75-77-4 | Chlorotrimethylsilane

Packsize	Purity	Availability	Price	Discounted Price
25g	99.00%	in stock	$18.00	$12.00
100g	99.00%	in stock	$28.00	$19.00
250g	99.00%	in stock	$40.00	$28.00
500g	99.00%	in stock	$52.00	$36.00
1000g	99.00%	in stock	$92.00	$64.00
2500g	99.00%	in stock	$215.00	$150.00

Description

• Catalog Number: AB45737
• Chemical Name: Chlorotrimethylsilane
• CAS Number: 75-77-4
• Molecular Formula: C3H9ClSi
• Molecular Weight: 108.6421
• MDL Number: MFCD00000502
• SMILES: C[Si](Cl)(C)C
• NSC Number: 15750

Computed Properties

• Complexity: 28.4
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 5

Literature

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• Grafting of montmorillonite with different functional silanes via two different reaction systems.

  Journal of colloid and interface science 20070901

• Chemical end-grafting of homogeneous polystyrene monolayers on mica and silica surfaces.

  Langmuir : the ACS journal of surfaces and colloids 20070828

• Chlorotrimethylsilane-nitrate salts as oxidants: direct oxidative conversion of thiols and disulfides to sulfonyl chlorides.

  The Journal of organic chemistry 20070720

• Deactivation pathways of ethylene polymerization catalysts derived from titanium and zirconium 1,3-bis(furyl)-1,1,3,3-tetramethyldisilazide complexes.

  Dalton transactions (Cambridge, England : 2003) 20070707

• Thermodynamics of adsorption of binary aqueous organic liquid mixtures on a RPLC adsorbent.

  Journal of chromatography. A 20070629

• Effects of surface adsorption on catalytic activity of heavy meromyosin studied using a fluorescent ATP analogue.

  Biochemistry 20070619

• Use of different types of mesoporous materials as tools for organic synthesis.

  Journal of colloid and interface science 20070615

• Stable isotope dilution analysis of salicylic acid and hydroquinone in human skin samples by gas chromatography with mass spectrometric detection.

  Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 20070601

• Determination of fluoride in toothpaste using headspace solid-phase microextraction and gas chromatography-flame ionization detection.

  Journal of chromatography. A 20070525

• Reaction of p-toluenesulfonylamide and M(NMe2)4 (M = Ti, V): generation of electron-deficient imido complexes of early transition metals.

  Inorganic chemistry 20070416

• Derivatization procedures and determination of levoglucosan and related monosaccharide anhydrides in atmospheric aerosols by gas chromatography-mass spectrometry.

  Talanta 20070415

• Vibrational spectroscopic analysis of chlorosilanes and siloxane oligomers: implications for the spectra of polydimethylsiloxanes.

  Applied spectroscopy 20070301

• Rhenium oxohalides: synthesis and crystal structures of ReO3Cl(THF)2, ReOCl4(THF), Re2O3Cl6(THF)2, and Re2O3Cl6(H2O)2.

  Dalton transactions (Cambridge, England : 2003) 20070214

• Solvent and temperature effects on the reduction and amination reactions of electrophiles by lithium dialkylaminoborohydrides.

  The Journal of organic chemistry 20070202

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  Guang pu xue yu guang pu fen xi = Guang pu 20070201

• Cavities generated by self-organised monolayers as sensitive coatings for surface acoustic wave resonators.

  Analytical and bioanalytical chemistry 20070101

• Expedient syntheses of the N-heterocyclic carbene precursor imidazolium salts IPr.HCl, IMes.HCl and IXy.HCl.

  Beilstein journal of organic chemistry 20070101

• Unbiased characterization of genotype-dependent metabolic regulations by metabolomic approach in Arabidopsis thaliana.

  BMC systems biology 20070101

• Four-week short chain fructo-oligosaccharides ingestion leads to increasing fecal bifidobacteria and cholesterol excretion in healthy elderly volunteers.

  Nutrition journal 20070101

• Diffusivities of tris(2,2'-bipyridyl)ruthenium inside silica-nanochannels modified with alkylsilanes.

  Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 20061201

• Development of a multianalyte method for the determination of anabolic hormones in bovine urine by isotope-dilution GC-MS/MS.

