge, England) 20120201

• Oxidative amidation of aromatic ethers catalyzed by rhodium acetate.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20120123

• The role of three-center/four-electron bonds in superelectrophilic dirhodium carbene and nitrene catalytic intermediates.

  Dalton transactions (Cambridge, England : 2003) 20120121

• N-Directing group assisted rhodium-catalyzed aryl C-H addition to aryl aldehydes.

  Organic letters 20120120

• Asymmetric Rh(I)-catalyzed intramolecular [3 + 2] cycloaddition of 1-yne-vinylcyclopropanes for bicyclo[3.3.0] compounds with a chiral quaternary carbon stereocenter and density functional theory study of the origins of enantioselectivity.

  Journal of the American Chemical Society 20120111

• Chiral ammonium-capped rhodium(0) nanocatalysts: synthesis, characterization, and advances in asymmetric hydrogenation in neat water.

  ChemSusChem 20120109

• Highly regioselective isomerization-hydroaminomethylation of internal olefins catalyzed by Rh complex with Tetrabi-type phosphorus ligands.

  Organic letters 20120106

• One-pot synthesis of isoquinolinium salts by rhodium-catalyzed C-H bond activation: application to the total synthesis of oxychelerythrine.

  Angewandte Chemie (International ed. in English) 20120102

• Enhanced Pd pillared clays by Rh inclusion for the catalytic hydrodechlorination of chlorophenols in water.

  Water science and technology : a journal of the International Association on Water Pollution Research 20120101

• Degradation of azo dye with dirhodium(II) caprolactamate as heterogeneous catalyst.

  Water science and technology : a journal of the International Association on Water Pollution Research 20120101

• Potential of gold nanoparticles for oxidation in fine chemical synthesis.

  Annual review of chemical and biomolecular engineering 20120101

• Stripping voltammetric determination of palladium, platinum and rhodium in freshwater and sediment samples from South African water resources.

  Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering 20120101

• Selective cytotoxicity of rhodium metalloinsertors in mismatch repair-deficient cells.

  Biochemistry 20111220

• Total synthesis of (-)-virginiamycin M2: application of crotylsilanes accessed by enantioselective Rh(II) or Cu(I) promoted carbenoid Si-H insertion.

  The Journal of organic chemistry 20111216

• Highly regioselective hydroaminomethylation of terminal olefins to linear amines using Rh complexes with a Tetrabi phosphorus ligand.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20111216

• Total synthesis of sialic acid by a sequential rhodium-catalyzed aziridination and Barbier allylation of D-glycal.

  Angewandte Chemie (International ed. in English) 20111209

• Stitching phospholanes together piece by piece: new modular di- and tridentate stereodirecting ligands.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20111209

• Unravelling the mechanism of glycerol hydrogenolysis over rhodium catalyst through combined experimental-theoretical investigations.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20111209

• Insight into the photoinduced ligand exchange reaction pathway of cis-[Rh2(μ-O2CCH3)2(CH3CN)6]2+ with a DNA model chelate.

  Inorganic chemistry 20111205

• Quantitative trace analysis of benzene using an array of plasma-treated metal-decorated carbon nanotubes and fuzzy adaptive resonant theory techniques.

  Analytica chimica acta 20111205

• D2-symmetric dirhodium catalyst derived from a 1,2,2-triarylcyclopropanecarboxylate ligand: design, synthesis and application.

  Journal of the American Chemical Society 20111130

• Selective hydroformylation-hydrogenation tandem reaction of isoprene to 3-methylpentanal.

  Dalton transactions (Cambridge, England : 2003) 20111128

• Rhodium(III)-catalyzed oxidative carbonylation of benzamides with carbon monoxide.

  Chemical communications (Cambridge, England) 20111128

• Pyridine synthesis from oximes and alkynes via rhodium(III) catalysis: Cp* and Cp(t) provide complementary selectivity.

  Chemical communications (Cambridge, England) 20111121

• Synthesis of isochromene and related derivatives by rhodium-catalyzed oxidative coupling of benzyl and allyl alcohols with alkynes.

  The Journal of organic chemistry 20111118

• Chiral allene-containing phosphines in asymmetric catalysis.

  Journal of the American Chemical Society 20111116

• Mechanistic studies of O2 reduction effected by group 9 bimetallic hydride complexes.

  Journal of the American Chemical Society 20111109

• Unravelling the reaction path of rhodium-MonoPhos-catalysed olefin hydrogenation.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20111104

• Rhodium-catalyzed annulation of N-benzoylsulfonamide with isocyanide through C-H activation.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20111104

• A general synthesis of dirhodium metallopeptides as MDM2 ligands.

  Chemical communications (Cambridge, England) 20111021

• Stereoselective rhodium-catalyzed amination of alkenes.

  Organic letters 20111021

• Zinc-catalyzed allenylations of aldehydes and ketones.

  Organic letters 20111021

• Synthesis of α,α-disubstituted aryl amines by rhodium-catalyzed amination of tertiary allylic trichloroacetimidates.

  Organic letters 20111021

• Asymmeric formal [3 + 3]-cycloaddition reactions of nitrones with electrophilic vinylcarbene intermediates.

  Journal of the American Chemical Society 20111019

• Mesoionic thiazol-5-ylidenes as ligands for transition metal complexes.

  Chemical communications (Cambridge, England) 20111014

• Optimizing dirhodium(II) tetrakiscarboxylates as chiral NMR auxiliaries.

  Organic & biomolecular chemistry 20111007

• Rhodium-catalyzed cross-coupling reaction of arylboronates and diazoesters and tandem alkylation reaction for the synthesis of quaternary α,α-heterodiaryl carboxylic esters.

  Organic letters 20111007

• Addition of arylboronic acids to arylpropargyl alcohols en route to indenes and quinolines.

  Organic letters 20111007

• Sensitive and selective chromogenic sensing of carbon monoxide via reversible axial CO coordination in binuclear rhodium complexes.

  Journal of the American Chemical Society 20111005

• Highly enantioselective rhodium-catalyzed asymmetric 1,4-addition reactions of arylboronic acids to acyclic α,β-unsaturated compounds: the formal synthesis of (-)-indatraline.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20111004

• Synthesis of indolizidines from optically pure α-amino acids via stereocontrolled rhodium-catalyzed hydroformylation of N-allylpyrroles.

  Chirality 20111001

• Reactivity of N-(1,2,4-triazolyl)-substituted 1,2,3-triazoles.

  Organic letters 20110916

• Rhodium-catalyzed olefin isomerization/enantioselective intramolecular Alder-ene reaction cascade.

  Organic letters 20110916

• Rearrangement of 2-aryloxybenzaldehydes to 2-hydroxybenzophenones by rhodium-catalyzed cleavage of aryloxy C-O bonds.

  Angewandte Chemie (International ed. in English) 20110912

• Bis(metallo) capsules based on two ionic diphosphines.

  Chemistry, an Asian journal 20110905

• Synthesis of 1-aminoisoquinolines via Rh(III)-catalyzed oxidative coupling.

  Organic letters 20110902

• Computational prediction of selectivities in nonreversible and reversible hydroformylation reactions catalyzed by unmodified rhodium-carbonyls.

  Journal of molecular modeling 20110901

• Application of a new amidophosphite ligand to Rh-catalyzed asymmetric hydrogenation of β-dehydroamino acid derivatives in supercritical carbon dioxide: activation effect of protic Co-solvents.

  Chirality 20110901

• New investigations of technical rhodium and iridium catalysts in homogeneous phase employing para-hydrogen induced polarization.

  Solid state nuclear magnetic resonance 20110901

• Interception of a Rautenstrauch intermediate by alkynes for [5+2] cycloaddition: rhodium-catalyzed cycloisomerization of 3-acyloxy-4-ene-1,9-diynes to bicyclo[5.3.0]decatrienes.

  Angewandte Chemie (International ed. in English) 20110822

• Synthesis of the anti-HIV agent (-)-hyperolactone C by using oxonium ylide formation-rearrangement.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20110822

• Theoretical studies on the mechanism and stereoselectivity of Rh(Phebox)-catalyzed asymmetric reductive aldol reaction.

  Organic & biomolecular chemistry 20110821

• Room-temperature Rh-catalyzed asymmetric 1,4-addition of arylboronic acids to maleimides and enones in the presence of CF3-substituted MeOBIPHEP analogues.

  The Journal of organic chemistry 20110819

• Rhodium-catalyzed oxidative ortho-acylation of benzamides with aldehydes: direct functionalization of the sp2 C-H bond.

  Organic letters 20110819

• Highly enantioselective arylation of N-tosylalkylaldimines catalyzed by rhodium-diene complexes.

  Journal of the American Chemical Society 20110817

• Combined C-H functionalization/Cope rearrangement with vinyl ethers as a surrogate for the vinylogous Mukaiyama aldol reaction.

  Journal of the American Chemical Society 20110810

• Chiral sulfoxide-olefin ligands: completely switchable stereoselectivity in rhodium-catalyzed asymmetric conjugate additions.

  Angewandte Chemie (International ed. in English) 20110808

• Hydroboration of an alkene by amine-boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation.

  Dalton transactions (Cambridge, England : 2003) 20110807

• Synthesis of azaheterocycles from aryl ketone O-acetyl oximes and internal alkynes by Cu-Rh bimetallic relay catalysts.

  The Journal of organic chemistry 20110805

• Expedient synthesis of N-acyl anthranilamides and β-enamine amides by the Rh(III)-catalyzed amidation of aryl and vinyl C-H bonds with isocyanates.

  Journal of the American Chemical Society 20110803

• Antileukemic activity and cellular effects of rhodium(III) crown thiaether complexes.

  Biometals : an international journal on the role of metal ions in biology, biochemistry, and medicine 20110801

• Factors affecting the electrochemical regeneration of NADH by (2,2'-bipyridyl) (pentamethylcyclopentadienyl)-rhodium complexes: impact on their immobilization onto electrode surfaces.

  Bioelectrochemistry (Amsterdam, Netherlands) 20110801

• Macrocyclization of oxetane building blocks with diazocarbonyl derivatives under rhodium(II) catalysis.

  Angewandte Chemie (International ed. in English) 20110801

• Profiling the tuneable R-SMS-Phos structure in the rhodium(I)-catalyzed hydrogenation of olefins: the last stand?

  Organic & biomolecular chemistry 20110721

• Control of selectivity in the generation and reactions of oxonium ylides.

  Chemical communications (Cambridge, England) 20110721

• Highly enantioselective cyclopropenation reaction of 1-alkynes with α-alkyl-α-diazoesters catalyzed by dirhodium(II) carboxylates.

  Angewandte Chemie (International ed. in English) 20110718

• Hydride mobility in trinuclear sulfido clusters with the core [Rh3(μ-H)(μ3-S)2]: molecular models for hydrogen migration on metal sulfide hydrotreating catalysts.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20110711

• Highly cytotoxic substitutionally inert rhodium(III) tris(chelate) complexes: DNA binding modes and biological impact on human cancer cells.

  Journal of inorganic biochemistry 20110701

• The development of Laue techniques for single-pulse diffraction of chemical complexes: time-resolved Laue diffraction on a binuclear rhodium metal-organic complex.

  Acta crystallographica. Section A, Foundations of crystallography 20110701

• Enantioselective addition of allyltin reagents to amino aldehydes catalyzed with bis(oxazolinyl)phenylrhodium(III) aqua complexes.

  Molecules (Basel, Switzerland) 20110627

• Solvent enhancement of reaction selectivity: a unique property of cationic chiral dirhodium carboxamidates.

  Journal of the American Chemical Society 20110622

• Synthesis of β- and γ-carbolines via ruthenium and rhodium catalysed [2+2+2] cycloadditions of yne-ynamides with methylcyanoformate.

  Chemical communications (Cambridge, England) 20110621

• Asymmetric Rh(II)-catalyzed cyclopropanation of alkenes with diacceptor diazo compounds: p-methoxyphenyl ketone as a general stereoselectivity controlling group.

  Journal of the American Chemical Society 20110615

• Relationship between electrochemical potentials and substitution reaction rates of ferrocene-containing β-diketonato rhodium(I) complexes; cytotoxicity of [Rh(FcCOCHCOPh)(cod)].

  Dalton transactions (Cambridge, England : 2003) 20110614

• Diastereoselectively switchable enantioselective trapping of carbamate ammonium ylides with imines.

  Journal of the American Chemical Society 20110608

• Rhodium-catalyzed decarboxylative cycloaddition route to substituted anilines.

  The Journal of organic chemistry 20110603

• Burkavidin: a novel secreted biotin-binding protein from the human pathogen Burkholderia pseudomallei.

  Protein expression and purification 20110601

• Adamantanes as spherical nanosondes in adducts with a chiral dirhodium complex-discriminating enantiomers and probing spatial proximities.

  Magnetic resonance in chemistry : MRC 20110601

• Enantioselective total synthesis of aperidine.

  Organic letters 20110520

• Rhodium-catalyzed selective olefination of arene esters via C-H bond activation.

  Organic letters 20110506

• Rhodium-catalyzed highly enantioselective addition of arylboronic acids to 2-nitrostyrenes by tert-butanesulfinylphosphine ligand.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20110502

• Immobilization of urease on nanostructured polymer membrane and preparation of urea amperometric biosensor.

  International journal of biological macromolecules 20110501

• Preparation, characterization and pH-metric measurements of 4-hydroxysalicylidenechitosan Schiff-base complexes of Fe(III), Co(II), Ni(II), Cu(II), Zn(II), Ru(III), Rh(III), Pd(II) and Au(III).

  Carbohydrate research 20110501

• Metalloradical-catalyzed rearrangement of cycloheptatrienyl to benzyl.

  Chemical communications (Cambridge, England) 20110428

• Selectivity manipulation of bicyclization reactions of 1,5-bis(1,2-allenylketone)s: Pd versus Rh and electronic effect.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20110426

• Regioselective synthesis of indenols by rhodium-catalyzed C-H activation and carbocyclization of aryl ketones and alkynes.

  Angewandte Chemie (International ed. in English) 20110426

• Interconversion between formic acid and H(2)/CO(2) using rhodium and ruthenium catalysts for CO(2) fixation and H(2) storage.

  ChemSusChem 20110418

• Hydrogen and methanol exchange processes for (TMP)Rh-OCH3(CH3OH) in binary solutions of methanol and benzene.

  Inorganic chemistry 20110418

• Isolation, characterization, and DNA binding kinetics of three dirhodium(II,II) carboxyamidate complexes: Rh2(μ-L)(HNOCCF3)3 where L= [OOCCH3]-, [OOCCF3]-, or [HNOCCF3]-.

  Inorganic chemistry 20110418

• High turnover in a photocatalytic system for water reduction to produce hydrogen using a Ru,  Rh,  Ru photoinitiated electron collector.

  ChemSusChem 20110418

• Development of amperometric α-ketoglutarate biosensor based on ruthenium-rhodium modified carbon fiber enzyme microelectrode.

  Biosensors & bioelectronics 20110415

• Dirhodium-catalyzed phenol and aniline oxidations with T-HYDRO. Substrate scope and mechanism of oxidation.

  The Journal of organic chemistry 20110415

• Highly cis-selective Rh(I)-catalyzed cyclopropanation reactions.

  The Journal of organic chemistry 20110415

• Highly enantioselective and efficient synthesis of flavanones including pinostrobin through the rhodium-catalyzed asymmetric 1,4-addition.

  Organic letters 20110415

• Sequential aldol condensation-transition metal-catalyzed addition reactions of aldehydes, methyl ketones, and arylboronic acids.

  Organic letters 20110415

• Zeolite-supported rhodium complexes and clusters: switching catalytic selectivity by controlling structures of essentially molecular species.

  Journal of the American Chemical Society 20110406

• Rh2(II)-catalyzed nitro-group migration reactions: selective synthesis of 3-nitroindoles from β-nitro styryl azides.

  Journal of the American Chemical Society 20110406

• Conformational studies on chiral rhodium complexes by ECD and VCD spectroscopy.

  Chirality 20110401

• o-Semiquinonato and o-iminosemiquinonato rhodium complexes. EPR study of the reactions in coordination sphere of rhodium.

  Journal of magnetic resonance (San Diego, Calif. : 1997) 20110401

• Rhodium(II) acetate-catalyzed stereoselective synthesis, SAR and anti-HIV activity of novel oxindoles bearing cyclopropane ring.

  European journal of medicinal chemistry 20110401

• The coupling of arylboronic acids with nitroarenes catalyzed by rhodium.

  Organic letters 20110401

• Dihydropyranone formation by ipso C-H activation in a glucal 3-carbamate-derived rhodium acyl nitrenoid.

  The Journal of organic chemistry 20110401

• Mechanism and origins of regio- and enantioselectivities in RhI-catalyzed hydrogenative couplings of 1,3-diynes and activated carbonyl partners: intervention of a cumulene intermediate.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20110328

• Kinetico-mechanistic studies of the acidolysis of Rh-C bonds in monocyclometallated dirhodium(II) acetato complexes; influence of electronic and steric effects.

  Dalton transactions (Cambridge, England : 2003) 20110321

• Study of the conformationally flexible, wide bite-angle diphosphine 4,6-bis(3-diisopropylphosphinophenyl)dibenzofuran in rhodium(I) and palladium(II) coordination complexes.

  Inorganic chemistry 20110321

• Synthesis of the cytotrienin A core via metal catalyzed C-C coupling.

  Organic letters 20110318

• Aliphatic C-H to C-C conversion: synthesis of (-)-cameroonan-7α-ol.

