75-97-8 | Pinacolone

Packsize	Purity	Availability	Price	Discounted Price
1g	97%	1 week	$163.00	$114.00
5g	97%	1 week	$167.00	$117.00
10g	97%	1 week	$172.00	$120.00
25g	97%	1 week	$184.00	$129.00
100g	97%	1 week	$229.00	$160.00

Description

• Catalog Number: AB44292
• Chemical Name: Pinacolone
• CAS Number: 75-97-8
• Molecular Formula: C6H12O
• Molecular Weight: 100.1589
• MDL Number: MFCD00008846
• SMILES: CC(=O)C(C)(C)C
• NSC Number: 935

Computed Properties

• Complexity: 76.7
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 7
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• XLogP3: 1.2

Literature

• The role of acid catalysis in the Baeyer-Villiger reaction. A theoretical study.

  The Journal of organic chemistry 20120817

• Hg(OTf)2-catalyzed vinylogous semi-pinacol rearrangement leading to 1,4-dihydroquinolines.

  Organic letters 20120302

• (E)-1-(1,3-Benzodioxol-5-yl)-4,4-di-methyl-pent-1-en-3-one.

  Acta crystallographica. Section E, Structure reports online 20120301

• Ionic crystals [M3O(OOCC6H5)6(H2O)3]4[α-SiW12O40] (M = Cr, Fe) as heterogeneous catalysts for pinacol rearrangement.

  Inorganic chemistry 20120116

• Synthesis, spectroscopic, and in vitro photosensitizing efficacy of ketobacteriochlorins derived from ring-B and ring-D reduced chlorins via pinacol-pinacolone rearrangement.

  The Journal of organic chemistry 20111104

• Isolation and characterization of 4-tert-butylphenol-utilizing Sphingobium fuliginis strains from Phragmites australis rhizosphere sediment.

  Applied and environmental microbiology 20101001

• Direct conversion of arylamines to pinacol boronates: a metal-free borylation process.

  Angewandte Chemie (International ed. in English) 20100301

• Effect of guest-host hydrogen bonding on the structures and properties of clathrate hydrates.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20100118

• Calyculins and related marine natural products as serine-threonine protein phosphatase PP1 and PP2A inhibitors and total syntheses of calyculin A, B, and C.

  Marine drugs 20100101

• Solvent-washable polymer templated synthesis of mesoporous materials and solid-acid nanocatalysts in one-pot.

  Chemical communications (Cambridge, England) 20091107

• 1-(4-Chloro-phen-yl)-4,4-dimethyl-pent-1-en-3-one.

  Acta crystallographica. Section E, Structure reports online 20090301

• The hydrogenation/transfer hydrogenation network in asymmetric reduction of ketones catalyzed by [RuCl2(binap)(pica)] complexes.

  Chemistry, an Asian journal 20081006

• Radical nucleophilic substitution of 2-(4-halophenyl)-2-methyl-1-chloropropane with enolate ions of ketones.

  The Journal of organic chemistry 20070413

• Coupling of enantioselective biooxidation of DL-1,2-propanediol and bioreduction of pinacolone via regeneration cycle of coenzyme.

  Applied microbiology and biotechnology 20060801

• Coupling of an aldehyde or ketone to pyridine mediated by a tungsten imido complex.

  Inorganic chemistry 20051212

• Synthesis of 2H-1,2-benzothiazine 1,1-dioxides via heteroannulation reactions of 2-iodobenzenesulfonamide with ketone enolates under S(RN)1 conditions.

  The Journal of organic chemistry 20051111

• A RuH(2)(CO)(PPh(3))(3)-catalyzed regioselective arylation of aromatic ketones with arylboronates via carbon-hydrogen bond cleavage.

  Journal of the American Chemical Society 20050427

• Designing the 'search pathway' in the development of a new class of highly efficient stereoselective hydrosilylation catalysts.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20050422

• Enzymatic enantioselective transcyanation of silicon-containing aliphatic ketone with (S)-hydroxynitrile lyase from Manihot esculenta.

  Applied microbiology and biotechnology 20041101

• Highly chemoselective oxidation of dithioester enethiolates to sulfenates: application to the synthesis of ketene dithioacetal s-oxides.

  The Journal of organic chemistry 20041001

• Degradation of isooctane by Mycobacterium austroafricanum IFP 2173: growth and catabolic pathway.

  Journal of applied microbiology 20040101

• Pinacol coupling reaction of beta-halo-alpha,beta-unsaturated aldehydes promoted by TiI4.

  Organic letters 20021114

• Multiplicity control in the polygeminal diazeniumdiolation of active hydrogen bearing carbons: chemistry of a new type of trianionic molecular propeller.

  Journal of the American Chemical Society 20011107

• Effect of meso-substituents on the osmium tetraoxide reaction and pinacol-pinacolone rearrangement of the corresponding vic-dihydroxyporphyrins.

  The Journal of organic chemistry 20010601

• Palladium-catalyzed tandem reactions to form 1-vinyl-1h-isochromene derivatives.

  The Journal of organic chemistry 20010518