  Analytical and bioanalytical chemistry 20061101

• Effects of the thermal heterogeneity of the column on chromatographic results.

  Journal of chromatography. A 20061027

• Influence of the degree of coverage of C18-bonded stationary phases on the mass transfer mechanism and its kinetics.

  Journal of chromatography. A 20060922

• Quantification of free and esterified sterols in Portuguese olive oils by solid-phase extraction and gas chromatography-mass spectrometry.

  Journal of chromatography. A 20060922

• Actin filament guidance on a chip: toward high-throughput assays and lab-on-a-chip applications.

  Langmuir : the ACS journal of surfaces and colloids 20060815

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  Langmuir : the ACS journal of surfaces and colloids 20060815

• Chlorosilane acute inhalation toxicity and development of an LC50 prediction model.

  Inhalation toxicology 20060701

• Development and validation of a new gas flame ionization detector method for the determination of finasteride in tablets.

  Analytical biochemistry 20060515

• Novel calixarene hemisphere synthesized via pinacol rearrangement of [2.1.2.1]metacyclophane.

  Organic letters 20060511

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  Organic letters 20060330

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  Journal of medicinal chemistry 20060323

• Dioxomolybdenum(VI) and dioxotungsten(VI) complexes supported by an amido ligand.

  Dalton transactions (Cambridge, England : 2003) 20060314

• An efficient diethyl ether-based soxhlet protocol to quantify faecal sterols from catchment waters.

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  Chemphyschem : a European journal of chemical physics and physical chemistry 20060213

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  Acta crystallographica. Section B, Structural science 20060201

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  Organic letters 20060119

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  Journal of the American Chemical Society 20051214

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  The Journal of organic chemistry 20051209

• The vibrational spectra of (CH3)3SiX (S=H, F, Br) molecules, revisited Transferable scale factor sets for methylsilane derivatives.

  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20051201

• Leukotoxin diols from ground corncob bedding disrupt estrous cyclicity in rats and stimulate MCF-7 breast cancer cell proliferation.

  Environmental health perspectives 20051201

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  The Journal of organic chemistry 20051111

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  Organic letters 20051110

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  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20051101

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  Organic letters 20051027

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  Dalton transactions (Cambridge, England : 2003) 20051007

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  Inorganic chemistry 20050502

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  Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 20050425

• Use of 15N-depleted artificial compost in bound residue studies.

  Chemosphere 20050401

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  Inorganic chemistry 20050321

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  Organic & biomolecular chemistry 20050307

• Difluoro complexes of platinum(II) and -(IV) with monodentate phosphine ligands: an exceptional stability of d6 octahedral organometallic fluorides.

  Inorganic chemistry 20050307

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  Biomacromolecules 20050101

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  BMC plant biology 20050101

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  Rapid communications in mass spectrometry : RCM 20050101

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  Nuclear receptor signaling 20050101

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  Molecular systems biology 20050101

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  The Journal of organic chemistry 20041224

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  Organic letters 20041209

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  Langmuir : the ACS journal of surfaces and colloids 20041123

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  Forensic science international 20041029

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  The Journal of organic chemistry 20041029

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• Chlorotrimethylsilane, a reagent for the direct quantitative analysis of fats and oils present in vegetable and meat samples.

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• Development and validation of a gas chromatography-mass spectrometry method for the simultaneous determination of buprenorphine, flunitrazepam and their metabolites in rat plasma: application to the pharmacokinetic study.

  Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 20040805

• GHB in postmortem toxicology. Discrimination between endogenous production from exposure using multiple specimens.

  Forensic science international 20040716

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  The Analyst 20040401

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  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20040301

• Pd(0)-catalyzed conjugate addition of benzylzinc chlorides to alpha,beta-enones in an atmosphere of carbon monoxide: preparation of 1,4-diketones.

  The Journal of organic chemistry 20040206

• Analytical derivatization-a tool for determination of orotic acid.

  Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 20040125

• Rhodium-catalyzed asymmetric 1,6-addition of aryltitanates to enynones giving axially chiral allenes.