  The Journal of organic chemistry 20110318

• Rhodium-catalyzed enantioselective addition of boronic acids to N-benzylnicotinate salts.

  Journal of the American Chemical Society 20110309

• Cellular selectivity and biological impact of cytotoxic rhodium(III) and iridium(III) complexes containing methyl-substituted phenanthroline ligands.

  ChemMedChem 20110307

• Catalytic thia-Sommelet-Hauser rearrangement: application to the synthesis of oxindoles.

  Organic letters 20110304

• Stereocontrolled synthesis of (+)-methoxyphenylkainic acid and (+)-phenylkainic acid.

  Organic letters 20110304

• O-substituted alkyl aldehydes for rhodium-catalyzed intermolecular alkyne hydroacylation: the utility of methylthiomethyl ethers.

  Organic letters 20110304

• Rh(III)-catalyzed directed C-H olefination using an oxidizing directing group: mild, efficient, and versatile.

  Journal of the American Chemical Society 20110302

• Redox-neutral atom-economic rhodium-catalyzed coupling of terminal alkynes with carboxylic acids toward branched allylic esters.

  Journal of the American Chemical Society 20110302

• Rhodium-catalyzed 1,4-addition of lithium 2-furyltriolborates to unsaturated ketones and esters for enantioselective synthesis of γ-oxo-carboxylic acids by oxidation of the furyl ring with ozone.

  Chemistry, an Asian journal 20110301

• Diverse strategies toward indenol and fulvene derivatives: Rh-catalyzed C-H activation of aryl ketones followed by coupling with internal alkynes.

  Journal of the American Chemical Society 20110223

• C-H activation of 2,4,6-triphenylphosphinine: unprecedented formation of cyclometalated [(P^C)Ir(III)] and [(P^C)Rh(III)] complexes.

  Chemical communications (Cambridge, England) 20110221

• Asymmetric synthesis of β-substituted γ-lactams via rhodium/diene-catalyzed 1,4-additions: application to the synthesis of (R)-baclofen and (R)-rolipram.

  Organic letters 20110218

• Rhodium-catalyzed synthesis of 2,3-disubstituted indoles from β,β-disubstituted stryryl azides.

  Angewandte Chemie (International ed. in English) 20110211

• Exploring a reaction mechanism for acetato ligand replacement in paddlewheel tetrakisacetatodirhodium (II,II) complex by ammonia: computational density functional theory study.

  The journal of physical chemistry. A 20110210

• Rhodium(III)-catalyzed arylation of Boc-imines via C-H bond functionalization.

  Journal of the American Chemical Society 20110209

• The vinyl moiety as a handle for regiocontrol in the preparation of unsymmetrical 2,3-aliphatic-substituted indoles and pyrroles.

  Angewandte Chemie (International ed. in English) 20110207

• Synthesis of highly functionalized cyclohexenone rings: rhodium-catalyzed 1,3-acyloxy migration and subsequent [5+1] cycloaddition.

  Angewandte Chemie (International ed. in English) 20110207

• Telomestatin: formal total synthesis and cation-mediated interaction of its seco-derivatives with G-quadruplexes.

  Journal of the American Chemical Society 20110202

• Asymmetric transfer hydrogenation of prochiral ketones in aqueous media with chiral water-soluble and heterogenized bifunctional catalysts of the RhCp*-type ligand.

  Chirality 20110201

• Ionic liquid ultrasound assisted dispersive liquid-liquid microextraction method for preconcentration of trace amounts of rhodium prior to flame atomic absorption spectrometry determination.

  Journal of hazardous materials 20110130

• Stereoselective coordination of C5-symmetric corannulene derivatives with an enantiomerically pure [Rh(I)(nbd*)] metal complex.

  Angewandte Chemie (International ed. in English) 20110124

• Artificial metalloenzymes based on the biotin-avidin technology: enantioselective catalysis and beyond.

  Accounts of chemical research 20110118

• Photocatalytic production of hydrogen by disproportionation of one-electron-reduced rhodium and iridium-ruthenium complexes in water.

  Angewandte Chemie (International ed. in English) 20110117

• Cooperative catalysis in highly enantioselective Mannich-type three-component reaction of a diazoacetophenone with an alcohol and an imine.

  Chemical communications (Cambridge, England) 20110114

• Rh-catalyzed [7 + 1] cycloaddition of buta-1,3-dienylcyclopropanes and CO for the synthesis of cyclooctadienones.

  Organic letters 20110107

• Design and synthesis of α-carboxy phosphononucleosides.

  The Journal of organic chemistry 20110107

• Synthetic and mechanistic pathways of cis and trans-hydroxytamoxifen drug derivatives reacting with Cp*Rh complexes that involve η1-N, η2-N,O, η1-O, and η6 bonding modes, via a novel N-π rearrangement; relative binding affinities and computer docking studies of cis and trans-η6-Cp*Rh-hydroxytamoxifen complexes at the estrogen, ERα and ERβ receptors, and growth inhibition to breast cancer cells.

  Inorganic chemistry 20110103

• Tetradentate bis-phosphine ligands (P(2)N(2) and P(2)S(2)) and their Rh(III), Ni(II) and (105)Rh complexes: X-ray crystal structures of trans-[RhCl(2)(L2)]PF(6), [Ni(L2)](PF(6))(2) and μ-O(2)SO(2)-[Ni(L5)](2)(PF(6))(2).

  Nuclear medicine and biology 20110101

• Free Rhodium (II) citrate and rhodium (II) citrate magnetic carriers as potential strategies for breast cancer therapy.

  Journal of nanobiotechnology 20110101

• Chirality responsive helical poly(phenylacetylene) bearing L-proline pendants.

  Chirality 20110101

• Highly selective rhodium catalyzed domino C-H activation/cyclizations.

  Chimia 20110101

• Rhodium(III)-catalyzed arene and alkene C-H bond functionalization leading to indoles and pyrroles.

  Journal of the American Chemical Society 20101229

• C2-symmetric chiral disulfoxide ligands in rhodium-catalyzed 1,4-addition: from ligand synthesis to the enantioselection pathway.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20101227

• Comparing the enantioselective power of steric and electrostatic effects in transition-metal-catalyzed asymmetric synthesis.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20101227

• Mechanistically driven development of iridium catalysts for asymmetric allylic substitution.

  Accounts of chemical research 20101221

• Concise synthesis of the Erythrina alkaloid 3-demethoxyerythratidinone via combined rhodium catalysis.

  Organic letters 20101217

• Design and synthesis of cyclic sulfonamides and sulfamates as new calcium sensing receptor agonists.

  Bioorganic & medicinal chemistry letters 20101215

• Design and synthesis of a novel three-hindered quadrant bisphosphine ligand and its application in asymmetric hydrogenation.

  Chemical communications (Cambridge, England) 20101207

• Solid-state (15)N CPMAS NMR and computational analysis of ligand hapticity in rhodium(η-diene) poly(pyrazolyl)borate complexes.

  Inorganic chemistry 20101206

• Synthesis of 2-pyridones and iminoesters via Rh(III)-catalyzed oxidative coupling between acrylamides and alkynes.

  Organic letters 20101203

• Di- and trisubstituted γ-lactams via Rh(II)-carbenoid reaction of N-Cα-branched, N-bis(trimethylsilyl)methyl α-diazoamides. Synthesis of (±)-α-allokainic acid.

  Organic letters 20101203

• Hydride ion-carrier ability in Rh(I) complexes of a nicotinamide-functionalised N-heterocyclic carbene ligand.

  Dalton transactions (Cambridge, England : 2003) 20101128

• Enantioselective desymmetrization of cyclopropenes by hydroacylation.

  Journal of the American Chemical Society 20101124

• N-methylephedrium salts as chiral surfactants for asymmetric hydrogenation in neat water with rhodium(0) nanocatalysts.

  ChemSusChem 20101122

• Rhodium-catalysed conjugate addition of arylboronic acids to enantiopure dehydroamino acid derivatives.

  Organic & biomolecular chemistry 20101121

• Linear-selective rhodium(I)-catalyzed addition of arylboronic acids to allyl sulfones.

  Angewandte Chemie (International ed. in English) 20101115

• The complexation of rhodium(III) with acyclic diaminedithioether (DADTE) ligands.

  Dalton transactions (Cambridge, England : 2003) 20101114

• Catalytic asymmetric dihydroxylation of enamides and application to the total synthesis of (+)-tanikolide.

  Angewandte Chemie (International ed. in English) 20101108

• Rh-catalyzed oxidative coupling between primary and secondary benzamides and alkynes: synthesis of polycyclic amides.

  The Journal of organic chemistry 20101105

• Concise and enantioselective total synthesis of 15-deoxy-Δ-(12,14)-prostaglandin J(2).

  The Journal of organic chemistry 20101105

• Seedless polyol synthesis and CO oxidation activity of monodisperse (111)- and (100)-oriented rhodium nanocrystals in sub-10 nm sizes.

  Langmuir : the ACS journal of surfaces and colloids 20101102

• Trapping unstable benzoquinone analogues by coordination to a [(η(5)-C(5)Me(5))Ir] fragment and the anticancer activity of the resulting complexes.

  Angewandte Chemie (International ed. in English) 20101102

• Probing the stereo-electronic properties of cationic rhodium complexes bearing chiral diphosphine ligands by 103Rh NMR.

  Magnetic resonance in chemistry : MRC 20101101

• Asymmetric transfer hydrogenation of ketones catalyzed by rhodium complexes containing amino acid triazole ligands.

  Organic & biomolecular chemistry 20101021

• Rhodium-catalyzed regioselective amination of secondary allylic trichloroacetimidates with unactivated aromatic amines.

  Organic letters 20101015

• Comparison of Rh-OCH3 and Rh-CH2OH bond dissociation energetics from methanol C-H and O-H bond reactions with rhodium(II) porphyrins.

  Journal of the American Chemical Society 20101006

• Intramolecular hydroamination of unbiased and functionalized primary aminoalkenes catalyzed by a rhodium aminophosphine complex.

  Journal of the American Chemical Society 20101006

• Rhodium-catalyzed organothio exchange reaction of α-organothioketones with disulfides.

  Chemical & pharmaceutical bulletin 20101001

• Synthesis of hybrid transition-metalloproteins via thiol-selective covalent anchoring of Rh-phosphine and Ru-phenanthroline complexes.

  Dalton transactions (Cambridge, England : 2003) 20100928

• An approach to bimetallic catalysts by ligand design.

  Dalton transactions (Cambridge, England : 2003) 20100928

• Stereoselective synthesis of vinyl-substituted (Z)-stilbenes by rhodium-catalysed addition of arylboronic acids to allenic alcohols.

  Organic & biomolecular chemistry 20100921

• Utilization of aldoses as a carbonyl source in cyclocarbonylation of enynes.

  The Journal of organic chemistry 20100917

• Aerobic oxidation of alcohols catalyzed by rhodium(III) porphyrin complexes in water: reactivity and mechanistic studies.

  Chemical communications (Cambridge, England) 20100914

• Catalyst-controlled formal [4 + 3] cycloaddition applied to the total synthesis of (+)-barekoxide and (-)-barekol.

  Journal of the American Chemical Society 20100908

• Catalytic asymmetric synthesis of the endo-6-aryl-8-oxabicyclo[3.2.1]oct-3-en-2-one natural product from Ligusticum chuanxing via 1,3-dipolar cycloaddition of a formyl-derived carbonyl ylide using Rh2(S-TCPTTL)4.

  The Journal of organic chemistry 20100903

• Enantioselective formal synthesis of (-)-englerin A via a Rh-catalyzed [4 + 3] cycloaddition reaction.

  Organic letters 20100820

• Synthesis and structural characterization of binuclear half-sandwich iridium, rhodium and ruthenium complexes containing 4,4'-dipyridyldisulfide (4DPDS) ligands.

  Dalton transactions (Cambridge, England : 2003) 20100814

• Synthesis of the guaianolide ring system via cycloaddition of a bicyclic carbonyl ylide with allyl propiolate.

  Organic letters 20100806

• Origin of pressure effects on regioselectivity and enantioselectivity in the rhodium-catalyzed hydroformylation of styrene with (S,S,S)-BisDiazaphos.

  Journal of the American Chemical Society 20100804

• Rhodium-catalyzed oxidative cycloaddition of benzamides and alkynes via C-H/N-H activation.

  Journal of the American Chemical Society 20100804

• Solvent and temperature induced switching between structural isomers of Rh(I) phosphinoalkyl thioether (PS) complexes.

  Inorganic chemistry 20100802

• Regiodivergent ligand-controlled rhodium-catalyzed [(2+2)+2] carbocyclization reactions with alkyl substituted methyl propiolates.

  Angewandte Chemie (International ed. in English) 20100802

• Rhodium-catalyzed asymmetric conjugate addition of organoboronic acids to nitroalkenes using chiral bicyclo[3.3.0] diene ligands.

  Angewandte Chemie (International ed. in English) 20100802

• Rh catalyzed olefination and vinylation of unactivated acetanilides.

  Journal of the American Chemical Society 20100728

• Versatile new C(3)-symmetric tripodal tetraphosphine ligands; structural flexibility to stabilize Cu(I) and Rh(I) species and tune their reactivity.

  Inorganic chemistry 20100719

• A rhodium IBiox[(-)-menthyl] complex as a highly selective catalyst for the asymmetric hydroarylation of azabicyles: an alternative route to epibatidine.

  Organic letters 20100716

• Metallopeptides for asymmetric dirhodium catalysis.

  Journal of the American Chemical Society 20100714

• Cell-selective, apoptosis-inducing rhodium(III) crown thiaether complexes.

  ChemMedChem 20100705

• Hydrogenolysis of 1,2-propanediol for the production of biopropanols from glycerol.

  ChemSusChem 20100621

• Photophysical properties, DNA photocleavage, and photocytotoxicity of a series of dppn dirhodium(II,II) complexes.

  Inorganic chemistry 20100621

• Tunable aqueous phase synthesis and shape-dependent electrochemical properties of rhodium nanostructures.

  Inorganic chemistry 20100621

• Solid-state NMR characterization of Wilkinson's catalyst immobilized in mesoporous SBA-3 silica.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20100618

• Helix induction by dirhodium: access to biocompatible metallopeptides with defined secondary structure.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20100611

• Rhodium-catalyzed linear codimerization and cycloaddition of ketenes with alkynes.

  Molecules (Basel, Switzerland) 20100609

• Rhodium-catalyzed cyclopropenation of alkynes: synthesis of trifluoromethyl-substituted cyclopropenes.

  Angewandte Chemie (International ed. in English) 20100607

• Design of luminescent biotinylation reagents derived from cyclometalated iridium(III) and rhodium(III) bis(pyridylbenzaldehyde) complexes.

  Inorganic chemistry 20100607

• Regioselective rhodium(I)-catalyzed hydroarylation of protected allylic amines with arylboronic acids.

  Organic letters 20100604

• Chiral Induction by cinchona alkaloids in the rhodium(II) catalyzed O-H insertion reaction.

  Chemical & pharmaceutical bulletin 20100601

• Rhodium(III)-catalyzed isoquinolone synthesis: the N-O bond as a handle for C-N bond formation and catalyst turnover.

  Journal of the American Chemical Society 20100526

• Chiral 1-phenylethylamine-derived phosphine-phosphoramidite ligands for highly enantioselective Rh-catalyzed hydrogenation of beta-(acylamino)acrylates: significant effect of substituents on 3,3'-positions of binaphthyl moiety.

  Organic & biomolecular chemistry 20100521

• Structure-selective modification of aromatic side chains with dirhodium metallopeptide catalysts.

  Journal of the American Chemical Society 20100519

• Rh(I)-catalyzed cycloisomerization of vinyl bicyclopropyl compounds to azabicyclo[3.2.2]nona-2,8-dienes.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20100510

• Highly efficient Rh(I)-catalyzed asymmetric hydrogenation of beta-amino acrylonitriles.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20100510

• Rhodium-catalyzed cascade reaction: aryl addition/intramolecular esterification to access 3-aryl and 3-alkenyl phthalides.

  Angewandte Chemie (International ed. in English) 20100510

• Rhodium-catalyzed oxidative coupling/cyclization of 2-phenylindoles with alkynes via C-H and N-H bond cleavages with air as the oxidant.

  Organic letters 20100507

• Asymmetric Rh(I)-catalyzed addition of MIDA boronates to N-tert-butanesulfinyl aldimines: development and comparison to trifluoroborates.

  The Journal of organic chemistry 20100507

• A recyclable nanoparticle-supported rhodium catalyst for hydrogenation reactions.

  Molecules (Basel, Switzerland) 20100505

• Rh(II)-catalyzed reaction of alpha-diazocarbonyl compounds bearing beta-trichloroacetylamino substituent: C-H insertion versus 1,2-H shift.

  Chemistry, an Asian journal 20100503

• Rhodium(I)-catalyzed intramolecular carbonylative [2+2+1] cycloadditions and cycloisomerizations of bis(sulfonylallene)s.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20100503

• The intramolecular amination of allenes.

  Chemical communications (Cambridge, England) 20100428

• Synthesis and application of tetraphosphane ligands in rhodium-catalyzed hydroformylation of terminal olefins: high regioselectivity at high temperature.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20100426

• Conjugated diene-assisted allylic C-H bond activation: cationic Rh(I)-catalyzed syntheses of polysubstituted tetrahydropyrroles, tetrahydrofurans, and cyclopentanes from ene-2-dienes.

