7688-25-7 | 1,4-Bis(diphenylphosphino)butane

Packsize	Purity	Availability	Price	Discounted Price
5g	98%	in stock	$8.00	$5.00
25g	98%	in stock	$13.00	$9.00
100g	98%	in stock	$26.00	$18.00

Description

• Catalog Number: AB43162
• Chemical Name: 1,4-Bis(diphenylphosphino)butane
• CAS Number: 7688-25-7
• Molecular Formula: C28H28P2
• Molecular Weight: 426.4694
• MDL Number: MFCD00003051
• SMILES: C(CP(c1ccccc1)c1ccccc1)CCP(c1ccccc1)c1ccccc1

Computed Properties

• Complexity: 362
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 30
• Rotatable Bond Count: 9
• XLogP3: 6.6

Literature

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  Chemistry (Weinheim an der Bergstrasse, Germany) 20121105

• Direct substitution of primary allylic amines with sulfinate salts.

  Journal of the American Chemical Society 20120912

• Synthesis, spectral, thermal, X-ray single crystal of new RuCl₂(dppb)diamine complexes and their application in hydrogenation of Cinnamic aldehyde.

  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20120901

• Correlation between photophysical parameters and gold-gold distances in gold(I) (4-pyridyl)ethynyl complexes.

  Inorganic chemistry 20120716

• cis-[1,4-Bis(diphenyl-phosphan-yl)butane-κ(2)P,P']dichlorido(cyclo-hexane-1,2-diamine-κ(2)N,N')ruthenium(II) dichloro-methane monosolvate.

  Acta crystallographica. Section E, Structure reports online 20120501

• Ruthenium(II) phosphine/diimine/picolinate complexes: inorganic compounds as agents against tuberculosis.

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  Dalton transactions (Cambridge, England : 2003) 20110707

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• [1,4-Bis(diphenyl-phosphan-yl)butane-κP,P']chlorido(η-inden-yl)ruthenium(II).

  Acta crystallographica. Section E, Structure reports online 20110501

• Reactions of a gold(I) thiolate complex [Au(Tab)(2)](2)(PF(6))(2) (Tab = 4-(trimethylammonio)benzenethiolate) with diphosphine ligands.

  Dalton transactions (Cambridge, England : 2003) 20110121

• Synthesis of symmetrical and unsymmetrical diarylalkynes from propiolic acid using palladium-catalyzed decarboxylative coupling.

  The Journal of organic chemistry 20100917

• Ruthenium-catalyzed oxidation of alcohols into amides.

  Organic letters 20090618

• Palladium-catalyzed decarboxylative coupling of alkynyl carboxylic acids and aryl halides.

  The Journal of organic chemistry 20090206

• μ-1,4-Bis(diphenyl-phosphino-yl)butane-κO:O']bis-[cyclo-pentyl-diphen-yl(trifluoro-acetato-κO)tin(IV).

  Acta crystallographica. Section E, Structure reports online 20080601

• Evaluation of C4 diphosphine ligands in rhodium catalysed methanol carbonylation under a syngas atmosphere: synthesis, structure, stability and reactivity of rhodium(I) carbonyl and rhodium(III) acetyl intermediates.

  Dalton transactions (Cambridge, England : 2003) 20071221

• Mixed-ligand organometallic polymers containing the 'Pd(2)(dmb)2(2+)' fragment: properties of the [Pd2(dmb)2(diphos)2+](n) polymers/oligomers in solution and in the solid state.

  Inorganic chemistry 20040823

• Preparation and solid-state characterization of mixed-ligand coordination/organometallic oligomers and polymers of copper(I) and silver(I) using diphosphine and mono- and diisocyanide ligands.

  Inorganic chemistry 20040517

• A trichloro-bridged binuclear ruthenium complex with 1,1,1-tris(diphenylphosphinomethyl)ethane.

  Acta crystallographica. Section C, Crystal structure communications 20031101

• Progress in the palladium-catalyzed cyanation of aryl chlorides.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20030414

• Gold(I) macrocycles and topologically chiral [2]catenanes.

  Journal of the American Chemical Society 20020417

• Self-assembly of rings, catenanes, and a doubly braided catenane containing gold(I): the hinge-group effect in diacetylide ligands.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20010817

• Rate and mechanism of the reversible formation of cationic (eta3-allyl)-palladium complexes in the oxidative addition of allylic acetate to palladium(0) complexes ligated by diphosphanes.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20010316