  Organic letters 20040122

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  Analytical chemistry 20040101

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  Acta crystallographica. Section C, Crystal structure communications 20040101

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  Se pu = Chinese journal of chromatography 20040101

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  Analytical chemistry 20031215

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  Analytical biochemistry 20031201

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  The Journal of organic chemistry 20031128

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  Organic letters 20031113

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  Organic letters 20030918

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  The Journal of organic chemistry 20030627

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  Organic letters 20030529

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  Journal of the American Society for Mass Spectrometry 20030401

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  The Journal of organic chemistry 20030124

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  Organic letters 20030123

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  Chemical communications (Cambridge, England) 20030107

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  Rapid communications in mass spectrometry : RCM 20030101

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  The Journal of organic chemistry 20021129

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  Journal of chromatography. A 20021129

• Rhodium-catalyzed asymmetric 1,4-addition of aryltitanium reagents generating chiral titanium enolates: isolation as silyl enol ethers.

  Journal of the American Chemical Society 20021016

• Synthesis and structure of a series of new d(1)-Aryl imido-vanadium(IV) complexes stabilized by n-donor ligands.

  Inorganic chemistry 20020812

• Conformationally constrained ethylenediamines: synthesis and receptor binding of 6,8-diazabicyclo[3.2.2]nonanes.

  Bioorganic & medicinal chemistry 20020701

• Silicon-based metalloprotease inhibitors: synthesis and evaluation of silanol and silanediol peptide analogues as inhibitors of angiotensin-converting enzyme.

  Journal of the American Chemical Society 20020626

• Magnesium halide-catalyzed anti-aldol reactions of chiral N-acylthiazolidinethiones.

  Organic letters 20020404

• Comparison of methods for extraction, storage, and silylation of pentafluorobenzyl derivatives of carbonyl compounds and multi-functional carbonyl compounds.

  Analytical and bioanalytical chemistry 20020401

• Atmospheric pressure ionization LC-MS-MS determination of urushiol congeners.

  Journal of agricultural and food chemistry 20020327

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  Chemical communications (Cambridge, England) 20020321

• Synthesis and characterization of endcapped C18 stationary phases using a silica hydride intermediate.

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• Diastereoselective magnesium halide-catalyzed anti-aldol reactions of chiral N-acyloxazolidinones.

  Journal of the American Chemical Society 20020123

• TMSCl as a mild and effective source of acidic catalysis in Fischer glycosidation and use of propargyl glycoside for anomeric protection.

  Bioscience, biotechnology, and biochemistry 20020101

• Reactivity and derivatization of five-coordinate, chelated aluminum.

  Inorganic chemistry 20011217

• Hair analysis for pharmaceutical drugs. II. Effective extraction and determination of sildenafil (Viagra) and its N-desmethyl metabolite in rat and human hair by GC-MS.

  Biological & pharmaceutical bulletin 20011201

• Use of 2-(tert-butyldiphenylsilyloxymethyl) benzoyl as N-protecting group for the synthesis of prooligonucleotides.

  Bioorganic & medicinal chemistry letters 20011105

• Sorption of nonpolar aromatic contaminants by chlorosilane surface modified natural minerals.

  Environmental science & technology 20011101

• Tandem chain extension-homoenolate formation: the formation of alpha-methylated-gamma-keto esters.

  Organic letters 20010920

• Intramolecular iron(II)-catalyzed nitrogen transfer reactions of unsaturated alkoxycarbonyl azides: a facile and stereoselective route to 4,5-disubstituted oxazolidinones.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20010618

• Amino acid, fatty acid, and carbohydrate content of Artocarpus altilis (breadfruit).

  Journal of chromatographic science 20010601

• Chlorotrimethylsilane as a reagent for gas chromatographic analysis of fats and oils.

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  Current protocols in cell biology 20010501

• Stereoselective reactions. XXXIV. Enantioselective deprotonation of prochiral 4-substituted cyclohexanones using chiral bidentate lithium amides having a bulky group instead of a phenyl group on the chiral carbon.

  Chemical & pharmaceutical bulletin 20010401

• Change of the reaction pattern by methodological variations in a multicomponent assembly promoted by Ni complexes.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20010401

• Titanium alkali metal nitrido complexes.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20010202

• Effects of trimethylsilylation of copper(II)-phthalocyanine sulfonyl-aminopropyl silica gels on the separation of pi-electron-rich compounds by high-performance liquid chromatography.

  Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 20010201

• Dealkylation of phosphonate esters with chlorotrimethylsilane.

  Nucleosides, nucleotides & nucleic acids 20010101