  Journal of the American Chemical Society 20100407

• Rhodium-catalyzed [2+2+2] cycloaddition of various fluorine-containing alkynes--novel synthesis of multi-substituted fluoroalkylated aromatic compounds.

  Organic & biomolecular chemistry 20100407

• A C(2)-symmetric chiral bis-sulfoxide ligand in a rhodium-catalyzed reaction: asymmetric 1,4-addition of sodium tetraarylborates to chromenones.

  Journal of the American Chemical Society 20100407

• Rhodium(NHC)-catalyzed amination of aryl bromides.

  Organic letters 20100402

• Synthesis of naphtho[1,8-bc]pyran derivatives and related compounds through hydroxy group directed C-H bond cleavage under rhodium catalysis.

  Chemistry, an Asian journal 20100401

• Chemoenzymatic synthesis and application of bicyclo[2.2.2]octadiene ligands: increased efficiency in rhodium-catalyzed asymmetric conjugate additions by electronic tuning.

  Angewandte Chemie (International ed. in English) 20100401

• Surface and catalytic elucidation of Rh/gamma-Al2O3 catalysts during NO reduction by C3H8 in the presence of excess O2, H2O, and SO2.

  The journal of physical chemistry. A 20100325

• Crystal transformation and host molecular motions in CO2 adsorption process of a metal benzoate pyrazine (M(II) = Rh, Cu).

  Journal of the American Chemical Society 20100324

• Characterization of a rhodium-sparteine complex, [((-)-sparteine)Rh(eta4-COD)]+: crystal structure and DNMR/DFT studies on ligand-rotation dynamics.

  Dalton transactions (Cambridge, England : 2003) 20100321

• Asymmetric synthesis and photophysical properties of benzopyrano- or naphthopyrano-fused helical phosphafluorenes.

  Organic letters 20100319

• Origins of the selectivity for borylation of primary over secondary C-H bonds catalyzed by Cp*-rhodium complexes.

  Journal of the American Chemical Society 20100310

• Rhodium carbenoid approach for introduction of 4-substituted (Z)-pent-2-enoates into sterically encumbered pyrroles and indoles.

  Organic letters 20100305

• Novel and efficient chiral bisphosphorus ligands for rhodium-catalyzed asymmetric hydrogenation.

  Organic letters 20100305

• Synthesis and reactivity of rhodium(II) N-triflyl azavinyl carbenes.

  Journal of the American Chemical Society 20100303

• Platinum, palladium, and rhodium deposition to the Prunus laurus cerasus leaf surface as an indicator of the vehicular traffic pollution in the city of Varese area: an easy and reliable method to detect PGEs released from automobile catalytic converters.

  Environmental science and pollution research international 20100301

• Optimization of cotton seed biodiesel quality (critical properties) through modification of its FAME composition by highly selective homogeneous hydrogenation.

  Bioresource technology 20100301

• Domino rhodium/palladium-catalyzed dehydrogenation reactions of alcohols to acids by hydrogen transfer to inactivated alkenes.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20100301

• Rhodium(III) and iridium(III) complexes with 1,2-naphthoquinone-1-oximate as a bidentate ligand: synthesis, structure, and biological activity.

  Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 20100301

• Diastereo- and enantioselective hydrogenation of a challenging enamide derived from 4-phenyl-2-tetralone: an appealing shortcut towards enantiopure cis-2-aminotetraline derivatives.

  Chemistry, an Asian journal 20100301

• Catalytic oxyamidation of indoles.

  Angewandte Chemie (International ed. in English) 20100222

• Large-scale asymmetric synthesis of a cathepsin S inhibitor.

  The Journal of organic chemistry 20100219

• Time-resolved electron paramagnetic resonance study of rhodium(III) corrole excited states.

  The journal of physical chemistry. A 20100211

• Base-catalyzed insertion of dioxygen into rhodium-hydrogen bonds: kinetics and mechanism.

  Inorganic chemistry 20100201

• Synthesis, substitution kinetics, and electrochemistry of the first tetrathiafulvalene-containing beta-diketonato complexes of rhodium(I).

  Inorganic chemistry 20100201

• Fully and partially coherent pathways in multiply enhanced odd-order wave-mixing spectroscopy.

  The journal of physical chemistry. A 20100121

• Rhodium-catalyzed [3 + 2] annulation of indoles.

  Journal of the American Chemical Society 20100120

• The organometallic fluorine chemistry of palladium and rhodium: studies toward aromatic fluorination.

  Accounts of chemical research 20100119

• Synthesis and application of modular phosphine-phosphoramidite ligands in asymmetric hydroformylation: structure-selectivity relationship.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20100118

• Catalytic enantioselective hydrogenation of N-alkoxycarbonyl hydrazones: a practical synthesis of chiral hydrazines.

  Organic letters 20100115

• Rhodium(I)-catalyzed intramolecular ene reaction of vinylidenecyclopropanes and alkenes for the formation of bicyclo[5.1.0]octylenes.

  Organic letters 20100101

• Novel, tunable, and efficient chiral bisdihydrobenzooxaphosphole ligands for asymmetric hydrogenation.

  Organic letters 20100101

• Rhodium carbene routes to oxazoles and thiazoles. Catalyst effects in the synthesis of oxazole and thiazole carboxylates, phosphonates, and sulfones.

  The Journal of organic chemistry 20100101

• Synthesis of methoxyfumimycin with 1,2-addition to ketimines.

  The Journal of organic chemistry 20100101

• Preparation and characterization of Rh catalyst supported on nanoporous alumina for the ethylene hydroformylation.

  Journal of nanoscience and nanotechnology 20100101

• Anticancer activity of heteroleptic diimine complexes of dirhodium: a study of intercalating properties, hydrophobicity and in cellulo activity.

  Dalton transactions (Cambridge, England : 2003) 20091228

• Highly enantioselective hetero-Diels-Alder reactions between Rawal's diene and aldehydes catalyzed by chiral dirhodium(II) carboxamidates.

  Chemical communications (Cambridge, England) 20091221

• Easy access to isoquinolines and tetrahydroquinolines from ketoximes and alkynes via rhodium-catalyzed C-H bond activation.

  The Journal of organic chemistry 20091218

• Synthesis of 1,4-dichloro-1,3-butadienes by rhodium complex catalyzed reaction of terminal alkynes with trichloroacetyl chloride.

  The Journal of organic chemistry 20091218

• Square planar bis{3,6-bis(trimethylsilyl)benzene-1,2-dithiolato}metal complexes of Cr(II), Co(III), and Rh(II): an experimental and density functional theoretical study.

  Inorganic chemistry 20091207

• Regioselective synthesis of halohydrin esters from epoxides: reaction with acyl halides and rhodium-catalyzed three-component coupling reaction with alkyl halides and carbon monoxide.

  Chemical communications (Cambridge, England) 20091207

• Synthesis of non-proteinogenic phenylalanine derivatives by rhodium-catalyzed [2+2+2] cycloaddition reactions.

  Organic & biomolecular chemistry 20091207

• Component match in rhodium catalyzed three-component reactions of ethyl diazoacetate, H2O and aryl imines: a highly diastereoselective one-step synthesis of beta-aryl isoserine derivatives.

  Organic & biomolecular chemistry 20091207

• Total synthesis of platensimycin and related natural products.

  Journal of the American Chemical Society 20091125

• Synthesis of highly substituted naphthalene and anthracene derivatives by rhodium-catalyzed oxidative coupling of arylboronic acids with alkynes.

  Organic letters 20091119

• Experimental evidence for the all-up reactive conformation of chiral rhodium(II) carboxylate catalysts: enantioselective synthesis of cis-cyclopropane alpha-amino acids.

  Journal of the American Chemical Society 20091118

• Flame atomic absorption spectrometry for the determination of trace amount of rhodium after separation and preconcentration onto modified multiwalled carbon nanotubes as a new solid sorbent.

  Talanta 20091115

• ESI-MS, DFT, and synthetic studies on the H(2)-mediated coupling of acetylene: insertion of C=X bonds into rhodacyclopentadienes and Brønsted acid cocatalyzed hydrogenolysis of organorhodium intermediates.

  Journal of the American Chemical Society 20091111

• Supramolecular NHC ligands: on the influence of Zn(II)-templates on the activity of Rh(I)(cod) complexes in 'carbene polymerization'.

  Dalton transactions (Cambridge, England : 2003) 20091107

• Rhodium-catalyzed synthesis of 3-hydroxy-beta-lactams via oxonium ylide generation: three-component reaction between azetidine-2,3-diones, ethyl diazoacetate, and alcohols.

  The Journal of organic chemistry 20091106

• Excess substrate is a spectator ligand in a rhodium-catalyzed asymmetric [2 + 2 + 2] cycloaddition of alkenyl isocyanates with tolanes.

  Organic letters 20091105

• Phthalides by rhodium-catalyzed ketone hydroacylation.

  Journal of the American Chemical Society 20091104

• Enantioselective rhodium-catalyzed [2 + 2 + 2] cycloadditions of terminal alkynes and alkenyl isocyanates: mechanistic insights lead to a unified model that rationalizes product selectivity.

  Journal of the American Chemical Society 20091104

• Rh(II)-Catalyzed skeletal reorganization of 1,6- and 1,7-enynes through electrophilic activation of alkynes.

  Journal of the American Chemical Society 20091028

• Asymmetric transfer hydrogenation of ketones catalyzed by amino acid derived rhodium complexes: on the origin of enantioselectivity and enantioswitchability.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20091026

• Enantioselective rhodium-catalyzed conjugate alkynylation of 5-benzylidene Meldrum's acids with TMS-acetylene.

  Journal of the American Chemical Society 20091021

• Preparation of multisubstituted enamides via rhodium-catalyzed carbozincation and hydrozincation of ynamides.

  The Journal of organic chemistry 20091016

• Rhodium and iridium amido complexes supported by silyl pincer ligation: ammonia N-H bond activation by a [PSiP]Ir complex.

  Journal of the American Chemical Society 20091014

• Hydrogen-deuterium exchange reactions of aromatic compounds and heterocycles by NaBD4-activated rhodium, platinum and palladium catalysts.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20091012

• Rhodium-catalyzed ring-opening reactions of a 3-aza-2-oxabicyclo[2.2.1]hept-5-ene with arylboronic acids.

  The Journal of organic chemistry 20091002

• Organic carbonates as alternative solvents for asymmetric hydrogenation.

  Chirality 20091001

• Rhodium-mediated enantioselective cyclopropanation of allenes.

  Organic letters 20091001

• Steric tuning of the amidomonophosphane-rhodium(I) catalyst in asymmetric addition of arylboroxines to N-phosphinoyl aldimines.

  Organic letters 20091001

• Asymmetric Rh-catalyzed intermolecular hydroacylation of 1,5-hexadiene with salicylaldehyde.

  Chemical & pharmaceutical bulletin 20091001

• Development of a continuous-flow system for asymmetric hydrogenation using self-supported chiral catalysts.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20090928

• Enantioselective rhodium-catalyzed [4+2+2] cycloaddition of dienyl isocyanates for the synthesis of bicyclic azocine rings.

  Journal of the American Chemical Society 20090923

• Total synthesis of alkaloid (+/-)-G. B. 13 using a Rh(I)-catalyzed ketone hydroarylation and late-stage pyridine reduction.

  Journal of the American Chemical Society 20090923

• Easy preparation of Cp*-functionalized N-heterocyclic carbenes and their coordination to rhodium and iridium.

  Dalton transactions (Cambridge, England : 2003) 20090921

• N-heterocyclic carbenes bearing two, one and no nitrogen atoms at the ylidene carbon: insight from theoretical calculations.

  Dalton transactions (Cambridge, England : 2003) 20090921

• Pyrazolyl-N-heterocyclic carbene complexes of rhodium as hydrogenation catalysts: The influence of ligand steric bulk on catalyst activity.

  Dalton transactions (Cambridge, England : 2003) 20090921

• Expanded ring and functionalised expanded ring N-heterocyclic carbenes as ligands in catalysis.

  Dalton transactions (Cambridge, England : 2003) 20090921

• Synthesis, structure and properties of [1,2,4]triazolo[4,3-a]pyridin-3-ylidene rhodium and palladium complexes.

  Dalton transactions (Cambridge, England : 2003) 20090921

• Carbene-anchored/pendent-imidazolium species as precursors to di-N-heterocyclic carbene-bridged mixed-metal complexes.

  Dalton transactions (Cambridge, England : 2003) 20090921

• A critical electrostatic interaction mediates inhibitor recognition by human asparagine synthetase.

  Bioorganic & medicinal chemistry 20090915

• Rhodium-catalyzed oxidative coupling of aromatic imines with internal alkynes via regioselective C-H bond cleavage.

  Chemical communications (Cambridge, England) 20090914

• Methanol as a reaction medium and reagent in substrate reactions of rhodium porphyrins.

  Inorganic chemistry 20090907

• Phosphabarrelene-modified Rh-catalysts: a new and selective route towards hydroxy-functionalized bicyclic imidazoles via tandem reactions.

  Chemical communications (Cambridge, England) 20090907

• Bis(oxazolinylmethyl)pyrrole derivatives and their coordination as chiral 'pincer' ligands to rhodium.

  Inorganic chemistry 20090907

• Rh-catalyzed reductive coupling reaction of aldehydes with conjugated dienes promoted by triethylborane.

  Organic letters 20090903

• Isoquinoline synthesis via rhodium-catalyzed oxidative cross-coupling/cyclization of aryl aldimines and alkynes.

  Journal of the American Chemical Society 20090902

• Chiral amidophosphane-rhodium(i)-catalyzed asymmetric conjugate arylation of acyclic enones with arylboronic acids.

  Chemical & pharmaceutical bulletin 20090901

• Liquid-liquid extraction/separation of platinum(IV) and rhodium(III) from acidic chloride solutions using tri-iso-octylamine.

  Journal of hazardous materials 20090830

• Synthesis of functionalized alpha-pyrone and butenolide derivatives by rhodium-catalyzed oxidative coupling of substituted acrylic acids with alkynes and alkenes.

  The Journal of organic chemistry 20090821

• Formal aromatic C-H insertion for stereoselective isoquinolinone synthesis and studies on mechanistic insights into the C-C bond formation.

  The Journal of organic chemistry 20090821

• Preparation of a bis(hydrosulfido) complex of Mo having a tetraphosphine co-ligand and its transformation into MoRh2 and MoIr2 mixed-metal sulfido clusters.

  Dalton transactions (Cambridge, England : 2003) 20090821

• Live cell cytotoxicity studies: documentation of the interactions of antitumor active dirhodium compounds with nuclear DNA.

  Journal of the American Chemical Society 20090819

• Synthesis of a core carbon framework of cyanosporasides A and B.

  The Journal of organic chemistry 20090807

• Enantioselective Rh-catalyzed hydrogenation of 3-aryl-2-phosphonomethylpropenoates by a new class of chiral ferrocenyl diphosphine ligands.

  Organic letters 20090806

• Eta(5)-1,2,3-trisilacyclopentadienyl--a ligand for transition metal complexes: rhodium half-sandwich and ruthenium sandwich.

  Journal of the American Chemical Society 20090729

• Room-temperature hydrogen generation from hydrous hydrazine for chemical hydrogen storage.

  Journal of the American Chemical Society 20090729

• A highly enantioselective allylic amination reaction using a commercially available chiral rhodium catalyst: resolution of racemic allylic carbonates.

  Organic letters 20090716

• Divergent and expeditious access to fused skeletons inspired by indole alkaloids and transtaganolides.

  Organic letters 20090716

• Metal nanoparticle/ionic liquid/cellulose: new catalytically active membrane materials for hydrogenation reactions.

  Biomacromolecules 20090713

• Efficient and practical arene hydrogenation by heterogeneous catalysts under mild conditions.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20090713

• Unlocking ylide reactivity in the metal-catalyzed allylic substitution reaction: stereospecific construction of primary allylic amines with aza-ylides.

  Journal of the American Chemical Society 20090701

• Catalytic synthesis of amino acid and peptide derivatized gadonanotubes.

  Journal of the American Chemical Society 20090624

• Asymmetric [4 + 3] cycloadditions between vinylcarbenoids and dienes: application to the total synthesis of the natural product (-)-5-epi-vibsanin E.

  Journal of the American Chemical Society 20090617

• A DFT study on the mechanism of a novel, regioselective, intramolecular N-pi rearrangement of cis and trans-eta1-N-Cp*Rh-hydroxytamoxifen complexes to their eta6 derivatives; potential breast cancer pharmaceuticals, and fluorescent probes.

  Dalton transactions (Cambridge, England : 2003) 20090614

• Exceptional sensitivity of metal-aryl bond energies to ortho-fluorine substituents: influence of the metal, the coordination sphere, and the spectator ligands on M-C/H-C bond energy correlations.

  Journal of the American Chemical Society 20090610

• Asymmetric synthesis of neolignans (-)-epi-conocarpan and (+)-conocarpan via Rh(II)-catalyzed C-H insertion process and revision of the absolute configuration of (-)-epi-conocarpan.

  The Journal of organic chemistry 20090605

• Flexible synthesis of fused benzofuran derivatives by rhodium-catalyzed [2 + 2 + 2] cycloaddition with phenol-linked 1,6-diynes.

  Organic letters 20090604

• Chiral crown conformation of Rh(2)(S-PTTL)(4): enantioselective cyclopropanation with alpha-alkyl-alpha-diazoesters.

