945-51-7 | Diphenyl sulfoxide

Packsize	Purity	Availability	Price	Discounted Price
25g	98%	in stock	$12.00	$8.00
500g	98%	in stock	$211.00	$148.00

Description

• Catalog Number: AB79251
• Chemical Name: Diphenyl sulfoxide
• CAS Number: 945-51-7
• Molecular Formula: C12H10OS
• Molecular Weight: 202.2722
• MDL Number: MFCD00002085
• SMILES: O=S(c1ccccc1)c1ccccc1

Computed Properties

• Complexity: 171
• Covalently-Bonded Unit Count: 1
• Heavy Atom Count: 14
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• XLogP3: 2.1

Literature

• Mechanistic studies on a sulfoxide transfer reaction mediated by diphenyl sulfoxide/triflic anhydride.

  Chemistry (Weinheim an der Bergstrasse, Germany) 20120305

• Tunable stereoselectivity during sialylation using an N-acetyl-5-N,4-O-oxazolidinone-protected p-toluene 2-thio-sialoside donor with Tf(2)O/Ph(2)SO/TTBPy.

  Carbohydrate research 20110816

• Li⁺ selective podand-type fluoroionophore based on a diphenyl sulfoxide derivative bearing two pyrene groups.

  Molecules (Basel, Switzerland) 20110810

• Fluorescence emission mechanism and fluorescence properties of ternary Tb(III) complex with diphenyl sulphoxide and bipyridine.

  Luminescence : the journal of biological and chemical luminescence 20110101

• Gold-catalyzed oxidative ring expansions and ring cleavages of alkynylcyclopropanes by intermolecular reactions oxidized by diphenylsulfoxide.

  Angewandte Chemie (International ed. in English) 20101217

• Investigating the coenzyme specificity of phenylacetone monooxygenase from Thermobifida fusca.

  Applied microbiology and biotechnology 20101101

• Calyculins and related marine natural products as serine-threonine protein phosphatase PP1 and PP2A inhibitors and total syntheses of calyculin A, B, and C.

  Marine drugs 20100101

• [Study on photoluminescence of 2-(4-chloro-benzoyl)benzoic acid complexes].

  Guang pu xue yu guang pu fen xi = Guang pu 20091101

• Polystyrene bound oxidovanadium(IV) and dioxidovanadium(V) complexes of histamine derived ligand for the oxidation of methyl phenyl sulfide, diphenyl sulfide and benzoin.

  Dalton transactions (Cambridge, England : 2003) 20090328

• Efficient dehydrative sialylation of C-4-aminated sialyl-hemiketal donors with Ph2SO/Tf2O.

  The Journal of organic chemistry 20090220

• Photosensitized oxidation of alkyl phenyl sulfoxides. C-S bond cleavage in alkyl phenyl sulfoxide radical cations.

  The Journal of organic chemistry 20080801

• Toward prediction of alkane/water partition coefficients.

  Journal of medicinal chemistry 20080710

• DNA cleavage by photolysis of aryl sulfoxides.

  Bioorganic & medicinal chemistry letters 20071115

• Pyramidal inversion mechanism of simple chiral and achiral sulfoxides: a theoretical study.

  Chirality 20070701

• Use of simple docking methods to screen a virtual library for heteroactivators of cytochrome P450 2C9.

  Journal of medicinal chemistry 20070322

• On the use of 3,5-O-benzylidene and 3,5-O-(di-tert-butylsilylene)-2-O-benzylarabinothiofuranosides and their sulfoxides as glycosyl donors for the synthesis of beta-arabinofuranosides: importance of the activation method.

  The Journal of organic chemistry 20070302

• Microsphere-based protease assays and screening application for lethal factor and factor Xa.

  Cytometry. Part A : the journal of the International Society for Analytical Cytology 20060501

• Efficient glycosidation of a phenyl thiosialoside donor with diphenyl sulfoxide and triflic anhydride in dichloromethane.

  Organic letters 20060302

• Synthesis and spectroscopic behavior of highly luminescent Eu(3+)-dibenzoylmethanate (DBM) complexes with sulfoxide ligands.

  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20050901

• Photosensitized oxygenation of sulfides within an amphiphilic dendrimer containing a benzophenone core.

  The journal of physical chemistry. B 20050512

• Calculating virtual log P in the alkane/water system (log P(N)(alk)) and its derived parameters deltalog P(N)(oct-alk) and log D(pH)(alk).

  Journal of medicinal chemistry 20050505

• A facile one-pot benzylation of sodium enolates using trifluoromethanesulfonic anhydride and diphenyl sulfoxide.

  Chemical & pharmaceutical bulletin 20050501

• Synthesis, characterization, and photochemical behavior of {Ru(arene)}2+ derivatives of alpha-[PW11O39]7-: an organometallic way to ruthenium-substituted heteropolytungstates.

  Inorganic chemistry 20050418

• Determination of the sulphoxides and sulphones of three simple sulphides in rat urine: effects of phenobarbitone, beta-naphthoflavone and methimazole.

  Biomedical chromatography : BMC 20050101

• [Influence of Pr3+ on Eu3+ luminescence in three component complex system of Eu(ClO4)3-DPSO-phen].

  Guang pu xue yu guang pu fen xi = Guang pu 20041101

• Hammett correlations in the photosensitized oxidation of 4-substituted thioanisoles.

  The Journal of organic chemistry 20040206

• Ph2SO/Tf2O: a powerful promotor system in chemoselective glycosylations using thioglycosides.

  Organic letters 20030501

• [Fluorescence enhancement character of terbium perchlorate and thulium perchlorate with phenylcarboxymethyl sulfoxide coordination compounds].

  Guang pu xue yu guang pu fen xi = Guang pu 20021201

• HPLC analysis of 4-chlorophenyl methyl sulphide and diphenyl sulphide and their corresponding sulphoxides and sulphones in rat liver microsomes.

  Journal of pharmaceutical and biomedical analysis 20020101

• Novel pyrimidine-bridged platinum(II) complexes: multinuclear magnetic resonance spectroscopy and crystal structures of (NR4)2[(PtCl3)2(mu-pyrimidine)] and cis- and trans-[Pt(R2SO)Cl2]2(mu-pyrimidine).

  Inorganic chemistry 20010924

• Total synthesis of natural dysidiolide.

  The Journal of organic chemistry 20010223

• Diarylsulfones, a new chemical class of nonnucleoside antiviral inhibitors of human immunodeficiency virus type 1 reverse transcriptase.

  Antimicrobial agents and chemotherapy 19930401