865-47-4 | Potassium Tert-Butoxide

Availability
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Description

• Catalog Number: AB46924
• Chemical Name: Potassium Tert-Butoxide
• CAS Number: 865-47-4
• Molecular Formula: C4H9KO
• Molecular Weight: 112.212
• MDL Number: MFCD00012162
• SMILES: [O-]C(C)(C)C.[K+]

Computed Properties

• Complexity: 29
• Covalently-Bonded Unit Count: 2
• Heavy Atom Count: 6
• Hydrogen Bond Acceptor Count: 1

Literature

• High yielding synthesis of N-ethyl dehydroamino acids.

  Amino acids 20121001

• Intramolecular direct dehydrohalide coupling promoted by KO(t)Bu: total synthesis of Amaryllidaceae alkaloids anhydrolycorinone and oxoassoanine.

  Organic letters 20120907

• Potassium tert-butoxide-mediated regioselective silaboration of aromatic alkenes.

  Chemical communications (Cambridge, England) 20120818

• Lipase-mediated synthesis of water-soluble plant stanol derivatives in tert-butanol.

  Bioresource technology 20120601

• Neocuproine-KOtBu promoted intramolecular cross coupling to approach fused rings.

  Chemical communications (Cambridge, England) 20110921

• Mizoroki-heck-type reaction mediated by potassium tert-butoxide.

  Angewandte Chemie (International ed. in English) 20110509

• Cross coupling: When is free really free?

  Nature chemistry 20101201

• An efficient organocatalytic method for constructing biaryls through aromatic C-H activation.

  Nature chemistry 20101201

• Pd-catalyzed arylation of silyl enol ethers of substituted alpha-fluoroketones.

  Organic & biomolecular chemistry 20090421

• 3-Aryltetronic acids: efficient preparation and use as precursors for vulpinic acids.

  The Journal of organic chemistry 20090206

• Determination of carbamate, phenylurea and phenoxy acid herbicide residues by gas chromatography after potassium tert-butoxide/dimethyl sulphoxide/ethyl iodide derivatization reaction.

  Journal of chromatography. A 20081031

• New synthetic routes to optically active alpha-quaternary alpha-aryl amino acid derivatives via the diastereoselective Stevens and Sommelet-Hauser rearrangements.

  Organic & biomolecular chemistry 20081021

• Transition metal-free addition of ketones or nitriles to 1,3-dienes.

  Chemical communications (Cambridge, England) 20080207

• Palladium-catalyzed cross-coupling reactions of silanolates: a paradigm shift in silicon-based cross-coupling reactions.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20060623

• Bioassay monitoring of waste PCB samples during chemical destruction treatments.

  Water science and technology : a journal of the International Association on Water Pollution Research 20060101

• Chemiluminescence in molecular recognition: base-induced decomposition of optically active dioxetanes bearing a bisnaphthol moiety with a complex of optically active crown ether-potassium tert-butoxide.

  Chemical communications (Cambridge, England) 20050214

• Formation of 4-aminopyrimidines via the trimerization of nitriles using focused microwave heating.

  Journal of combinatorial chemistry 20050101

• Synthesis of carbazoles via an intramolecular cyclization of 2-(6-substituted 3(Z)-hexen-1,5-diynyl)anilines and their related molecules.

  The Journal of organic chemistry 20040319

• Utilizing capillary gas chromatography mass spectrometry to determine 4-benzotrifluoride t-butyl ether as a reaction by-product in fluoxetine synthesized using potassium t-butoxide as base.

  Journal of pharmaceutical and biomedical analysis 20030205

• Synthesis and characterization of injectable, water-soluble copolymers of tertiary amine methacrylates and poly(ethylene glycol) containing methacrylates.

  Biomaterials 20021101