  Journal of the American Chemical Society 20090603

• Mechanistic investigations into the asymmetric transfer hydrogenation of ketones catalyzed by pseudo-dipeptide ruthenium complexes.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20090602

• In situ time-resolved XAFS studies of metal particle formation by photoreduction in polymer solutions.

  Langmuir : the ACS journal of surfaces and colloids 20090602

• Synthesis of phthalocyanine stabilized rhodium nanoparticles and their application in biosensing of cytochrome c.

  Bioelectrochemistry (Amsterdam, Netherlands) 20090601

• Syntheses and crystal structures of ruthenium and rhodium olefin complexes containing GaCp.

  Inorganic chemistry 20090601

• Polymerization of phenylacetylene by rhodium complexes within a discrete space of apo-ferritin.

  Journal of the American Chemical Society 20090527

• A bulky rhodium complex bound to an adenosine-adenosine DNA mismatch: general architecture of the metalloinsertion binding mode.

  Biochemistry 20090526

• Redox-regulated Inhibition of T7 RNA polymerase via establishment of disulfide linkages by substituted Dppz dirhodium(II,II) complexes.

  Inorganic chemistry 20090518

• Electrochemical and electrogenerated chemiluminescent studies of a trinuclear complex, [((phen)2Ru(dpp))2RhCl2]5+, and its interactions with calf thymus DNA.

  Analytical chemistry 20090515

• Chemoselective tryptophan labeling with rhodium carbenoids at mild pH.

  Journal of the American Chemical Society 20090506

• Structure-activity relationships and DNA binding properties of apoptosis inducing cytotoxic rhodium(III) polypyridyl complexes containing the cyclic thioether [9]aneS(3).

  Journal of inorganic biochemistry 20090501

• Chemoselective hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol.

  Chemical communications (Cambridge, England) 20090421

• Rh(2)(II)-catalyzed synthesis of carbazoles from biaryl azides.

  The Journal of organic chemistry 20090417

• Synthesis and isolation of a stable, axially-chiral seven-membered N-heterocyclic carbene.

  Dalton transactions (Cambridge, England : 2003) 20090407

• Highly stereoselective synthesis of aminoglycosides via rhodium-catalyzed and substrate-controlled aziridination of glycals.

  Organic & biomolecular chemistry 20090407

• Asymmetric synthesis of diamine derivatives via sequential palladium and rhodium catalysis.

  Journal of the American Chemical Society 20090401

• First total synthesis of antiostatin A1, a potent carbazole-based naturally occurring antioxidant.

  Chemical communications (Cambridge, England) 20090328

• Stereoselective synthesis of multisubstituted enamides via rhodium-catalyzed carbozincation of ynamides.

  Journal of the American Chemical Society 20090325

• Synthesis of (+)-coronafacic acid.

  The Journal of organic chemistry 20090320

• Rhodium-catalyzed vinylcyclopropanation/cyclopentenation of strained alkenes via a sequential carborhodation process.

  The Journal of organic chemistry 20090320

• Rhodium(I)-catalyzed cyclization reaction of o-alkynyl phenols and anilines. Domino approach to 2,3-disubstituted benzofurans and indoles.

  Organic letters 20090319

• The reopening rate of the fingers domain is a determinant of base selectivity for RB69 DNA polymerase.

  Biochemistry 20090317

• Effect of A and B metal ion site occupancy on conformational changes in an RB69 DNA polymerase ternary complex.

  Biochemistry 20090317

• Rh-catalyzed isomerization and intramolecular redox reaction of alkynyl ethers affording dihydropyrans and ketoolefins.

  Journal of the American Chemical Society 20090311

• Rhodium-catalyzed reductive cleavage of carbon-cyano bonds with hydrosilane: a catalytic protocol for removal of cyano groups.

  Journal of the American Chemical Society 20090311

• Application of a rhodium-catalyzed addition/cyclization sequence toward the synthesis of polycyclic heteroaromatics.

  The Journal of organic chemistry 20090220

• Rhodium(I)-catalyzed synthesis of indoles: amino-Claisen rearrangement of N-propargylanilines.

  The Journal of organic chemistry 20090220

• DNA mismatch binding and antiproliferative activity of rhodium metalloinsertors.

  Journal of the American Chemical Society 20090218

• An acyclic dimer of cyclodiphosphazane {(t)BuHN((t)BuNP)2OCH2}2 containing alkoxo and amido functionalities: synthesis, derivatization, Bi- (Pd(II), Rh(I)), and tetranuclear (Pd(II), Au(I), Rh(I)Au(I)) transition metal complexes.

  Inorganic chemistry 20090216

• Discovery of mu-opioid selective ligands derived from 1-aminotetralin scaffolds made via metal-catalyzed ring-opening reactions.

  Bioorganic & medicinal chemistry letters 20090215

• Highly cis-selective cyclopropanations with ethyl diazoacetate using a novel Rh(I) catalyst with a chelating N-heterocyclic iminocarbene ligand.

  Organic letters 20090205

• Rhodium-catalyzed methylthio transfer reaction between ketone alpha-positions: reversible single-bond metathesis of C-S and C-H bonds.

  Organic letters 20090205

• Chelation-assisted carbon-halogen bond activation by a rhodium(I) complex.

  Inorganic chemistry 20090202

• Highly effective degradation of polychlorinated biphenyls in soil mediated by a Ca/Rh bicatalytic system.

  Chemosphere 20090201

• Cytotoxic rhodium(III) and iridium(III) polypyridyl complexes: structure-activity relationships, antileukemic activity, and apoptosis induction.

  ChemMedChem 20090201

• Rhodium-catalyzed direct oxidative carbonylation of aromatic C-H bond with CO and alcohols.

  Journal of the American Chemical Society 20090121

• Reagent-controlled regiodivergent resolution of unsymmetrical oxabicyclic alkenes using a cationic rhodium catalyst.

  Journal of the American Chemical Society 20090121

• Synthesis of enamides via Rh/C-catalyzed direct hydroacylation of ketoximes.

  Organic letters 20090115

• Catalyzed addition of diazoacetoacetates to imines: synthesis of highly functionalized aziridines.

  Organic & biomolecular chemistry 20090107

• Stereoselective rhodium-catalyzed conjugate addition of boronic acids to unprotected delta-hydroxy-gamma-butenolides. Synthesis of (-)-7-oxamuricatacin and beta-substituted derivatives.

  The Journal of organic chemistry 20090102

• Highly regioselective hydroformylation of styrene and its derivatives catalyzed by Rh complex with tetraphosphorus ligands.

  Organic letters 20090101

• Stereoselective hydrogenation of olefins using rhodium-substituted carbonic anhydrase--a new reductase.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20090101

• Autothermal catalytic partial oxidation of glycerol to syngas and to non-equilibrium products.

  ChemSusChem 20090101

• Rhodium(I)-catalyzed intramolecular carbonylative [2+2+1] cycloaddition of bis(allene)s: bicyclo[6.3.0]undecadienones and bicyclo[5.3.0]decadienones.

  Angewandte Chemie (International ed. in English) 20090101

• Total synthesis of indolizidine alkaloid (-)-209D: overriding substrate bias in the asymmetric rhodium-catalyzed [2+2+2] cycloaddition.

  Angewandte Chemie (International ed. in English) 20090101

• Rh(I)-catalyzed regio- and stereospecific carbonylation of 1-(1-alkynyl)cyclopropyl ketones: a modular entry to highly substituted 5,6-dihydrocyclopenta[c]furan-4-ones.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20090101

• Methyleneimidazoline complexes of iridium, rhodium, and palladium from selective C(sp3)-H bond activation.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20090101

• Rhodium-catalyzed enantioselective and diastereoselective hydrogenation of beta-ketoenamides: efficient access to anti 1,3-amino alcohols.

  Angewandte Chemie (International ed. in English) 20090101

• Rhodium-catalyzed asymmetric enyne cycloisomerization of terminal alkynes and formal total synthesis of (-)-platensimycin.

  Angewandte Chemie (International ed. in English) 20090101

• Chemistry of ethylene glycol on a Rh(100) single-crystal surface.

  ChemSusChem 20090101

• Tandem silylformylation-crotylsilylation/Tamao oxidation of internal alkynes: a remarkable example of generating complexity from simplicity.

  Organic letters 20081218

• Rhodium(I)-catalyzed one-pot synthesis of dialkyl ketones from methanol and alkenes through directed sp3 C-H bond activation of N-methylamine.

  Chemical communications (Cambridge, England) 20081130

• Solar energy in production of L-glutamate through visible light active photocatalyst--redox enzyme coupled bioreactor.

  Chemical communications (Cambridge, England) 20081114

• Rh(I)-catalyzed direct arylation of pyridines and quinolines.

  Journal of the American Chemical Society 20081112

• Back-electron transfer suppresses the periodic length dependence of DNA-mediated charge transport across adenine tracts.

  Journal of the American Chemical Society 20081112

• Synthesis of D- and L-carbocyclic nucleosides via rhodium-catalyzed asymmetric hydroacylation as the key step.

  Organic letters 20081106

• Metal-catalyzed reaction of N-(2-indolyl)methyl, N-bis(trimethylsilyl)methyl diazoamides: an entry into the beta-carboline ring system.

  Chemical communications (Cambridge, England) 20081021

• Synthesis, characterization, and reactivity of rhodium(I) acetylacetonato complexes containing pyridinecarboxaldimine ligands.

  Inorganic chemistry 20081006

• Sterically hindered benzophenones via rhodium-catalyzed oxidative arylation of aldehydes.

  The Journal of organic chemistry 20081003

• Synthesis of (-)-hamigeran B.

  The Journal of organic chemistry 20081003

• Chiral recognition of Schiff bases by 15N NMR spectroscopy in the presence of a dirhodium complex. Deuterium isotope effect on 15N chemical shift of the optically active Schiff bases and their dirhodium tetracarboxylate adducts.

  Magnetic resonance in chemistry : MRC 20081001

• Synthesis, structure and antitumor activity of [RhCl3(N-N)(DMSO)] polypyridyl complexes.

  Journal of inorganic biochemistry 20081001

• Fused tetracycles with a benzene or cyclohexadiene core: [2 + 2 + 2] cycloadditions on macrocyclic systems.

  Chemical communications (Cambridge, England) 20080928

• Branch-selective reductive coupling of 2-vinyl pyridines and imines via rhodium catalyzed C-C bond forming hydrogenation.

  Journal of the American Chemical Society 20080924

• An efficient low-temperature route to polycyclic isoquinoline salt synthesis via C-H activation with [Cp*MCl2]2 (M = Rh, Ir).

  Journal of the American Chemical Society 20080917

• Rhodium-catalyzed substitution reaction of aryl fluorides with disulfides: p-orientation in the polyarylthiolation of polyfluorobenzenes.

  Journal of the American Chemical Society 20080917

• Electron-transfer reactions of nitrosyl and superoxo metal complexes.

  Inorganic chemistry 20080915

• Transition-metal-catalyzed chemoselective methylenation of dicarbonyl substrates.

  The Journal of organic chemistry 20080905

• Asymmetric enamide hydrogenation using phosphinite thioglycosides: synthesis of D- and L-aminoesters using D-sugars as catalyst precursors.

  Organic letters 20080904

• PCR-like cascade reactions in the context of an allosteric enzyme mimic.

  Journal of the American Chemical Society 20080903

• Rhodium-catalyzed asymmetric addition of terminal alkynes to diarylphosphinylallenes.

  Chemistry, an Asian journal 20080901

• Synthesis of bulky arylphosphanes by rhodium-catalyzed formal [2+2+2] cycloaddition reaction and their use as ligands.

  Chemistry, an Asian journal 20080901

• Catalytic C-H amination for the preparation of substituted 1,2-diamines.

  Journal of the American Chemical Society 20080827

• Catalytic enantioselective intermolecular cycloaddition of 2-diazo-3,6-diketoester-derived carbonyl ylides with alkynes and styrenes using chiral dirhodium(II) carboxylates.

  Organic letters 20080821

• Highly regioselective isomerization-hydroformylation of internal olefins to linear aldehyde using rh complexes with tetraphosphorus ligands.

  Organic letters 20080821

• Iron(II) bromide-catalyzed synthesis of benzimidazoles from aryl azides.

  Organic letters 20080807

• Metal complexes with the ligand derived from 6-acetyl-1,3,7-trimethyllumazine and benzohydrazide. Molecular structures of two new Co(II) and Rh(III) complexes and analysis of in vitro antitumor activity.

  Journal of inorganic biochemistry 20080801

• Direct functionalization of nitrogen heterocycles via Rh-catalyzed C-H bond activation.

  Accounts of chemical research 20080801

• Structure-activity relationships of 2-aryl-1H-indole inhibitors of the NorA efflux pump in Staphylococcus aureus.

  Bioorganic & medicinal chemistry letters 20080801

• A chiral rhodium carboxamidate catalyst for enantioselective C-H amination.

  Journal of the American Chemical Society 20080723

• Rhodium(II)-catalyzed decomposition of 3-O-(2-diazo-2-phenylacetyl)-1,2;5,6-di-O-isopropylidene-alpha-D-allofuranose: diastereoselective ether formation.

  Carbohydrate research 20080721

• Rh-catalyzed intermolecular cyclopropanation with alpha-alkyl-alpha-diazoesters: catalyst-dependent chemo- and diastereoselectivity.

  Organic letters 20080717

• A convenient synthesis and the asymmetric hydrogenation of N-phthaloyl dehydroamino acid esters.

  Organic letters 20080717

• Synthesis, biological activity, and structure-activity relationships for potent cytotoxic rhodium(III) polypyridyl complexes.

  Journal of medicinal chemistry 20080710

• One-pot synthesis of highly functionalized pyridines via a rhodium carbenoid induced ring expansion of isoxazoles.

  Journal of the American Chemical Society 20080709

• Synthesis of enantiomerically pure 1,2,3,4-tetrahydro-beta-carbolines and N-acyl-1-aryl ethylamines by rhodium-catalyzed hydrogenation.

  Chemistry, an Asian journal 20080707

• Synthesis, structural characterization, and ligand replacement reactions of gem-dithiolato-bridged rhodium and iridium complexes.

  Inorganic chemistry 20080707

• Dendrimer templated synthesis of one nanometer Rh and Pt particles supported on mesoporous silica: catalytic activity for ethylene and pyrrole hydrogenation.

  Nano letters 20080701

• Stereoselective total syntheses of uncommon sesquiterpenoids isolated from Jatropha neopauciflora.

  Organic letters 20080619

• Simultaneous determination of Pt and Rh by catalytic adsorptive stripping voltammetry, using hexamethylene tetramine (HMTA) as complexing agent.

  Talanta 20080615

• Rh(I)-catalyzed intramolecular [3 + 2] cycloaddition of trans-vinylcyclopropane-enes.

  Journal of the American Chemical Society 20080611

• Toward autonomously operating molecular machines driven by transition-metal catalyst.

  Molecular bioSystems 20080601

• High throughput screening arrays of rhodium and iridium complexes as catalysts for intramolecular hydroamination using parallel factor analysis.

  The Analyst 20080601

• Cobalt/rhodium heterobimetallic nanoparticle-catalyzed carbonylative [2+2+1] cycloaddition of allenes and bisallenes to Pauson-Khand-type reaction products.

  Chemical communications (Cambridge, England) 20080528

• Asymmetric synthesis of (-)-incarvillateine employing an intramolecular alkylation via Rh-catalyzed olefinic C-H bond activation.

  Journal of the American Chemical Society 20080521

• Access to enantioenriched alpha-amino esters via rhodium-catalyzed 1,4-addition/enantioselective protonation.

  Journal of the American Chemical Society 20080514

• Theoretical elucidation of the rhodium-catalyzed [4 + 2] annulation reactions.

  Journal of computational chemistry 20080415

• Syntheses of novel di- and trinucleating ligands having a triethylbenzene core with N,N-bidentate tethers: their complexation toward Pd and Rh organometallic fragments.

  Dalton transactions (Cambridge, England : 2003) 20080414

• General access to the vinca and tacaman alkaloids using a Rh(II)-catalyzed cyclization/cycloaddition cascade.

  The Journal of organic chemistry 20080404

• A theoretical study on the trans-addition intramolecular hydroacylation of 4-alkynals catalyzed by cationic rhodium complexes.

  The Journal of organic chemistry 20080404

• Rhodium(II)-catalyzed transylidation of aryliodonium ylides: electronic effects of aryl groups determine their thermodynamic stabilities.

  Organic letters 20080403

• Tandem Rh(i)-catalyzed [(5+2)+1] cycloaddition/aldol reaction for the construction of linear triquinane skeleton: total syntheses of (+/-)-hirsutene and (+/-)-1-desoxyhypnophilin.

  Journal of the American Chemical Society 20080402

• BINOL-derived phosphoramidites in asymmetric hydrogenation: can the presence of a functionality in the amino group influence the catalytic outcome?

  Chemical Society reviews 20080401

• Synthesis and dynamic structure of multinuclear Rh complexes of porphyrinoids.

  Chemical communications (Cambridge, England) 20080328

• Efficient amide-directed catalytic asymmetric hydroboration.

  Journal of the American Chemical Society 20080326

• Rhodium-catalyzed kinetic resolution of tertiary homoallyl alcohols via stereoselective carbon-carbon bond cleavage.

  Organic letters 20080320

• Enantioselective synthesis of beta2-amino acids via Rh-catalyzed asymmetric hydrogenation with BoPhoz-type ligands: important influence of an N-H proton in the ligand on the enantioselectivity.

  The Journal of organic chemistry 20080307

• Mo(CO)6- and [Rh(CO)2Cl]2-catalyzed allenic cyclocarbonylation reactions of alkynones: efficient access to bicyclic dienediones.

  Organic letters 20080306

• Diastereo- and enantioselective hydrogenative aldol coupling of vinyl ketones: design of effective monodentate TADDOL-like phosphonite ligands.

  Journal of the American Chemical Society 20080305

• Asymmetric hydrogenation catalyzed by a rhodium complex of (R)-(tert-butylmethylphosphino)(di-tert-butylphosphino)methane: scope of enantioselectivity and mechanistic study.

  Journal of the American Chemical Society 20080227

• Rh(I)-catalyzed arylation of heterocycles via C-H bond activation: expanded scope through mechanistic insight.

  Journal of the American Chemical Society 20080227

• Simple rhodium-chlorophosphine pre-catalysts for the ortho-arylation of phenols.

  Chemical communications (Cambridge, England) 20080227

• 2D NMR study of the DNA duplex d(CTCTC*A*ACTTCC).d(GGAAGTTGAGAG) cross-linked by the antitumor-active dirhodium(II,II) unit at the cytosine-adenine step.

  Biochemistry 20080226

• Adsorption of naphthalene and quinoline on Pt, Pd and Rh: a DFT study.

  Chemphyschem : a European journal of chemical physics and physical chemistry 20080222

• The application of BTEM to UV-vis and UV-vis CD spectroscopies: the reaction of Rh4(CO)12 with chiral and achiral ligands.

  Talanta 20080215

• Carbon-carbon bond activation of 2,2,6,6-tetramethyl-piperidine-1-oxyl by a Rh(II) metalloradical: a combined experimental and theoretical study.

  Journal of the American Chemical Society 20080213

• Sequential Rh(I)/Pd-catalyzed 1,4-addition/intramolecular allylation: stereocontrolled construction of gamma-butyrolactones and cyclopropanes.

  Organic letters 20080207

• Bis-(2,5-diphenylphospholanes) with sp2 carbon linkers: synthesis and application in asymmetric hydrogenation.

  The Journal of organic chemistry 20080201

• Total synthesis of (+)-achalensolide based on the rh(i)-catalyzed allenic Pauson-Khand-type reaction.

  The Journal of organic chemistry 20080201

• Template-assisted synthesis of shape-controlled Rh2P nanocrystals.

  Inorganic chemistry 20080121

• Asymmetric hydrogenation of unsaturated ureas with the BIPI ligands.

  Organic letters 20080117

• Rhodium-catalyzed oxidative coupling of triarylmethanols with internal alkynes via successive C-H and C-C bond cleavages.

  The Journal of organic chemistry 20080104

• Oxidative coupling of arylboronic acids with arenes via Rh-catalyzed direct C-H arylation.

  Organic letters 20080103

• A computational study on DNA bases interactions with dinuclear tetraacetato-diaqua-dirhodium(II,II) complex.

  Journal of inorganic biochemistry 20080101

• Thermal desorption of polychlorobiphenyls from contaminated soils and their hydrodechlorination using Pd- and Rh-supported catalysts.

  Chemosphere 20080101

• Intramolecular alkyl phosphine dehydrogenation in cationic rhodium complexes of tris(cyclopentylphosphine).

  Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

• Stereoselective isomerisation of N-allyl aziridines into geometrically stable Z enamines by using rhodium hydride catalysis.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

• Rhodium-complex-catalyzed asymmetric hydrogenation: transformation of precatalysts into active species.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

• Highly Enantio- and s-trans C=C bond selective catalytic hydrogenation of cyclic enones: alternative synthesis of (-)-menthol.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

• Rh III- and Ir III-catalyzed asymmetric transfer hydrogenation of ketones in water.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

• Exploiting self-assembly for ligand-scaffold optimization: substrate-tailored ligands for efficient catalytic asymmetric hydroboration.

  Angewandte Chemie (International ed. in English) 20080101

• Gold-catalyzed allyl-allyl coupling.

  Angewandte Chemie (International ed. in English) 20080101

• Novel contributions to the mechanism of the enantioselective hydrogenation of dimethyl itaconate with rhodium complexes.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

• A carbonyl ylide cycloaddition approach to platensimycin.

  Angewandte Chemie (International ed. in English) 20080101

• Fluorescent naphthyl- and anthrylazoles from the catalytic coupling of phenylazoles with internal alkynes through the cleavage of multiple C-H bonds.

  Angewandte Chemie (International ed. in English) 20080101

• Nickel, palladium and rhodium induced IFN-gamma and IL-10 production as assessed by in vitro ELISpot-analysis in contact dermatitis patients.

  BMC immunology 20080101

• N-tosyloxycarbamates as reagents in rhodium-catalyzed C-H amination reactions.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

• [Synthesis and luminescent spectral characteristics of porphyrin complexes with platinum group metals].

  Bioorganicheskaia khimiia 20080101

• Organic carbonates as alternative solvents for palladium-catalyzed substitution reactions.

  ChemSusChem 20080101

• Modular chiral bidentate phosphonites: design, synthesis, and application in catalytic asymmetric hydroformylation reactions.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

• Efficient catalytic decomposition of formic acid for the selective generation of H2 and H/D exchange with a water-soluble rhodium complex in aqueous solution.

  ChemSusChem 20080101

• Head-to-head right-handed cross-links of the antitumor-active bis(mu-N,N'-di-p-tolylformamidinato)dirhodium(II,II) unit with the dinucleotides d(GpA) and d(ApG).

  Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

• The reaction of mixtures of [Rh4(CO)12] and triphenylphosphite with carbon monoxide or syngas as studied by high-resolution, high-pressure NMR spectroscopy.

  Magnetic resonance in chemistry : MRC 20080101

• Rh-catalyzed asymmetric hydrogenation of unsaturated lactate precursors in propylene carbonate.

  ChemSusChem 20080101

• Converting unprotected monosaccharides into functionalised lactols in aqueous media: metal-mediated allylation combined with tandem hydroformylation-cyclisation.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

• Evaluation of C4 diphosphine ligands in rhodium catalysed methanol carbonylation under a syngas atmosphere: synthesis, structure, stability and reactivity of rhodium(I) carbonyl and rhodium(III) acetyl intermediates.

  Dalton transactions (Cambridge, England : 2003) 20071221

• Enantioselective synthesis of chiral sulfones by Rh-catalyzed asymmetric addition of boronic acids to alpha,beta-unsaturated 2-pyridyl sulfones.

  The Journal of organic chemistry 20071221

• Optimal TBHP allylic oxidation of Delta5-steroids catalyzed by dirhodium caprolactamate.

  Organic letters 20071220

• Allyl deprotection of galacturonic acid derivatives: mechanistic aspects of mercuric-catalyzed prop-1-enyl acetal cleavage.

  Carbohydrate research 20071210

• DNA binding and topoisomerase II inhibitory activity of water-soluble ruthenium(II) and rhodium(III) complexes.

  Inorganic chemistry 20071210

• Rhodium-catalyzed decarbonylation of aldoses.

  The Journal of organic chemistry 20071207

• Rhodium-catalyzed cyclohydrocarbonylation approach to the syntheses of enantiopure homokainoids.

  The Journal of organic chemistry 20071207

• Addition of alkynes to aldehydes and activated ketones catalyzed by rhodium-phosphine complexes.

  The Journal of organic chemistry 20071207

• Developing chiral ligands for asymmetric hydrogenation.

  Accounts of chemical research 20071201

• Asymmetric hydrogenation using monodentate phosphoramidite ligands.

  Accounts of chemical research 20071201

• Thioether-functionalized ferrocenyl-bis(phosphonite), Fe{(C5H4)P(-OC10H6(micro-S)C10H6O-)}2: synthesis, coordination behavior, and application in Suzuki-Miyaura cross-coupling reactions.

  Inorganic chemistry 20071126

• Features and applications of [Rh(CO)(2)Cl](2)-catalyzed alkylations of unsymmetrical allylic substrates.

  The Journal of organic chemistry 20071123

• Anti-Markovnikov addition of both primary and secondary amines to terminal alkynes catalyzed by the TpRh(C2H4)2/PPh3 system.

  Journal of the American Chemical Society 20071114

• Rh-catalyzed asymmetric hydrogenation of gamma-phthalimido-substituted alpha,beta-unsaturated carboxylic acid esters: an efficient enantioselective synthesis of beta-aryl-gamma-amino acids.

  Organic letters 20071108

• Rh-catalyzed highly enantioselective formation of functionalized cyclopentanes and cyclopentanones.

  Organic & biomolecular chemistry 20071107

• Stereochemical features making deoxycholic acid derived tropos biphenylphosphites efficient chiral ligands for rhodium: the asymmetric hydrogenation of dimethylitaconate as a case study.

  The Journal of organic chemistry 20071026

• Catalytic enantioselective amination of silyl enol ethers using chiral dirhodium(II) carboxylates: asymmetric formal synthesis of (-)-metazocine.

  Organic letters 20071025

• Site-selective modification of peptides using rhodium and palladium catalysis: complementary electrophilic and nucleophilic arylation.

  Chemical communications (Cambridge, England) 20071014

• Transition-metal-catalyzed group transfer reactions for selective C-H bond functionalization of artemisinin.

  Organic letters 20071011

• Delta-sultone formation through Rh-catalyzed C-H insertion.

  Organic letters 20071011

• Insertion of a bulky rhodium complex into a DNA cytosine-cytosine mismatch: an NMR solution study.

  Journal of the American Chemical Society 20071010

• Simultaneous arming and structure/activity studies of natural products employing O-H insertions: an expedient and versatile strategy for natural products-based chemical genetics.

  Journal of the American Chemical Society 20071010

• Adducts of rhodium(II) tetraacetate with some nitrogenous organic ligands: application of natural abundance 15N and 13C CPMAS NMR spectroscopy.

  Solid state nuclear magnetic resonance 20071001

• Heterogeneous catalytic synthesis of ethanol from biomass-derived syngas.

  Chemical Society reviews 20070901

• Dirhodium(II)-catalyzed C-H amination reaction of (S)-3-(tert-butyldimethylsilyloxy)-2-methylpropyl carbamate: a facile preparation of optically active monoprotected 2-amino-2-methyl-1,3-propanediol.

  Chemical & pharmaceutical bulletin 20070901

• Allosterically regulated supramolecular catalysis of acyl transfer reactions for signal amplification and detection of small molecules.

  Journal of the American Chemical Society 20070822

• Synthesis of (+/-)-3H-epivincamine via a Rh(II)-triggered cyclization/cycloaddition cascade.

  Organic letters 20070816

• One-step RhCl3-catalyzed deprotection of acyclic N-allyl amides.

  The Journal of organic chemistry 20070803

• Inhibition of endonuclease cleavage and DNA replication of E. coli plasmid by the antitumor rhodium(II) complex.

  Archives of biochemistry and biophysics 20070801

• Rhodium-catalyzed enantioselective desymmetrization of meso-3,5-dimethyl glutaric anhydride: a general strategy to syn-deoxypolypropionate synthons.

  Journal of the American Chemical Society 20070801

• Enantioselective synthesis of pachastrissamine (jaspin B) using dirhodium(II)-catalyzed C-H amination and asymmetric dihydroxylation as key steps.

  Chemical & pharmaceutical bulletin 20070801

• Nanometer sized tridecylamine capped Rhodium dispersed on high surface area support: catalytic investigations.

  Journal of nanoscience and nanotechnology 20070801

• Binuclear and trinuclear complexes of exoO(2)-cyclam.

  Dalton transactions (Cambridge, England : 2003) 20070721

• Rhodium-catalyzed reductive mannich coupling of vinyl ketones to N-sulfonylimines mediated by hydrogen.

  The Journal of organic chemistry 20070720

• Surface processes occurring on Rh/alumina during chiral modification by cinchonidine: an ATR-IR spectroscopy study.

  Langmuir : the ACS journal of surfaces and colloids 20070717

• Formate as a CO surrogate for cascade processes: Rh-catalyzed cooperative decarbonylation and asymmetric Pauson-Khand-type cyclization reactions.

  Chemical communications (Cambridge, England) 20070707

• Computational prediction of the regio- and diastereoselectivity in a rhodium-catalyzed hydroformylation/cyclization domino process.

  Journal of molecular modeling 20070701

• Intermolecular reactions of electron-rich heterocycles with copper and rhodium carbenoids.

  Chemical Society reviews 20070701

• Designed evolution of artificial metalloenzymes: protein catalysts made to order.

  Organic & biomolecular chemistry 20070621

• Enantioselective reductive coupling of acetylene to N-arylsulfonyl imines via rhodium catalyzed C-C bond-forming hydrogenation: (Z)-dienyl allylic amines.

  Journal of the American Chemical Society 20070613

• Dynamic axial ligand-site exchange in facially discriminated ruthenium(II) carbonyl and rhodium(III) halide metalloporphyrins.

  Inorganic chemistry 20070611

• A rhodium(I)-catalyzed demethylation-cyclization of o-anisole-substituted ynamides in the synthesis of chiral 2-amido benzofurans.

  Organic letters 20070607

• Synthesis of bulky phosphines by rhodium-catalyzed formal [2+2+2] cycloaddition reactions of tethered diynes with 1-alkynylphosphine sulfides.

  Journal of the American Chemical Society 20070606

• Covalent binding and conformational change of pUC19 DNA by rhodium (II) metal complex.

  Journal of biomolecular structure & dynamics 20070601

• Rhodium-catalyzed hydroformylation of 1-hexene in an ionic liquid: a molecular dynamics study of the hexene/[BMI][PF6] interface.

  The journal of physical chemistry. B 20070510

• Rh(I)-catalyzed carbonylative cyclization reactions of alkynes with 2-bromophenylboronic acids leading to indenones.

  Journal of the American Chemical Society 20070502

• Design of C2-symmetric tetrahydropentalenes as new chiral diene ligands for highly enantioselective Rh-catalyzed arylation of N-tosylarylimines with arylboronic acids.

  Journal of the American Chemical Society 20070502

• The total synthesis of siphonazole, a structurally unusual bis-oxazole natural product.

  Chemical communications (Cambridge, England) 20070421

• Preparation of Pt/Rh bimetallic colloidal particles in polymer solutions using borohydride-reduction.

  Journal of colloid and interface science 20070415

• Synthesis of densely functionalised arenes using [2 + 2 + 2] cycloaddition reactions.

  Organic & biomolecular chemistry 20070407

• Ovarian cancer activity of cyclic amine and thiaether metal complexes.

  Journal of medicinal chemistry 20070405

• A general phase transfer protocol for synthesizing alkylamine-stabilized nanoparticles of noble metals.

  Analytica chimica acta 20070404

• Nitrile-promoted Rh-catalyzed intermolecular hydroacylation of olefins with salicylaldehyde.

  The Journal of organic chemistry 20070330

• Rhodium-catalyzed asymmetric one-pot transesterification and [2 + 2 + 2] cycloaddition leading to enantioenriched 3,3-disubstituted phthalides.

  Organic letters 20070329

• Kinetics of oxidation of nitroxyl radicals with superoxometal complexes of chromium and rhodium.

  Inorganic chemistry 20070319

• Benzylic substitution of gramines with boronic acids and rhodium or iridium catalysts.

  Organic letters 20070315

• Highly selective supramolecular catalyzed allylic alcohol isomerization.

  Journal of the American Chemical Society 20070314

• Behaviour of palladium(II), platinum(IV), and rhodium(III) in artificial and natural waters: influence of reactor surface and geochemistry on metal recovery.

  Analytica chimica acta 20070307

• Catalytic multicomponent reactions for the synthesis of N-aryl trisubstituted pyrroles.

  The Journal of organic chemistry 20070302

• Reversible switching of the sol-gel transition with ultrasound in rhodium(I) and iridium(I) coordination networks.

  Journal of the American Chemical Society 20070227

• Scope and mechanism of the intermolecular addition of aromatic aldehydes to olefins catalyzed by Rh(I) olefin complexes.

  Journal of the American Chemical Society 20070221

• Oxidation of secondary amines catalyzed by dirhodium caprolactamate.

  Chemical communications (Cambridge, England) 20070221

• Asymmetric synthesis of the epimeric (3S)-3-((E)-hex-1-enyl)-2-methylcyclohexanones.

  Molecules (Basel, Switzerland) 20070221

• Evaluation of functionalized silica's for the adsorptive recovery of homogenous catalysts through interaction with the metal centre.

  Journal of chromatography. A 20070216

• De novo synthesis of Troc-protected amines: intermolecular rhodium-catalyzed C-H amination with N-tosyloxycarbamates.

  Organic letters 20070215

• Ligand and substrate effects on the mechanism of rhodium-catalyzed hydrogenation of enamides.

  The Journal of organic chemistry 20070202

• Synthesis of the pyrrolidinone core of KSM-2690 B.

  Organic letters 20070201

• High-throughput nanoparticle catalysis: partial oxidation of propylene.

  Combinatorial chemistry & high throughput screening 20070201

• Potential mobilization of platinum-group elements by siderophores in surface environments.

  Environmental science & technology 20070201

• Rh(I)-catalyzed bimolecular cyclization between two different 1,5-bisallenes: a combinatorial one-step approach to heterosteroids and mechanistic implications.

  Chemistry, an Asian journal 20070108

• 1H, 13C and 15N NMR coordination shifts in gold(III), cobalt(III), rhodium(III) chloride complexes with pyridine, 2,2'-bipyridine and 1,10-phenanthroline.

  Magnetic resonance in chemistry : MRC 20070101

• Hydroaminomethylation with novel rhodium-carbene complexes: an efficient catalytic approach to pharmaceuticals.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20070101

• Rh-catalyzed enantioselective conjugate addition of arylboronic acids with a dynamic library of chiral tropos phosphorus ligands.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20070101

• Dipyrrolyl-functionalized bipyridine-based anion receptors for emission-based selective detection of dihydrogen phosphate.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20070101

• Hydrogen-atom transfer in open-shell organometallic chemistry: the reactivity of Rh(II)(cod) and Ir(II)(cod) radicals.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20070101

• Rhodium-catalyzed cycloisomerization: formation of indoles, benzofurans, and enol lactones.

  Angewandte Chemie (International ed. in English) 20070101

• Rh-catalyzed highly enantioselective synthesis of 3-arylbutanoic acids.

  Angewandte Chemie (International ed. in English) 20070101

• Synthesis of 2,3-disubstituted indoles by a rhodium-catalyzed aromatic amino-Claisen rearrangement of N-propargyl anilines.

  Angewandte Chemie (International ed. in English) 20070101

• Propylene carbonate as a solvent for asymmetric hydrogenations.

  Angewandte Chemie (International ed. in English) 20070101

• A one-pot synthesis of (E)-disubstituted alkenes by a bimetallic [Rh-Pd]-catalyzed hydrosilylation/hiyama cross-coupling sequence.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20070101

• Immunotoxicity and sensitizing capacity of metal compounds depend on speciation.

  International journal of immunopathology and pharmacology 20070101

• Solvent-dependent interconversions between Rh(I), Rh(II), and Rh(III) complexes of an aryl-monophosphine ligand.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20070101

• Preparation of arylzinc reagents and their use in the rhodium-catalyzed asymmetric 1,4-addition for the synthesis of 2-aryl-4-piperidones.

  Nature protocols 20070101

• Counter propagation artificial neural networks modeling of an enantioselectivity of artificial metalloenzymes.

  Molecular diversity 20070101

• Enantioselective reductive coupling of 1,3-enynes to heterocyclic aromatic aldehydes and ketones via rhodium-catalyzed asymmetric hydrogenation: mechanistic insight into the role of Brønsted acid additives.

  Journal of the American Chemical Society 20061227

• Asymmetric induction in hydrogen-mediated reductive aldol additions to alpha-amino aldehydes catalyzed by rhodium: selective formation of syn-stereotriads directed by intramolecular hydrogen-bonding.

  Journal of the American Chemical Society 20061227

• Supramolecular allosteric cofacial porphyrin complexes.

  Journal of the American Chemical Society 20061220

• Rhodium-catalyzed arylative and alkenylative cyclization of 1,5-enynes induced by geminal carbometalation of alkynes.

  Journal of the American Chemical Society 20061213

• Elucidation of structural isomers from the homogeneous rhodium-catalyzed isomerization of vegetable oils.

  Journal of agricultural and food chemistry 20061213

• Highly selective hydroaminomethylation of internal alkenes to give linear amines.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20061204

• Synthesis and characterization of a trigonal bipyramidal supramolecular cage based upon rhodium and platinum metal centers.

  Chemical communications (Cambridge, England) 20061128

• Reductive aldol coupling of divinyl ketones via rhodium-catalyzed hydrogenation: syn-diastereoselective construction of beta-hydroxyenones.

  Organic letters 20061123

• Cyclopentadienone synthesis by rhodium(I)-catalyzed [3 + 2] cycloaddition reactions of cyclopropenones and alkynes.

  Journal of the American Chemical Society 20061122

• Tandem cyclization of alkynes via rhodium alkynyl and alkenylidene catalysis.

  Journal of the American Chemical Society 20061122

• Dirhodium(II,II) complexes: molecular characteristics that affect in vitro activity.

  Journal of medicinal chemistry 20061116

• Hydrogen bonding makes a difference in the rhodium-catalyzed enantioselective hydrogenation using monodentate phosphoramidites.

  Journal of the American Chemical Society 20061108

• Aqueous-phase hydroformylation of 1-octene: styrene latices as phase-transfer agents.

  Angewandte Chemie (International ed. in English) 20061106

• Rhodium N-confused porphyrin-catalyzed alkene cyclopropanation.

  Chemical communications (Cambridge, England) 20061104

• Dirhodium(II) tetrakis(perfluorobutyrate)-catalyzed 1,4-hydrosilylation of alpha,beta-unsaturated carbonyl compounds.

  Chemical & pharmaceutical bulletin 20061101

• [Synthesis of fluorine compounds based on special properties of fluorine compounds].

  Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan 20061101

• Dirhodium tetracarboxylates derived from adamantylglycine as chiral catalysts for enantioselective C-h aminations.

  Organic letters 20061026

• Cycloaddition protocol for the assembly of the hexacyclic framework associated with the kopsifoline alkaloids.

  Organic letters 20061026

• Targeting DNA mismatches with rhodium intercalators functionalized with a cell-penetrating peptide.

  Biochemistry 20061010

• Asymmetric hydrogenation with antibody-achiral rhodium complex.

  Organic & biomolecular chemistry 20061007

• Comparison of the anti-neoplastic effects of dirhodium(II) tetrapropionate and its adducts with nicotinate and isonicotinate anions in mice bearing Ehrlich tumors.

  European journal of medicinal chemistry 20061001

• Controlled synthesis of (S,S)-2,7-diaminosuberic acid: a method for regioselective construction of dicarba analogues of multicystine-containing peptides.

  The Journal of organic chemistry 20060929

• Rh-catalyzed asymmetric hydrogenation of alpha-aryl imino esters: an efficient enantioselective synthesis of aryl glycine derivatives.

  Angewandte Chemie (International ed. in English) 20060925

• NiN(2)S(2) complexes as metallodithiolate ligands to Rh(I), Rh(II) and Rh(III).

  Dalton transactions (Cambridge, England : 2003) 20060921

• Expanding the useful range of ionic liquids: melting point depression of organic salts with carbon dioxide for biphasic catalytic reactions.

  Chemical communications (Cambridge, England) 20060921

• A theoretical study of rhodium(I) catalyzed carbonylative ring expansion of aziridines to beta-lactams: crucial activation of the breaking C-N bond by hyperconjugation.

  The Journal of organic chemistry 20060915

• Synthesis of the tetracyclic framework of the erythrina alkaloids using a [4 + 2]-cycloaddition/Rh(I)-catalyzed cascade of 2-imidofurans.

  The Journal of organic chemistry 20060915

• Direct C-H arylation of (hetero)arenes with aryl iodides via rhodium catalysis.

  Journal of the American Chemical Society 20060913

• Rhodium-catalyzed stereoselective formation of Z-enamines from allylaziridines.

  Journal of the American Chemical Society 20060913

• Highly efficient Rh(I)-catalyzed asymmetric hydrogenation of enamines using monodente spiro phosphonite ligands.

  Journal of the American Chemical Society 20060913

• Asymmetric transfer hydrogenation catalysed by hydrophobic dendritic DACH-rhodium complex in water.

  Organic & biomolecular chemistry 20060907

• Phosphabarrelenes as ligands in rhodium-catalyzed hydroformylation of internal alkenes essentially free of alkene isomerization.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20060906

• High-precision catalysts: regioselective hydroformylation of internal alkenes by encapsulated rhodium complexes.

  Journal of the American Chemical Society 20060906

• Studies of interaction between Rh(I) and human serum albumin in a 'nanostructured biocatalyst' active in the hydroformylation reaction.

  Journal of inorganic biochemistry 20060901

• Phosphine-olefin ligands: a facile dehydrogenative route to catalytically active rhodium complexes.

  Chemical communications (Cambridge, England) 20060828

• Catalytic hydrodechlorination of 2,4-dichlorophenol on Pd/Rh/C catalysts.

  Journal of hazardous materials 20060825

• Head-to-head cross-linked adduct between the antitumor unit bis(mu-N,N'-di-p-tolylformamidinato)dirhodium(II,II) and the DNA fragment d(GpG).

  Chemistry (Weinheim an der Bergstrasse, Germany) 20060825

• Cationic Rh(I) catalyst in fluorinated alcohol: mild intramolecular cycloaddition reactions of ester-tethered unsaturated compounds.

  The Journal of organic chemistry 20060818

• Alpha-hydroxy esters via enantioselective hydrogen-mediated C-C coupling: regiocontrolled reactions of silyl-substituted 1,3-diynes.

  Organic letters 20060817

• Enantioselective synthesis of beta-amino esters and its application to the synthesis of the enantiomers of the antidepressant Venlafaxine.

  Chemical communications (Cambridge, England) 20060807

• Polymer-bound dirhodium tetracarboxylate films for fluorescent detection of nitric oxide.

  Inorganic chemistry 20060807

• Dirhodium tetracarboxylate derived from adamantylglycine as a chiral catalyst for carbenoid reactions.

  Organic letters 20060803

• Diversity synthesis using the complimentary reactivity of rhodium(II)- and palladium(II)-catalyzed reactions.

  The Journal of organic chemistry 20060721

• 1,2-migration in rhodium(II) carbene transfer reaction: remarkable steric effect on migratory aptitude.

  The Journal of organic chemistry 20060721

• Application of the Rh(II) cyclization/cycloaddition cascade for the total synthesis of (+/-)-aspidophytine.

  Organic letters 20060720

• Enantioselective C-C bond cleavage creating chiral quaternary carbon centers.

  Organic letters 20060720

• Rhodium(I)-catalyzed carboxylation of aryl- and alkenylboronic esters with CO2.

  Journal of the American Chemical Society 20060712

• Self-supported organometallic rhodium quinonoid nanocatalysts for stereoselective polymerization of phenylacetylene.

  Journal of the American Chemical Society 20060712

• Generation of acyloxyketenes from unstable mesoionic 1,3-dioxolium-4-olates and their reaction with ketenophiles to give [2 + 2] cycloadducts.

  The Journal of organic chemistry 20060707

• TADDOL-derived phosphites and phosphoramidites for efficient rhodium-catalyzed asymmetric hydroboration.

  Organic letters 20060706

• Asymmetric rhodium-catalyzed hydrogenation meets gold-catalyzed cyclization: Enantioselective synthesis of 8-hydroxytetrahydroisoquinolines.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20060705

• Synthesis and characterization of monodispersed rhodium nanoparticles organized in 3-D symmetrical structures soluble in organic media.

  Journal of nanoscience and nanotechnology 20060701

• Rhodium-catalyzed addition of arylboronic acids to isatins: an entry to diversity in 3-aryl-3-hydroxyoxindoles.

  Organic letters 20060622

• Achiral benzophenone ligand-rhodium complex with chiral diamine activator for high enantiocontrol in asymmetric transfer hydrogenation.

  Chemical communications (Cambridge, England) 20060614

• Simple transformation of crystalline chiral natural anions to liquid medium and their use to induce chirality.

  Chemical communications (Cambridge, England) 20060614

• The dirhodium-method in the determination of absolute configurations of phospholene chalcogenides.

  Chirality 20060601

• Light activated compounds as antimicrobial agents - patently obvious?

  Recent patents on anti-infective drug discovery 20060601

• Rhodium-catalyzed ring-opening reactions of N-boc-azabenzonorbornadienes with amine nucleophiles.

  Journal of the American Chemical Society 20060531

• A tetracoordinated rhodium aminyl radical complex.

  Journal of the American Chemical Society 20060524

• Hybrid bidentate ligand for functional recognition: an application to regioselective C=C double bond hydrogenation.

  Chemical communications (Cambridge, England) 20060521

• Asymmetric synthesis of protected arylglycines by rhodium-catalyzed addition of arylboronic acids to N-tert-butanesulfinyl imino esters.

  Journal of the American Chemical Society 20060517

• Rhodium-catalyzed asymmetric addition of aryl- and alkenylboronic acids to isatins.

  Angewandte Chemie (International ed. in English) 20060512

• Rhodium-catalyzed intramolecular, anti-Markovnikov hydroamination. Synthesis of 3-arylpiperidines.

  Journal of the American Chemical Society 20060510

• Cp*Rh-based indicator-displacement assays for the identification of amino sugars and aminoglycosides.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20060503

• The oxidative mannich reaction catalyzed by dirhodium caprolactamate.

  Journal of the American Chemical Society 20060503

• A mismatch-selective bifunctional rhodium-Oregon Green conjugate: a fluorescent probe for mismatched DNA.

  Journal of the American Chemical Society 20060503

• The determination of lead in sugar and sweets without digestion by electrothermal atomic absorption spectrometry (ETAAS) with a rhodium chemical modifier.

  Food additives and contaminants 20060501

• Cellular sensitivity to beta-diketonato complexes of ruthenium(III), chromium(III) and rhodium(III).

  Medicinal chemistry (Shariqah (United Arab Emirates)) 20060501

• Rhodium(I)-catalyzed nucleophilic ring-opening reactions of oxabicyclo adducts derived from the [4 + 2]-cycloaddition of 2-imido-substituted furans.

  The Journal of organic chemistry 20060414

• The direct determination of partial molar volumes and reaction volumes in ultra-dilute non-reactive and reactive multi-component systems using a combined spectroscopic and modified response surface model approach.

  Dalton transactions (Cambridge, England : 2003) 20060328

• Rhodium(I)-catalyzed intramolecular pauson-khand-type [2 + 2 + 1] cycloaddition of allenenes.

  Organic letters 20060316

• Rhodium-catalyzed [2 + 2 + 2] cycloaddition of alkenyl isocyanates and alkynes.

  Journal of the American Chemical Society 20060308

• Enantioselective Rh-catalyzed hydrogenation of N-formyl dehydroamino esters with monodentate phosphoramidite ligands.

  The Journal of organic chemistry 20060303

• Enantioselective reductive coupling of alkynes and alpha-keto aldehydes via rhodium-catalyzed hydrogenation: an approach to bryostatin substructures.

  Organic letters 20060302

• A versatile approach toward the ansamycin antibiotics.

  Organic letters 20060302

• Regioselective and enantiospecific rhodium-catalyzed allylic amination with thymine: synthesis of a new conformationally rigid nucleoside.

  Chemical communications (Cambridge, England) 20060227

• Experimental and computational studies on the mechanism of N-heterocycle C-H activation by Rh(I).

  Journal of the American Chemical Society 20060222

• Mechanistic studies of an unusual epoxide-forming elimination of a beta-hydroxyalkyl rhodium porphyrin.

  Chemical communications (Cambridge, England) 20060207

• Rhodium assisted C-H activation of benzaldehyde thiosemicarbazones and their oxidation via activation of molecular oxygen.

  Inorganic chemistry 20060206

• Hydrogen-mediated aldol reductive coupling of vinyl ketones catalyzed by rhodium: high syn-selectivity through the effect of tri-2-furylphosphine.

  Organic letters 20060202

• Highly enantioselective direct reductive coupling of conjugated alkynes and alpha-ketoesters via rhodium-catalyzed asymmetric hydrogenation.

  Journal of the American Chemical Society 20060125

• A highly selective synthesis of 3-hydroxy-2-methylpropionamide involving a one-pot tandem hydroformylation-hydrogenation sequence.

  Chemical communications (Cambridge, England) 20060114

• Coordination chemistry of phosphanyl amino acids: solid state and solution structures of neutral and cationic rhodium complexes.

  Dalton transactions (Cambridge, England : 2003) 20060107

• Effect of ring methylation on the photophysical, photochemical and photobiological properties of cis-dichlorobis(1,10-phenanthroline)rhodium(III)Chloride.

  Photochemistry and photobiology 20060101

• Photophysical properties of a rhodium tetraphenylporphyrin-tin corrole dyad. The first example of a through metal-metal bond energy transfer.

  Photochemistry and photobiology 20060101

• Synthesis of phosphine containing amino acids: utilization of peptide synthesis in ligand design.

  Biopolymers 20060101

• Radiosensitization of CHO cells by two novel rhodium complexes under oxic and hypoxic conditions.

  Anticancer research 20060101

• Simultaneous determination of palladium, platinum and rhodium by on-line column enrichment and HPLC with 5-(2,4-dihydroxyphenylazo)-rhodanine as pre-column derivatization reagent.

  Annali di chimica 20060101

• Synthesis of (+/-)-brazilin using IBX.

  Organic letters 20051222

• Unprecedented hybrid scorpionate/phosphine ligand able to be anchored to carbosilane dendrimers.

  Inorganic chemistry 20051212

• Synthesis of colloidal dispersions of rhodium nanoparticles under high temperatures and high pressures.

  Journal of colloid and interface science 20051201

• Synthesis and electronic characterization of bipyridine dithiolate rhodium(III) complexes.

  Inorganic chemistry 20051128

• Simultaneous determination of palladium, platinum, rhodium and gold by on-line solid phase extraction and high performance liquid chromatography with 5-(2-hydroxy-5-nitrophenylazo)thiorhodanine as pre-column derivatization regents.

  Journal of chromatography. A 20051111

• Benzylic oxidation catalyzed by dirhodium(II,III) caprolactamate.

  Organic letters 20051110

• Catalytic addition methods for the synthesis of functionalized diazoacetoacetates and application to the construction of highly substituted cyclobutanones.

  Organic letters 20051110

• Rh-catalyzed asymmetric hydrogenation of prochiral olefins with a dynamic library of chiral TROPOS phosphorus ligands.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20051104

• Direct determination of selenium in urine samples by electrothermal atomic absorption spectrometry using a Zr plus Rh-treated graphite tube and co-injection of Rh as chemical modifier.

  Analytical and bioanalytical chemistry 20051101

• Enhanced sensitivity of lithium dithionates doped with rhodium and nickel for EPR dosimetry.

  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20051101

• Syntheses, structures, and reactivity of new pentamethylcyclopentadienyl-rhodium(III) and -iridium(III) 4-acyl-5-pyrazolonate complexes.

  Inorganic chemistry 20051031

• Rhodium-mediated formation of peroxides from dioxygen: isolation of hydroperoxo, silylperoxo, and methylperoxo intermediates.

  Angewandte Chemie (International ed. in English) 20051028

• Synthesis of biologically active amines via rhodium-bisphosphite-catalyzed hydroaminomethylation.

  Organic letters 20051027

• Detection and elimination of product inhibition from the asymmetric catalytic hydrogenation of enamines.

  Organic letters 20051027

• Amplification of asymmetric induction in sequential reactions of bis-diazoacetates catalyzed by chiral dirhodium(II) carboxamidates.

  Organic letters 20051027

• Solution self-assembly and solid state properties of fluorinated amphiphilic calix[4]arenes.

  Chemical communications (Cambridge, England) 20051021

• N-tosyloxycarbamates as a source of metal nitrenes: rhodium-catalyzed C-H insertion and aziridination reactions.

  Journal of the American Chemical Society 20051019

• Catalysis of enantioselective [2+1]-cycloaddition reactions of ethyl diazoacetate and terminal acetylenes using mixed-ligand complexes of the series Rh2(RCO2)n(L*4-n). Stereochemical heuristics for ligand exchange and catalyst synthesis.

  Journal of the American Chemical Society 20051019

• Chemical optimization of artificial metalloenzymes based on the biotin-avidin technology: (S)-selective and solvent-tolerant hydrogenation catalysts via the introduction of chiral amino acid spacers.

  Chemical communications (Cambridge, England) 20051014

• Practical synthesis of Dirhodium(II) tetrakis[N-phthaloyl-(S)-tert-leucinate].

  Chemical & pharmaceutical bulletin 20051001

• Total synthesis of (-)-colchicine via a Rh-triggered cycloaddition cascade.

  Organic letters 20050929

• Asymmetric synthesis of 5-arylcyclohexenones by rhodium(I)-catalyzed conjugate arylation of racemic 5-(trimethylsilyl)cyclohexenone with arylboronic acids.

  Organic letters 20050929

• Enantioselective 1,3-dipolar cycloaddition of nitrones to methacrolein catalyzed by (eta5-C5Me5)M{(R)-prophos} containing complexes (M = Rh, Ir; (R)-prophos = 1,2-bis(diphenylphosphino)propane): on the origin of the enantioselectivity.

  Journal of the American Chemical Society 20050928

• Redox-active dirhodium(II,II) species covalently entrapped into a methylmethacrylate backbone.

  Dalton transactions (Cambridge, England : 2003) 20050921

• Peripheral SH-functionalisation of carbosilane dendrimers including the synthesis of the model compound dimethylbis(propanethiol)silane and their interaction with rhodium complexes.

  Dalton transactions (Cambridge, England : 2003) 20050921

• Efficient electrochemical conversion of carbon monoxide by rhodium octaethylporphyrin adsorbed on carbon black.

  Inorganic chemistry 20050919

• Enantioselective RH-catalyzed hydrogenation of enol acetates and enol carbamates with monodentate phosphoramidites.

  Organic letters 20050915

• An application of the phosphine-catalyzed [4 + 2] annulation in indole alkaloid synthesis: formal syntheses of (+/-)-alstonerine and (+/-)-macroline.

  Organic letters 20050915

• Beta-aryl eliminations from Rh(I) iminyl complexes.

  Journal of the American Chemical Society 20050824

• Hydrogen-mediated reductive coupling of conjugated alkynes with ethyl (N-Sulfinyl)iminoacetates: synthesis of unnatural alpha-amino acids via rhodium-catalyzed C-C bond forming hydrogenation.

  Journal of the American Chemical Society 20050817

• Asymmetric hydrogenation of prochiral olefins catalysed by furanoside thioether-phosphinite Rh(I) and Ir(I) complexes.

  Dalton transactions (Cambridge, England : 2003) 20050807

• [Cp*Rh(bpy)(H2O)]2+ as a coenzyme substitute in enzymatic oxidations catalyzed by Baeyer-Villiger monooxygenases.

  Chemical communications (Cambridge, England) 20050807

• Control of competing N-H insertion and Wolff rearrangement in dirhodium(II)-catalyzed reactions of 3-indolyl diazoketoesters. synthesis of a potential precursor to the marine 5-(3-indolyl)oxazole martefragin A.

  The Journal of organic chemistry 20050722

• Direct electron transfer between cytochrome P450scc and gold nanoparticles on screen-printed rhodium-graphite electrodes.

  Biosensors & bioelectronics 20050715

• Rh(I)-catalyzed CO gas-free cyclohydrocarbonylation of alkynes with formaldehyde to alpha,beta-butenolides.

  Chemical communications (Cambridge, England) 20050714

• A readily prepared neutral heterobimetallic titanium(IV)-rhodium(I) catalyst for intramolecular hydroacylation.

  Chemical communications (Cambridge, England) 20050714

• Immobilization of chiral ferrocenyl ligands on silica gel and their testing in Pd-catalyzed allylic substitution and Rh-catalyzed hydrogenation.

  Molecules (Basel, Switzerland) 20050714

• Adsorption of [D2]methanol on Ru(001)--O surfaces: the influence of preadsorbed oxygen on the methoxide geometry.

  Chemphyschem : a European journal of chemical physics and physical chemistry 20050711

• Achiral ligands dramatically enhance rate and enantioselectivity in the Rh/phosphoramidite-catalyzed hydrogenation of alpha,beta-disubstituted unsaturated acids.

  Angewandte Chemie (International ed. in English) 20050704

• 'Matched/mismatched' diastereomeric dirhodium(II) carboxamidate catalyst pairs. Structure-selectivity correlations in diazo decomposition and hetero-Diels-Alder reactions.

  The Journal of organic chemistry 20050624

• Efficient aziridination of olefins catalyzed by mixed-valent dirhodium(II,III) caprolactamate.

  Organic letters 20050623

• Artificial metalloenzymes for enantioselective catalysis based on the noncovalent incorporation of organometallic moieties in a host protein.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20050620

• Organic phase stabilization of rhodium nanoparticle catalyst by direct phase transfer from aqueous solution to room temperature ionic liquid based on surfactant counter anion exchange.

  Chemical communications (Cambridge, England) 20050614

• Rhodium-catalyzed nondecarbonylative addition reaction of ClCOCOOC2H5 to alkynes.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20050606

• Control of helix sense by composition of chiral-achiral copolymers of N-propargylbenzamides.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20050606

• The rhodium catalyzed three-component reaction of diazoacetates, titanium(IV) alkoxides and aldehydes.

  Chemical communications (Cambridge, England) 20050528

• Rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to coumarins: asymmetric synthesis of (R)-tolterodine.

  Organic letters 20050526

• Alpha-N-acetylmannosamine (ManNAc) synthesis via rhodium(II)-catalyzed oxidative cyclization of glucal 3-carbamates.

  The Journal of organic chemistry 20050513

• Mechanism and origin of enantioselectivity in the Rh2(OAc)(DPTI)3-catalyzed cyclopropenation of alkynes.

  Journal of the American Chemical Society 20050504

• Regioselectivity of rhodium nitrene insertion. Syntheses of protected glycals of l-daunosamine, d-saccharosamine, and l-ristosamine.

  Organic letters 20050428

• A fluorous chiral dirhodium(II) complex as a recyclable asymmetric catalyst.

  Organic letters 20050428

• Asymmetric hydrogenation using chiral Rh complexes immobilised with a new ion-exchange strategy.

  Organic & biomolecular chemistry 20050421

• [Rh(CO)2Cl]2-catalyzed domino reactions involving allylic substitution and subsequent carbocyclization reactions.

  Organic letters 20050414

• A study of [Co2(alkyne)(binap)(CO)4] complexes (BINAP=(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphine)).

  Chemistry (Weinheim an der Bergstrasse, Germany) 20050408

• Use of viscogens, dNTPalphaS, and rhodium(III) as probes in stopped-flow experiments to obtain new evidence for the mechanism of catalysis by DNA polymerase beta.

  Biochemistry 20050405

• Metal ion catalysis of natural products transformations. Novel aldopentose disproportionation reactions catalyzed by rhodium(III).

  Inorganic chemistry 20050321

• Highly regioselective synthesis of amino-functionalized dendritic polyglycerols by a one-pot hydroformylation/reductive amination sequence.

  The Journal of organic chemistry 20050318

• Cycloaddition chemistry of 2-vinyl-substituted indoles and related heteroaromatic systems.

  The Journal of organic chemistry 20050318

• Synthesis and application of phosphinoferrocenylaminophosphine ligands for asymmetric catalysis.

  The Journal of organic chemistry 20050304

• Effects of rhodium heterogeneous catalyst and isomerization conditions on linoleic acid conjugation of soybean oil.

  Journal of agricultural and food chemistry 20050223

• Diastereoselective and enantioselective Rh(I)-catalyzed additions of arylboronic acids to N-tert-butanesulfinyl and N-diphenylphosphinoyl aldimines.

  Journal of the American Chemical Society 20050202

• Covalent binding and interstrand cross-linking of duplex DNA by dirhodium(II,II) carboxylate compounds.

  Biochemistry 20050125

• The diastereoselective synthesis of quaternary substituted thioindolines from sulfur ylide intermediates.

  The Journal of organic chemistry 20050121

• Chiral 2,6-bis(oxazolinyl)pyridine-rare earth metal complexes as catalysts for highly enantioselective 1,3-dipolar cycloaddition reactions of 2-benzopyrylium-4-olates.

  The Journal of organic chemistry 20050107

• Fluorous mixture synthesis of 4-alkylidene cyclopentenones via a rhodium-catalyzed [2+2+1] cycloaddition of alkynyl allenes.

  Journal of combinatorial chemistry 20050101

• Synthesis and efficiency of a spherical macroporous epoxy-polyamide chelating resin for preconcentrating and separating trace noble metal ions.

  Annali di chimica 20050101

• DNA binding and photocleavage in vitro by new dirhodium(II) dppz complexes: correlation to cytotoxicity and photocytotoxicity.

  Inorganic chemistry 20041227

• Asymmetric synthesis of the central tryptophan residue of stephanotic acid.

  Organic & biomolecular chemistry 20041221

• Catalytic reductive coupling of epoxides and aldehydes: epoxide-ring opening precedes carbonyl reduction.

  Angewandte Chemie (International ed. in English) 20041217

• Ring expansion-annulation strategy for the synthesis of substituted azulenes and oligoazulenes. 2. Synthesis of azulenyl halides, sulfonates, and azulenylmetal compounds and their application in transition-metal-mediated coupling reactions.

  The Journal of organic chemistry 20041210

• N-H insertion reactions of primary ureas: the synthesis of highly substituted imidazolones and imidazoles from diazocarbonyls.

  The Journal of organic chemistry 20041210

• Preparation of axially chiral biphenyl diphosphine ligands and their application in asymmetric hydrogenation.

  Chemical & pharmaceutical bulletin 20041201

• N-h insertion reactions of Boc-amino acid amides: solution- and solid-phase synthesis of pyrazinones and pyrazines.

  Organic letters 20041125

• Novel rhodium-catalyzed reaction of thiazolidine derivatives with carbodiimides.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20041119

• Stereoselective Rh-catalyzed hydrogenation of cyclobutyl chiral enamides: double stereodifferentiation vs catalyst-controlled diastereoselection.

  The Journal of organic chemistry 20041112

• Self-oxidation of a phenolate complex to a bimetallic stilbene quinone.

  Angewandte Chemie (International ed. in English) 20041112

• Artificial metalloenzymes: (strept)avidin as host for enantioselective hydrogenation by achiral biotinylated rhodium-diphosphine complexes.

  Journal of the American Chemical Society 20041110

• Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(II) complexes with bulky ortho-metalated aryl phosphines.

  Chemical communications (Cambridge, England) 20041107

• Preparation of enantiopure norbornane ligands bearing both (2S,3S)-bis(phosphinomethyl) and 7-syn-oxygen functional groups and an application to rhodium-catalyzed asymmetric hydrogenation.

  Chemical & pharmaceutical bulletin 20041101

• C2-symmetric diphosphinite ligands derived from carbohydrates. The strong influence of remote stereocenters on asymmetric rhodium-catalyzed hydrogenation.

  The Journal of organic chemistry 20041029

• Dirhodium(II) caprolactamate: an exceptional catalyst for allylic oxidation.

  Journal of the American Chemical Society 20041027

• Synthesis and coordinating ability of an anionic cobaltabisdicarbollide ligand geometrically analogous to BINAP.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20041025

• Oxidative C-arylation of free (NH)-heterocycles via direct (sp3) C-H bond functionalization.

  Journal of the American Chemical Society 20041020

• Intermolecular coupling of alkenes to heterocycles via C-H bond activation.

  The Journal of organic chemistry 20041015

• Binding of DNA purine sites to dirhodium compounds probed by mass spectrometry.

  Inorganic chemistry 20041004

• Synthesis of new monodentate spiro phosphoramidite ligand and its application in Rh-catalyzed asymmetric hydrogenation reactions.

  Organic letters 20040930

• Rhodium(II)-catalyzed aziridination of allyl-substituted sulfonamides and carbamates.

  The Journal of organic chemistry 20040917

• Chiral norbornadienes as efficient ligands for the rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to fumaric and maleic compounds.

  Organic letters 20040916

• An organometallic chemosensor for the sequence-selective detection of histidine- and methionine-containing peptides in water at neutral pH.

  Angewandte Chemie (International ed. in English) 20040913

• Stereodivergent construction of cyclic ethers by a regioselective and enantiospecific rhodium-catalyzed allylic etherification: total synthesis of gaur acid.

  Angewandte Chemie (International ed. in English) 20040913

• Powder diffraction study of a coordination polymer comprised of rigid building blocks: [Rh2(O2CCH3)4.mu2-Se2C5H8-Se,Se']infinity.

  Inorganic chemistry 20040906

• Synthesis and reactivity of fluoro complexes: Part 2. Rhodium(I) fluoro complexes with alkene and phosphine ligands. Synthesis of the first isolated rhodium(I) bifluoride complexes. Structure of [Rh3(mu3-OH)2(COD)(3)](HF2) by X-ray powder diffraction.

  Inorganic chemistry 20040906

• A short diastereoselective synthesis of orthogonally protected diaminosuccinic acid derivatives.

  The Journal of organic chemistry 20040903

• Reversal of P-glycoprotein-mediated multidrug resistance by Alisol B 23-acetate.

  Biochemical pharmacology 20040901

• 103Rh NMR spectroscopy and its application to rhodium chemistry.

  Magnetic resonance in chemistry : MRC 20040901

• Rhodium-103 NMR of [Rh(X)(PPh3)3] [X = Cl, N3, NCO, NCS, N(CN)2, NCBPh3, CNBPh3, CN] and derivatives containing CO, isocyanide, pyridine, H2 and O2. Ligand, solvent and temperature effects.

  Magnetic resonance in chemistry : MRC 20040901

• PGSE diffusion, 1H-19F HOESY and NMR studies on several [Rh(1,5-COD)(Biphemp)]X complexes: detecting positional anion effects.

  Magnetic resonance in chemistry : MRC 20040901

• Selective tryptophan modification with rhodium carbenoids in aqueous solution.

  Journal of the American Chemical Society 20040825

• 103Rh NMR chemical shifts in organometallic complexes: a combined experimental and density functional study.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20040820

• Cooperative bimetallic reactivity: hydrogen activation in two-electron mixed-valence compounds.

  Journal of the American Chemical Society 20040811

• Divergence of carbonyl ylide reactions as a function of diazocarbonyl compound and aldehyde substituent: dioxolanes, dioxolenes, and epoxides.

  The Journal of organic chemistry 20040806

• Polyphenols from peanut skins and their free radical-scavenging effects.

  Phytochemistry 20040801

• Bifunctional rhodium intercalator conjugates as mismatch-directing DNA alkylating agents.

  Journal of the American Chemical Society 20040721

• Investigation of the rh-catalyzed asymmetric reductive aldol reaction. Expanded scope based on reaction analysis.

  Organic letters 20040708

• N-Boc-L-valine-connected amidomonophosphane rhodium(I) catalyst for asymmetric arylation of N-tosylarylimines with arylboroxines.

  Journal of the American Chemical Society 20040707

• Effects of the photooxidant on DNA-mediated charge transport.

  Journal of the American Chemical Society 20040707

• Adducts of Rh2[MTPA]4 with some phosphine chalcogenides: nature of binding and ligand exchange.

  Magnetic resonance in chemistry : MRC 20040701

• Rh(I)-catalyzed ring opening of an IMDAF-derived oxabicyclo cycloadduct as the key step in the synthesis of (+/-)-epi-zephyranthine.

  Organic letters 20040624

• Rhodium-catalyzed direct C-H addition of 4,4-dimethyl-2-oxazoline to alkenes.

  Organic letters 20040513

• A new dirhodium(II) carboxamidate complex as a chiral Lewis acid catalyst for enantioselective hetero-Diels-Alder reactions.

  Angewandte Chemie (International ed. in English) 20040510

• Dirhodium tetracarboxylate scaffolds as reversible fluorescence-based nitric oxide sensors.

  Journal of the American Chemical Society 20040421

• Direct DNA photocleavage by a new intercalating dirhodium(II/II) complex: comparison to Rh2(mu-O2CCH3)4.

  Inorganic chemistry 20040419

• Cholesterol amperometric biosensor based on cytochrome P450scc.

  Biosensors & bioelectronics 20040415

• Direct, stereoselective substitution in [Rh(CO)(2)Cl](2)-catalyzed allylic alkylations of unsymmetrical substrates.

  Organic letters 20040415

• A novel class of P-O monophosphite ligands derived from D-mannitol: broad applications in highly enantioselective Rh-catalyzed hydrogenations.

  The Journal of organic chemistry 20040402

• Sweet success: Ionic liquids derived from non-nutritive sweeteners.

  Chemical communications (Cambridge, England) 20040321

• The complete characterization of a rhodium Lewis acid-dipolarophile complex as an intermediate for the enantioselective catalytic 1,3-dipolar cycloaddition of C,N-diphenylnitrone to methacrolein.

  Journal of the American Chemical Society 20040310

• Catalytic addition of metallo-aldehyde enolates to ketones: a new C-C bond-forming hydrogenation.

  Organic letters 20040304

• An expedient and practical method for the synthesis of a diverse series of cyclopropane alpha-amino acids and amines.

  The Journal of organic chemistry 20040220

• Metallo-aldehyde enolates via enal hydrogenation: catalytic cross aldolization with glyoxal partners as applied to the synthesis of 3,5-disubstituted pyridazines.

  The Journal of organic chemistry 20040220

• An alternative approach based on artificial neural networks to study controlled drug release.

  Journal of pharmaceutical sciences 20040201

• Anti-Markovnikov hydrofunctionalization of olefins mediated by rhodium-porphyrin complexes.

  Angewandte Chemie (International ed. in English) 20040201

• Surface-enhanced Raman scattering and micro-Raman imaging of Langmuir-Blodgett films of rhodium phthalocyanine.

  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20040101

• Improvement of catalyst durability by deposition of Rh on TiO2 in photooxidation of aromatic compounds.

  Environmental science & technology 20040101

• Cytotoxicity and cell death pathways invoked by two new rhodium-ferrocene complexes in benign and malignant prostatic cell lines.

  Anticancer research 20040101

• Dirhodium formamidinate compounds with bidentate nitrogen chelating ligands.

  Inorganic chemistry 20031229

• Isotope effects and the nature of selectivity in rhodium-catalyzed cyclopropanations.

  Journal of the American Chemical Society 20031224

• Charge transport in DNA duplex/quadruplex conjugates.

  Biochemistry 20031209

• Synthesis of new chiral monodentate phosphite ligands and their use in catalytic asymmetric hydrogenation.

  Organic letters 20031016

• A novel three-component reaction catalyzed by dirhodium(II) acetate: decomposition of phenyldiazoacetate with arylamine and imine for highly diastereoselective synthesis of 1,2-diamines.

  Organic letters 20031016

• Synthesis of both enantiomers of a P-chirogenic 1,2-bisphospholanoethane ligand via convergent routes and application to rhodium-catalyzed asymmetric hydrogenation of CI-1008 (pregabalin).

  Journal of the American Chemical Society 20030827

• Surface-enhanced Raman scattering in the ultraviolet spectral region: UV-SERS on rhodium and ruthenium electrodes.

  Journal of the American Chemical Society 20030813

• The first triple thiol-thiolate hydrogen bond versus triple diselenide bond that bridges two metal centers.

  Journal of the American Chemical Society 20030806

• Regioselective and enantiospecific rhodium-catalyzed allylic alkylation reactions using copper(I) enolates: synthesis of (-)-sugiresinol dimethyl ether.

  Journal of the American Chemical Society 20030730

• Artificial metalloenzymes for enantioselective catalysis based on biotin-avidin.

  Journal of the American Chemical Society 20030730

• Synthesis, complexation, and coordination oligomerization of 1,8-pyrazine-capped 5,12-dioxocyclams.

  Inorganic chemistry 20030714

• Stereospecific biocatalytic epoxidation: the first example of direct regeneration of a FAD-dependent monooxygenase for catalysis.

  Journal of the American Chemical Society 20030709

• Asymmetric synthesis of cis-5-tert-butylproline with metal carbenoid NH insertion.

  The Journal of organic chemistry 20030627

• A Rh(I)-catalyzed cycloisomerization of homo- and bis-homopropargylic alcohols.

  Journal of the American Chemical Society 20030625

• Spirocyclopropyl beta-lactams as mechanism-based inhibitors of serine beta-lactamases. Synthesis by rhodium-catalyzed cyclopropanation of 6-diazopenicillanate sulfone.

  Journal of medicinal chemistry 20030619

• Regio- and enantiospecific rhodium-catalyzed arylation of unsymmetrical fluorinated acyclic allylic carbonates: inversion of absolute configuration.

  Journal of the American Chemical Society 20030618

• Microwave-assisted C-H bond activation: a rapid entry into functionalized heterocycles.

  Organic letters 20030612

• Rhodium-catalyzed disulfide exchange reaction.

  Journal of the American Chemical Society 20030604

• Synthesis of griseolic acid analogues: regioselective alpha-facial [1,2]-migration in the rhodium acetate catalyzed reaction of D-glucose derived alpha-diazo-beta-keto ester.

  The Journal of organic chemistry 20030530

• New strategic reactions for organic synthesis: catalytic asymmetric C-H activation alpha to nitrogen as a surrogate for the mannich reaction.

  Journal of the American Chemical Society 20030528

• Rh(II) and Rh(I) two-legged piano-stool complexes: structure, reactivity, and electronic properties.

  Inorganic chemistry 20030519

• Rhodium-catalyzed anti-Markovnikov hydroamination of vinylarenes.

  Journal of the American Chemical Society 20030514

• Spectral pattern recognition of in situ FT-IR spectroscopic reaction data using minimization of entropy and spectral similarity (MESS): application to the homogeneous rhodium catalyzed hydroformylation of isoprene.

  Applied spectroscopy 20030501

• Highly selective catalyst-directed pathways to dihydropyrroles from vinyldiazoacetates and imines.

  Journal of the American Chemical Society 20030423

• Asymmetric hydrogenation of a 4,4-diaryl-3-butenoate; a novel approach to sertraline.

  Organic & biomolecular chemistry 20030407

• Asymmetric synthesis of beta-hydroxy acid via stereoselective dirhodium(II)-catalyzed C-H insertion of alpha-alkoxydiazoketone.

  Chemical & pharmaceutical bulletin 20030401

• [Determination of trace platinum, palladium, gold and rhodium in geological samples by ICP-AES after preconcentration by diphenlthiourea immobilized on aluminum oxide].

  Guang pu xue yu guang pu fen xi = Guang pu 20030401

• Application of chiral mixed phosphorus/sulfur ligands to enantioselective rhodium-catalyzed dehydroamino acid hydrogenation and ketone hydrosilylation processes.

  Journal of the American Chemical Society 20030326

• Convenient synthesis of polyfunctionalized beta-fluoropyrroles from rhodium(II)-catalyzed intramolecular N-H insertion reactions.

  Organic letters 20030306

• Rhodium carbenoid N-H insertion reactions of primary ureas: solution and solid-phase synthesis of imidazolones.

  Organic letters 20030220

• Catalysts with mixed ligands on immobilized supports. Electronic and steric advantages.

  Organic letters 20030220

• Stabilization of duplex DNA structure and suppression of transcription in vitro by bis(quinone diimine) complexes of rhodium(III) and ruthenium(II).

  Inorganic chemistry 20030210

• Asymmetric hydrogenation of itaconic acid and enol acetate derivatives with the Rh-TangPhos catalyst.

  Organic letters 20030123

• Borane-mediated aldol cycloreduction of monoenone monoketones: diastereoselective formation of quaternary centers.

  The Journal of organic chemistry 20030110

• Lipid solubility of the platinum group metals Pt, Pd and Rh in dependence on the presence of complexing agents.

  Environmental pollution (Barking, Essex : 1987) 20030101

• Thermally inert metal ammines as light-inducible DNA-targeted agents. Synthesis, photochemistry, and photobiology of a prototypical rhodium(III)-intercalator conjugate.

  Inorganic chemistry 20021230

• A novel chiral ferrocenyl phosphine ligand from sugar: applications in Rh-catalyzed asymmetric hydrogenation reactions.

  Organic letters 20021212

• Rhodium(II,II) dimer as an efficient catalyst for aziridination of sulfonamides and amidation of steroids.

  Organic letters 20021212

• One-pot sequences of reactions with sol-gel entrapped opposing reagents: an enzyme and metal-complex catalysts.

  Journal of the American Chemical Society 20021204

• Intermolecular coupling of isomerizable alkenes to heterocycles via rhodium-catalyzed C-H bond activation.

  Journal of the American Chemical Society 20021127

• Tandem cyclization-cycloaddition behavior of rhodium carbenoids with carbonyl compounds: stereoselective studies on the construction of novel epoxy-bridged tetrahydropyranone frameworks.

  The Journal of organic chemistry 20021115

• Remote electronic effects in the rhodium-catalyzed nucleophilic ring opening of oxabenzonorbornadienes.

  The Journal of organic chemistry 20021115

• The charge conduction properties of DNA holliday junctions depend critically on the identity of the tethered photooxidant.

  Journal of the American Chemical Society 20021023

• Stereochemistry of new nitrogen containing heterocyclic aldehyde. IX. Spectroscopic studies on novel mixed-ligand complexes of Rh(III).

  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20021001

• Photoinduced cleavage by a rhodium complex at G.U mismatches and exposed guanines in large and small RNAs.

  Biochimie 20020901

• Rhodium carboxylate catalyzed decomposition of vinyldiazoacetates in the presence of heterodienes: enantioselective synthesis of the 6-azabicyclo[3.2.2]nonane and 6-azabicyclo[3.2.2]nonanone ring systems.

  The Journal of organic chemistry 20020809

• Rhodium-catalyzed silylcarbocyclization (SiCaC) and carbonylative silylcarbocyclization (CO-SiCaC) reactions of enynes.

  Journal of the American Chemical Society 20020807

• Intermolecular transition metal-catalyzed [4 + 2 + 2] cycloaddition reactions: a new approach to the construction of eight-membered rings.

  Journal of the American Chemical Society 20020731

• Rhodium catalyzed [4 + 2 + 2] cycloaddition and alkyne insertion: a new route to eight-membered rings.

  Journal of the American Chemical Society 20020731

• Asymmetric hydroformylation with highly crosslinked polystyrene-supported (R,S)-BINAPHOS-Rh(I) complexes: the effect of immobilization position.

  Bioorganic & medicinal chemistry letters 20020722

• Electrochemical evaluation of rhodium dimer-DNA interactions.

  Journal of pharmaceutical and biomedical analysis 20020720

• Highly enantioselective syntheses of functionalized alpha-methylene-gamma-butyrolactones via Rh(I)-catalyzed intramolecular Alder ene reaction: application to formal synthesis of (+)-pilocarpine.

  Journal of the American Chemical Society 20020717

• Highly selective hydroformylation of the cinchona alkaloids.

  The Journal of organic chemistry 20020712

• Regio- and enantiospecific rhodium-catalyzed allylic etherification reactions using copper(I) alkoxides: influence of the copper halide salt on selectivity.

  Journal of the American Chemical Society 20020710

• Modification of carbon nanofibres for the immobilization of metal complexes: a case study with rhodium and anthranilic acid.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20020702

• Mechanism of asymmetric hydrogenation by rhodium complexes with unsymmetrical P-chirogenic bisphosphine ligands.

  Chirality 20020701

• Stereochemical aspects of the iodine(III)-mediated aziridination reaction of some cyclic allylic carbamates.

  Organic letters 20020627

• Catalytic asymmetric cyclopropanation using bridged dirhodium tetraprolinates on solid support.

  Organic letters 20020613

• Structure and chemistry of N-substituted corroles and their rhodium(I) and zinc(II) metal-ion complexes.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20020603

• Controlled release of rhodium (II) carboxylates and their association complexes with cyclodextrins from hydroxyapatite matrix.

  Biomaterials 20020601

• Synthesis of a potent antagonist of E-selectin.

  The Journal of organic chemistry 20020517

• Highly chemoselective rhodium-catalyzed methylenation of fluorine-containing ketones.

  Organic letters 20020516

• An ortho-substituted BIPHEP ligand and its applications in Rh-catalyzed hydrogenation of cyclic enamides.

  Organic letters 20020516

• Total synthesis of (S)-(+)-imperanene. Effective use of regio- and enantioselective intramolecular carbon-hydrogen insertion reactions catalyzed by chiral dirhodium(II) carboxamidates.

  The Journal of organic chemistry 20020503

• Preparation of new microgel polymers and their application as supports in organic synthesis.

  The Journal of organic chemistry 20020503

• First example of regiospecific intermolecular C-H insertion reactions of cyclic rhodium carbenoids: novel synthesis of 3-indol-3'-yloxindoles.

  Chemical communications (Cambridge, England) 20020421

• Oxidative charge transport through DNA in nucleosome core particles.

  Chemistry & biology 20020401

• Reaction of singlet oxygen with Ir(I) and Rh(I) thiolato complexes: oxidative addition vs. S-oxidation.

  Chemical communications (Cambridge, England) 20020321

• Synthesis of monodisperse oligo-p-phenylenes via rhodium-catalyzed alkyne cyclotrimerization.

  Organic letters 20020307

• Amidoglycosylation via metal-catalyzed internal nitrogen atom delivery.

  Organic letters 20020307

• Amplification of a cyclic mixed-metalloporphyrin tetramer from a dynamic combinatorial library through orthogonal metal coordination.

  Chemical communications (Cambridge, England) 20020307

• One-pot preparation of chiral beta-amino esters by rhodium-catalyzed three-components coupling reaction.

  Chemical & pharmaceutical bulletin 20020201

• Reactivity studies of anticancer active dirhodium complexes with 2-aminothiophenol.

  Inorganic chemistry 20020128

• Synthesis of furo[2,3b]furans and furo[2,3b]pyrans via rhodium-catalyzed tandem hydroformylation/acetalization.

  Organic letters 20020124

• DNA hydrolysis and oxidative cleavage by metal-binding peptides tethered to rhodium intercalators.

  Biochemistry 20020108

• Detection of DNA base mismatches using DNA intercalators.

  Methods in enzymology 20020101

• Highly enantioselective Rh-catalyzed hydrogenation based on phosphine-phosphite ligands derived from carbohydrates.

  The Journal of organic chemistry 20011214

• A dirhodium(II)-carbenoid route to (-)- and (+)-Geissman-Waiss lactone: synthesis of (1R,7R,8R)-(-)-turneforcidine.

  The Journal of organic chemistry 20011214

• High selectivity from configurational match/mismatch in carbon-hydrogen insertion reactions of steroidal diazoacetates catalyzed by chiral dirhodium(II) carboxamidates.

  The Journal of organic chemistry 20011130

• Innovative synthesis of 4-carbaldehydepyrrolin-2-ones by zwitterionic rhodium catalyzed chemo- and regioselective tandem cyclohydrocarbonylation/CO insertion of alpha-imino alkynes.

  Journal of the American Chemical Society 20011024

• Rhodium-catalyzed asymmetric 1,4-addition of organoboron reagents to 5,6-dihydro-2(1H)-pyridinones. Asymmetric synthesis of 4-aryl-2-piperidinones.

  The Journal of organic chemistry 20011019

• Regioselective and enantiospecific rhodium-catalyzed allylic amination with N-(arylsulfonyl)anilines.

  Organic letters 20011018

• Regioselective aromatic borylation in an inert solvent.

  Organic letters 20010906

• Synthesis of paramagnetic tetranuclear rhodium and iridium complexes with the 2,6-pyridinedithiolate ligand. Redox-induced degradation to diamagnetic triiridium compounds.

  Inorganic chemistry 20010827

• Long-range oxidative damage in DNA/RNA duplexes.

  Biochemistry 20010731

• Synthesis of a new class of 5'-functionalized adenosines using a rh(ii)-catalyzed 1,3-dipolar cycloaddition.

  Organic letters 20010726

• Dosimetry of beta-ray ophthalmic applicators: comparison of different measurement methods.

  Medical physics 20010701

• Regio- and diastereoselective tandem rhodium-catalyzed allylic alkylation/Pauson-Khand annulation reactions.

  Journal of the American Chemical Society 20010516

• Probing nucleic acid structure with shape-selective rhodium and ruthenium complexes.

  Current protocols in nucleic acid chemistry 20010501

• A ring expansion-annulation strategy for the synthesis of substituted azulenes. Preparation and Suzuki coupling reactions of 1-azulenyl triflates.

  Organic letters 20010405

• Enantioselective rhodium(I)-catalyzed hydrogenation of trifluoromethyl ketones.

  Organic letters 20010208

• Antifungal activity of rhodium, iridium, and ruthenium tripodal phosphine complexes.

  The new microbiologica 20000101

• Platinum group metal sensitivity: reactivity to platinum group metal salts in platinum halide salt-sensitive workers.

  Annals of allergy 19871201

• IgE antibody responses to platinum group metals: a large scale refinery survey.

  British journal of industrial medicine 19860101